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Nitric acid is a possible biomarker in the atmospheres of exoplanets. An accurate line list of rotational and rotational-vibrational transitions is computed for nitric acid (HNO$_3$). This line list covers wavelengths longer than 1.42…

Earth and Planetary Astrophysics · Physics 2015-08-06 Anatoly I. Pavlyuchko , Sergei N. Yurchenko , Jonathan Tennyson

Comprehensive rotation-vibration line lists are presented for the two main isotopologues of methyl chloride, $^{12}$CH$_3{}^{35}$Cl and $^{12}$CH$_3{}^{37}$Cl. The line lists, OYT-35 and OYT-37, are suitable for temperatures up to…

Earth and Planetary Astrophysics · Physics 2018-08-21 A. Owens , A. Yachmenev , W. Thiel , A. Fateev , J. Tennyson , S. N. Yurchenko

Sulphur dioxide is well-known in the atmospheres of planets and satellites, where its presence is often associated with volcanism, and in circumstellar envelopes of young and evolved stars as well as the interstellar medium. This work…

An analysis of the measured rovibrational transitions is carried out for the 12C32S2 isotopologue of carbon disulfide. Data from 21 sources is extracted and validated using a consistent set of standard linear molecule quantum numbers. A…

Atomic Physics · Physics 2025-02-28 Tanvi Sattiraju , Jonathan Tennyson

Sulphur trioxide (SO$_3$) is a trace species in the atmospheres of the Earth and Venus, as well as well as being an industrial product and an environmental pollutant. A variational line list for $^{32}$S$^{16}$O$_{3}$, named UYT2, is…

Earth and Planetary Astrophysics · Physics 2016-09-21 Daniel S. Underwood , Sergei N. Yurchenko , Jonathan Tennyson , Ahmed F. Al-Refaie , Sønnik Clausen , Alexander Fateev

We present line lists for ammonia (NH$_{3}$) at high temperatures obtained by recording Fourier transform infrared emission spectra. Calibrated line lists are presented for twelve temperatures (300 -- 1300$^{\circ}$C in 100$^{\circ}$C…

Instrumentation and Methods for Astrophysics · Physics 2015-05-28 R. J. Hargreaves , G. Li , P. F. Bernath

We present calculated rate coefficients for ro-vibrational transitions of CO in collisions with H atoms for a gas temperature range of 10 K $\leq T \leq$ 3000 K, based on the recent three-dimensional ab initio H-CO interaction potential of…

Astrophysics of Galaxies · Physics 2015-11-23 L. Song , N. Balakrishnan , K. M. Walker , P. C. Stancil , W. F. Thi , I. Kamp , A. van der Avoird , G. C. Groenenboom

In hot plasmas, a temperature of a few tens of eV is sufficient for producing highly stripped ions where multipole transitions become important. At low density, the transitions from tightly bound inner shells lead to electric-quadrupole…

Atomic Physics · Physics 2015-06-05 Jean-Christophe Pain , Franck Gilleron , Jacques Bauche , Claire Bauche-Arnoult

Using APEX-1 and APEX-2 observations, we have detected and studied the rotational lines of the HC$_3$N molecule (cyanoacetylene) in the powerful outflow/hot molecular core G331.512-0.103. We identified thirty-one rotational lines at $J$…

A novel, to the best of our knowledge, ultralow-temperature luminescence thermometry strategy is proposed, based on a measurement of relative intensities of hyperfine components in the spectra of Ho$^{3+}$ ions doped into a crystal. A…

Optics · Physics 2025-11-25 Marina N. Popova , Mosab Diab , Boris Z. Malkin

The precise measurement of transition frequencies in cold, trapped molecules has applications in fundamental physics, and extremely high accuracies are desirable. We determine suitable candidates by considering simple molecules with a…

Atomic Physics · Physics 2014-02-11 Stephan Schiller , Dimitar Bakalov , Vladimir I. Korobov

Aim: We present an improved database of temperature dependent rate coefficients for rotational state-to-state transitions in H$_{2}$O + H$_{2}$O collisions. The database includes 231 transitions between the lower $para$- and 210 transitions…

Chemical Physics · Physics 2023-10-19 Bikramaditya Mandal , Dmitri Babikov

A new hot line list for $^{14}$NH$_3$ is presented. The line list CoYuTe was constructed using an accurate, empirically refined potential energy surface and a CCSD(T)/aug-cc-pVQZ ab initio dipole moment surface of ammonia, previously…

Solar and Stellar Astrophysics · Physics 2019-11-26 Phillip A. Coles , Sergei N. Yurchenko , Jonathan Tennyson

Published high-resolution rotation-vibration transitions of \spec{h212c16o}, the principal isotopologue of methanal, are analyzed using the MARVEL (Measured Active Rotation-Vibration Energy Levels) procedure. The literature results are…

Molecular line-transition lists are an essential ingredient for radiative-transfer calculations. With recent databases now surpassing the billion-lines mark, handling them has become computationally prohibitive, due to both the required…

Earth and Planetary Astrophysics · Physics 2017-11-29 Patricio Cubillos

Atmospheric CO$_2$ concentrations are being closely monitored by remote sensing experiments which rely on knowing line intensities with an uncertainty of 0.5\%\ or better. Most available laboratory measurements have uncertainties much…

Atmospheric and Oceanic Physics · Physics 2015-10-28 Oleg L. Polyansky , Katarzyna Bielska , Mélanie Ghysels , Lorenzo Lodi , Nikolai F. Zobov , Joseph T. Hodges , Jonathan Tennyson

Line lists for the ground electronic ground state for six major isotopologues of nitric oxide are presented. The line lists are constructed using empirical energy levels (and line positions) and high-level {\it ab inito} intensities. The…

Earth and Planetary Astrophysics · Physics 2017-06-28 Andy Wong , Sergei N. Yurchenko , Peter Bernath , Holger S. P. Müller , Stephanie McConkey , Jonathan Tennyson

Accurate prediction of electron temperature ($T_{\rm e}$) is critical for non-equilibrium plasma applications ranging from hypersonic flight to plasma-assisted combustion. We recently proposed a thermodynamically consistent model for…

Plasma Physics · Physics 2026-03-13 Bernard Parent , Felipe Martin Rodriguez Fuentes

Collisional (de-)excitation of H$_{2}$ by helium plays an important role in the thermal balance and chemistry of various astrophysical environments, making accurate rate coefficients essential for the interpretation of observations of the…

Astrophysics of Galaxies · Physics 2024-05-15 Hubert Jóźwiak , Franck Thibault , Alexandra Viel , Piotr Wcisło , François Lique

Loops are fundamental structures in the magnetized atmosphere of the sun. Their physical properties are crucial for understanding the nature of the solar atmosphere. Transition region loops are relatively dynamic and their physical…

Solar and Stellar Astrophysics · Physics 2024-04-16 Shiyu Liang , Ziyuan Wang , Zhenghua Huang , Hengyuan Wei , Hui Fu , Ming Xiong , Lidong Xia