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The glass transition temperature and its connection to statistical properties of confined and free-standing polymer films of varying thickness containing unentangled to highly entangled bead-spring chains are studied by molecular dynamics…

Soft Condensed Matter · Physics 2023-09-21 Hsiao-Ping Hsu , Kurt Kremer

A lattice model of a hetero-polymer with random hydrophilic-hydrophobic charges interacting with the solvent is introduced, whose continnuum counterpart has been proposed by T. Garel, L. Leibler and H. Orland {J. Phys. II France 4, 2139…

Statistical Mechanics · Physics 2009-10-31 A. Trovato , J. van Mourik , A. Maritan

Perovskite solar cells (PSC) are promising potential competitors to established photovoltaic technologies due to their superior efficiency and low-cost solution processability. However, the limited understanding of the crystallization…

Materials Science · Physics 2024-11-01 M. Majewski , S. Qiu , O. Ronsin , L. Lüer , V. M. Le Corre , T. Du , C. J. Brabec , H. -J. Egelhaaf , J. Harting

Propylene carbonate (PC) wets graphite with a contact angle of 31 deg at ambient conditions. Molecular dynamics simulations agree with this contact angle after 40% reduction of the strength of graphite-C atom Lennard-Jones interactions with…

We analyze diffusion of small particles in a solid polymeric medium taking into account a short range particle-polymer interaction. The system is modeled by a particle diffusion on a ternary lattice where the sites occupied by polymer…

Statistical Mechanics · Physics 2015-06-11 Federico Camboni , Andreas Koher , Igor M. Sokolov

We examine sedimentation density profiles of star polymer solutions as an example of colloidal systems in sedimentation equilibrium which exhibit reentrant melting in their bulk phase diagram. Phase transitions between a fluid and a fluid…

Soft Condensed Matter · Physics 2009-11-07 J. Dzubiella , H. M. Harreis , C. N. Likos , H. Lowen

A parameterization strategy for molecular models on the basis of force fields is proposed, which allows a rapid development of models for small molecules by using results from quantum mechanical (QM) ab initio calculations and thermodynamic…

Chemical Physics · Physics 2009-04-22 Bernhard Eckl , Jadran Vrabec , Hans Hasse

Pair potentials that are bounded at the origin provide an accurate description of the effective interaction for many systems of dissolved soft macromolecules (e.g., flexible dendrimers). Using numerical free-energy calculations, we…

Soft Condensed Matter · Physics 2014-10-29 C. Speranza , S. Prestipino , G. Malescio , P. V. Giaquinta

The thermodynamic properties of the superconducting state in the amorphous ${\rm Sn_{1-x}Cu_{x}}$ thin films have been characterized. The concentration of copper changes in the range from $0.08$ to $0.41$. The calculations have been…

Superconductivity · Physics 2016-10-23 E. A. Drzazga , R. Szczęśniak , I. A. Domagalska , and K. Piwowarska

A coupled phase-field and hydrodynamic model is introduced to describe a two-phase, weakly compressible smectic (layered phase) in contact with an isotropic fluid of different density. A non-conserved smectic order parameter is coupled to a…

Soft Condensed Matter · Physics 2022-02-02 Eduardo Vitral , Perry H. Leo , Jorge Viñals

In the framework of the suggested in [arxiv:1803.08247 [cond-mat.mtrl-sci]] statistical theory of the equilibrium flow stress, including yield strength, ${\sigma}_y$, of polycrystalline materials under quasi-static (in case of tensile…

Materials Science · Physics 2020-01-01 Alexander A. Reshetnyak

We study statistical copolymerization effects on the upper critical solution temperature (CST) of generic homopolymers by means of coarse-grained Langevin dynamics computer simulations and mean-field theory. Our systematic investigation…

Soft Condensed Matter · Physics 2015-10-26 Bernhard Schulz , Richard Chudoba , Jan Heyda , Joachim Dzubiella

We present a detailed model for the thermal balance, chemistry, and radiative transfer within quiescent dense molecular cloud cores that contain a central protostar. Large variations in the gas temperature are expected to affect the…

Astrophysics · Physics 2009-10-30 S. D. Doty , D. A. Neufeld

Cold cores are an early step of star formation, characterized by densities > 10$^4$ cm$^{-3}$, low temperatures (< 15 K), and very low external UV radiation. We investigate the physico-chemical processes at play to tracing the origin of…

Astrophysics of Galaxies · Physics 2023-01-04 A. Taillard , V. WakelaM , P. Gratier , E. Dartois , M. Chabot , J. A. Noble , J. V. Keane , A. C. A. Boogert , D. Harsono

Force field have for decades proven to be an indispensable tool for molecular simulations which are out of reach for ab-initio methods. Recent efforts to improve the accuracy of these simulations have focused on the inclusion of many-body…

Chemical Physics · Physics 2020-06-26 Ruben Goeminne , Toon Verstraelen

Ferroelectric nematic fluids are promising materials for tunable nonlinear photonics, with applications ranging from second harmonic generation to sources of entangled photons. However, the few reported values of second-order…

We present the technical details of an experimental method to realize a model system for 2D phase transitions and the glass transition. The system consists of several hundred thousand colloidal super-paramagnetic particles confined by…

Soft Condensed Matter · Physics 2012-10-26 F. Ebert , P. Dillmann , G. Maret , P. Keim

In the formation and evolution of compact stars, nuclear matter explores high thermal excursions and is the site of intense neutrino emission. Neutrino transport as well as structural properties of this matter depend on the presence of…

Nuclear Theory · Physics 2008-11-26 P. Chomaz , C. Ducoin , F. Gulminelli , K. H. O. Hasnaoui , P. Napolitani

We construct a 3D radiative-hydrodynamic model atmosphere of parameters Teff = 4820 K, log g = 4.5, and solar chemical composition. The theoretical line profiles computed with this model are asymmetric, with their bisectors having a…

Solar and Stellar Astrophysics · Physics 2015-05-13 I. Ramirez , C. Allende Prieto , L. Koesterke , D. L. Lambert , M. Asplund

In this work we study a completely degenerated fermion gas at zero temperature within a semiclassical approximation for the Hamiltonian arising in polymer quantum mechanics. Polymer quantum systems are quantum mechanical models quantized in…

Solar and Stellar Astrophysics · Physics 2015-06-22 Guillermo Chacon-Acosta , Hector Hernandez-Hernandez