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Ferroelastic materials (materials with switchable spontaneous strain) often are centrosymmetric, but their domain walls are always polar, as their internal strain gradients cause polarization via flexoelectricity. This polarization is…

Materials Science · Physics 2025-03-11 Guangming Lu , Gustau Catalan , Ekhard K. H. Salje

The effect of polarization fatigue on the Rayleigh coefficients of ferroelectric lead zirconate titanate (PZT) thin film was systematically investigated. It was found that electrical fatigue strongly affects the Rayleigh behaviour of the…

Materials Science · Physics 2015-06-19 X. J. Lou , H. J. Zhang , Z. D. Luo , F. P. Zhang , Y. Liu , Q. D. Liu , A. P. Fang , B. Dkhil , M. Zhang , X. B. Ren , H. L. He

We describe the design of a new magnetic ferroelectric with large spontaneous magnetization and polarization using first-principles density functional theory. The usual difficulties associated with the production of robustly-insulating…

Materials Science · Physics 2011-11-09 Pio Baettig , Nicola Spaldin

Single charge control of localized excitons (LXs) in two-dimensional transition metal dichalcogenides (TMDCs) is crucial for potential applications in quantum information processing and storage. However, traditional electrostatic doping…

The proposal of using the field-effect for doping organic crystals has raised enormous interest. To assess the feasibility of such an approach, we investigate the effect of a strong electric field on the electronic structure of C60…

Materials Science · Physics 2007-05-23 Erik Koch , Olle Gunnarsson , Samuel Wehrli , Manfred Sigrist

Here we demonstrate that MnTe epitaxial films with zinc-blend structure and MnTe/ZnTe multilayers should show ferroelectric polarization in antiferromagnetically (AFM) ordered state and thus belong to multiferroics. Spontaneous…

Materials Science · Physics 2008-11-14 Helen V. Gomonay , Ievgeniia G. Korniienko

Materials with field-tunable polarization are of broad interest to condensed matter sciences and solid-state device technologies. Here, using hydrogen (H) donor doping, we modify the room temperature metallic phase of a perovskite nickelate…

The possibility that metals may support ferroelectricity is an open issue. Anderson and Blount showed that certain martensitic transitions involve inversion symmetry breaking and the formal existence of a polar axis, so 'metallic…

Materials Science · Physics 2016-04-08 Alessio Filippetti , Vincenzo Fiorentini , Francesco Ricci , Pietro Delugas , Jorge Íñiguez

Thin films of aluminum hafnium nitride (Al$_{1-x}$Hf$_{x}$N) were synthesized via reactive magnetron sputtering for Hf contents up to $x$ = 0.13. X-ray diffraction showed a single $c$-axis oriented wurtzite phase for all films. Hard X-ray…

Ferromagnetic films with perpendicular magnetic anisotropy are of interest in spintronics and superconducting spintronics. Perpendicular magnetic anisotropy can be achieved in thin ferromagnetic multilayer structures, when the anisotropy is…

Mesoscale and Nanoscale Physics · Physics 2023-06-01 N. Satchell , S. Gupta , M. Maheshwari , P. M. Shepley , M. Rogers , O. Cespedes , G. Burnell

We calculate the effect of epitaxial strain on the structure and properties of multiferroic bismuth ferrite, BiFeO3, using first-principles density functional theory. We find that, while small strains cause only quantitative changes in…

Materials Science · Physics 2021-04-06 A. J. Hatt , N. A. Spaldin , C. Ederer

We describe ferroelectric thin films with circular electrodes and develop a thermodynamic theory that explains previously mysterious experiments. It is found to be especially useful for restricted geometries such as microstructures for…

Materials Science · Physics 2015-06-19 Laurent Baudry , Anaïs Sené , Igor A. Luk'yanchuk , Laurent Lahoche , James F Scott

Bismuth based ternary oxide photocatalysts are of considerable interest in photoelectrochemical water splitting. Yet these oxides are highly stable in different environment, their relative inertness limits the available synthesis routes to…

Applied Physics · Physics 2019-11-28 Tilak Poudel , Baicheng Weng , Corey Grice , Yanfa Yan , Xunming Deng

Ferroelectricity can exist in elemental phases as a result of charge transfers between atoms occupying inequivalent Wyckoff positions. We investigate the emergence of ferroelectricity in two-dimensional elemental materials with buckled…

Using first-principles density functional theory calculations, we discover an anomalously large bi-axial strain-induced octahedral rotation axis reorientation in orthorhombic perovskites with tendency towards rhombohedral symmetry. The…

Materials Science · Physics 2011-06-14 James M. Rondinelli , Sinisa Coh

On the basis of detailed first-principles calculations the anisotropic thermoelectric transport properties of biaxially strained silicon were studied with focus on a possible enhancement of the powerfactor. Electron as well as hole doping…

Materials Science · Physics 2011-10-18 Nicki F. Hinsche , Ingrid Mertig , Peter Zahn

Bismuth (Bi) films hold potential for spintronic devices and topological one-dimensional edge transport. Large-area high-quality (111) Bi ultrathin films are grown on InSb (111)B substrates. Strong film-substrate interactions epitaxially…

We systematically investigate the effect of strain and doping on the polar metal phase in lithium osmate, LiOsO$_3$, using first-principles calculations. We demonstrate that the polar metal phase in LiOsO$_3$ can be controlled by biaxial…

Materials Science · Physics 2020-04-28 Awadhesh Narayan

Using first-principles calculations, we estimated the impact of large applied electric E fields on the structural, dielectric, and ferroelectric properties of typical ferroelectrics. At large fields, the structural parameters change…

Materials Science · Physics 2016-05-25 Daniel I. Bilc , Liviu Zarbo , Sorina Garabagiu , Eric Bousquet , Liliana Mitoseriu

The magnetic easy axis orientation was studied by the third order perturbed Heisenberg Hamiltonian. Ferromagnetic CoPt/AlN multilayer thin films with number of layers N=11, 16 and 21 synthesized on fused quartz substrates using dc magnetron…

Materials Science · Physics 2016-07-14 P. Samarasekara , Prabhani Rajakaruna