Related papers: Modified Associate Formalism without Entropy Parad…
We investigate the possible classification of zero-temperature spin-gapped phases of multicomponent electronic systems in one spatial dimension. At the heart of our analysis is the existence of non-perturbative duality symmetries which…
The thermodynamic approach to non-equilibrium dynamics describes the state of macroscopic systems by means of a collection of intensities or intensive variables. The latter are by definition the differentials of the entropy with respect to…
We present a thermodynamically consistent theoretical framework for lyotropic liquid crystals (LCs) based on the GENERIC (General Equation for the Non-Equilibrium Reversible-Irreversible Coupling) formalism. This formalism ensures…
The configurational entropy of supercooled liquids extrapolates to zero at the Kauzmann temperature, causing a crisis called the Kauzmann paradox. Here, using a class of multicomponent lattice glass models, we study a resolution of the…
In this paper, we suppose a possible extension of Gibbs ensemble theory so that it can provide a reasonable description to phase transitions and spontaneous symmetry breaking. The extension is founded on three hypotheses, and can be…
Predictive synthesis of aqueous organic solutions with desired liquid-solid phase equilibria could drive progress in industrial chemistry, cryopreservation, and beyond, but is limited by the predictive power of current solution…
A thermodynamic model of formation of multi-component solid solutions as a thermodynamic mixture of their binary components, is proposed. There are obtained expressions for the effective temperature of the equilibrium state of the solid…
High-entropy alloys, which exist in the high-dimensional composition space, provide enormous unique opportunities for realizing unprecedented structural and functional properties. A fundamental challenge, however, lies in how to predict the…
A model of low-temperature polar liquids is constructed that accounts for configurational heat capacity, entropy, and the effect of a strong electric field on the glass transition. The model is based on Pad{\'e}-truncated perturbation…
We study properties of entangled systems in the (mainly non-relativistic) second quantization formalism. This is then applied to interacting and non-interacting bosons and fermions and the differences between the two are discussed. We…
We investigate the theory of thermodynamic formalism from the perspective of computable analysis, with a special focus on the computability of equilibrium states. Specifically, we develop two complementary general approaches to verify the…
Thermodynamic perturbation theory for central-force (TPT-CF) type of associating potential is used to study the phase behavior of symmetric binary mixture of associating particles with spherically symmetric interaction. The model is…
We present a new methodology for the characterization of the metric entropy of infinite-dimensional ellipsoids with exponentially decaying semi-axes. This procedure does not rely on the explicit construction of coverings or packings and…
We consider the meta-equilibrium state of a composite system made up of independent subsystems satisfying the additive form of external constraints, as recently discussed by Abe [Phys. Rev. E {\bf 63}, 061105 (2001)]. We derive the additive…
Using molecular dynamics simulations we study the temperature-density phase diagram of a simple model system of particles in two dimensions. In addition to translational degrees of freedom, each particle has two internal states and…
We introduce a simple model of the time evolution of a binary mixture of compressible fluids including the thermal effects. Despite its apparent simplicity, the model is thermodynamically consistent admitting an entropy balance equation. We…
Dissipative quantum systems are frequently described within the framework of the so-called "system-plus-reservoir" approach. In this work we assign their description to the Maximum Entropy Formalism and compare the resulting thermodynamic…
The Lebwohl-Lasher model of uniaxial liquid crystals with (\textit{n} = 3, \textit{d} = 2) was reported earlier to undergo a crossover transition to a novel nematic phase at a temperature $T=T_{n}$. This phase has unbound topological…
Thermodynamics of a pseudospin-electron model without correlations is investigated. The correlation functions, the mean values of pseudospin and particle number, as well as the thermodynamic potential are calculated. The calculation is…
We present a novel joint time-dependent density-functional theory for the description of solute-solvent systems in time-dependent external potentials. Starting with the exact quantum-mechanical action functional for both electrons and…