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We investigate the attosecond response of the electronic cloud of a molecular system to an outer-valence ionization. The time needed for the remaining electrons to respond to a sudden perturbation in the electronic structure of the molecule…

Chemical Physics · Physics 2022-06-22 K. Chordiya , V. Despré , M. U. Kahaly , A. I. Kuleff

We use extreme-ultraviolet interferometry to measure the phase of high-order harmonic generation from transiently aligned CO2 molecules. We unambiguously observe a reversal in phase of the high order harmonic emission for higher harmonic…

Atomic Physics · Physics 2009-11-13 Xibin Zhou , Robynne Lock , Wen Li , Nick Wagner , Margaret. M. Murnane , Henry C. Kapteyn

We have recorded the coherent diffraction images of individual xenon clusters with intense extreme ultraviolet pulses to elucidate the influence of light-induced electronic changes on the diffraction pattern. Using the FLASH free-electron…

Single-particle methods based on Kohn-Sham unoccupied states to describe near-edge X-ray absorption (XAS) spectra are routinely applied for the description of K-edge spectra, as there is no complication due to spin-orbit (SO) coupling. L-…

Materials Science · Physics 2026-02-26 Esther A. B. Johnsen , Naoki Horiuchi , Toma Susi , Michael Walter

Developing a detailed understanding for the role of core electron excitation in liquid water under proton irradiation has become important due to the growing use of proton beams in radiation oncology. Using a first-principles,…

Materials Science · Physics 2019-08-14 Yi Yao , Dillon C. Yost , Yosuke Kanai

In this work we investigate the effects of the environment on the X-ray photoelectron spectra of hydrogen chloride and the chloride ions adsorbed on ice surfaces, as well as of chloride ions in water droplets. In our approach, we combine a…

Chemical Physics · Physics 2023-09-18 Richard A. Opoku , Céline Toubin , André Severo Pereira Gomes

We use variational quantum Monte Carlo to calculate the density-functional exchange-correlation hole n_{xc}, the exchange-correlation energy density e_{xc}, and the total exchange-correlation energy E_{xc}, of several electron gas systems…

Materials Science · Physics 2009-10-31 Maziar Nekovee , W. M. C. Foulkes , R. J. Needs

We employ the k-th nearest-neighbor estimator of configurational entropy in order to decode within a parameter-free numerical approach the complex high-order structural correlations in fluxional molecules going beyond the usual linear,…

Chemical Physics · Physics 2020-10-20 Rafal Topolnicki , Fabien Brieuc , Christoph Schran , Dominik Marx

X-ray Transient Absorption Spectroscopy near the carbon K-edge (1s, $\sim$ 285 eV) and chlorine L$_{2,3}$ edges (2p, $\sim$ 200 eV) is used to study the nuclear dynamics of CCl$_4$ vibrationally activated by impulsive stimulated Raman…

We report on the study of many-body interactions in a single high quality V-shaped quantum wire by means of continuous and time-resolved microphotoluminescence. The transition from a weakly interacting exciton gas when the carrier density n…

Condensed Matter · Physics 2007-05-23 Thierry Guillet , Roger Grousson , Valia Voliotis , Michel Menant , Xue-Lun Wang , Mutsuo Ogura

An effective Hamiltonian and equations of motion for treating both the resonant dipole-dipole interaction between two-level atoms and the resonant atom-field interaction are derived, which can suitably be used for studying the influence of…

Quantum Physics · Physics 2016-08-16 D. -G. Welsch , Ho Trung Dung , L. Knöll

We discuss the exchange-correlation energy of a multicomponent (multi-valley) two-dimensional electron gas and show that an extension of the recent parametrisation of the exchange-correlation energy by Attacalite et al (Phys. Rev. Lett. 88,…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 K. Karkkainen , M. Koskinen , S. M. Reimann , M. Manninen

We report the first direct spectroscopic evidence for coherent electronic coupling between excitons and trions in atomically thin transition metal dichalcogenides, specifically monolayer MoSe2. Signatures of coupling appear as isolated…

Mesoscale and Nanoscale Physics · Physics 2014-09-30 Akshay Singh , Galan Moody , Sanfeng Wu , Yanwen Wu , Nirmal J. Ghimire , Jiaqiang Yan , David G. Mandrus , Xiaodong Xu , Xiaoqin Li

Modern X-ray spectroscopy has proven itself as a robust tool for probing the electronic structure of atoms in complex environments. Despite working on energy scales that are much larger than those corresponding to nuclear motions, taking…

Chemical Physics · Physics 2017-06-28 Sven Karsten , Sergey I. Bokarev , Saadullah G. Aziz , Sergei D. Ivanov , Oliver Kühn

In this paper we present a study of an exciton system where electrons and holes are confined in double quantum well structures. The dominating interaction between excitons in such systems is a dipole - dipole repulsion. We show that the…

Quantum Gases · Physics 2015-05-13 B. Laikhtman , R. Rapaport

We present a theoretical study of interacting electron-hole pairs located on a magnetized surface of a strong topological insulator (TI). The excitonic energy levels and the optical absorption on such surface display unique and potentially…

Strongly Correlated Electrons · Physics 2011-07-05 Ion Garate , M. Franz

We investigate the role of the electron correlation effects in the calculations of the electric dipole polarizabilities (\alpha) of elements belonging to three different groups of periodic table. To understand the propagation of the…

Atomic Physics · Physics 2014-05-21 Yashpal Singh , B. K. Sahoo

The dissociation of excited electron-hole pairs is a microscopic process that is fundamental to the performance of photovoltaic systems. For this process to be successful, the oppositely charged electron and hole must overcome an…

Mesoscale and Nanoscale Physics · Physics 2017-08-14 Liang Shi , Chee Kong Lee , Adam P. Willard

We present analytical expressions of momentum-resolved core-level photoemission time delay in a molecular frame of a heteronuclear diatomic molecule upon photoionization by a linearly polarized soft x-rays attosecond pulse. For this…

Chemical Physics · Physics 2022-05-31 Y. Tamura , K. Yamazaki , K. Ueda , K. Hatada

We investigate theoretically the effects of interaction between an optical dipole (semiconductor quantum dot or molecule) and metal nanoparticles. The calculated absorption spectra of hybrid structures demonstrate strong effects of…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Jie-Yun Yan , Wei Zhang , Suqing Duan , Xian-Geng Zhao , Alexander O. Govorov
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