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Chemical bond analysis for the topological insulator (TI) Bi2Se3 following valence bond theory and VSEPR rule is proposed and compared to that of graphene. The existence of pi-bond trimers on surface Se-layer is revealed to be responsible…

Materials Science · Physics 2013-07-09 G. J. Shu , S. C. Liou , F. C. Chou

Layered narrow band gap semiconductor Bi2Se3 is composed of heavy elements with strong spin-orbital coupling (SOC), which has been identified both as a good candidate of thermoelectric material of high thermoelectric figure-of-merit (ZT)…

Materials Science · Physics 2018-04-04 G. J. Shu , S. C. Liou , S. K. Karna , R. Sankar , M. Hayashi , F. C. Chou

The existence of pi-bonds on topological insulator surfaces is found to be closely related to the phenomena of surface conduction and surface band spin polarization. A pi-bond trimer or pi-bond dimer on the surface can form open conjugated…

Strongly Correlated Electrons · Physics 2013-01-01 G. J. Shu , F. C. Chou

Topological insulators are materials with an insulating bulk interior while maintaining gapless boundary states against back scattering. Bi$_2$Se$_3$ is a prototypical topological insulator with a Dirac-cone surface state around $\Gamma$.…

Topological insulators are new class of quantum materials, which have insulating energy gaps in bulk, but exhibit gapless edge states or surface states that are protected by time-reversal symmetry at boundary. It was theoretically predicted…

Mesoscale and Nanoscale Physics · Physics 2018-03-07 G. H. Cao , H. J. Liu , J. H. Liang , L. Cheng , D. D. Fan , Z. Y. Zhang

The emergence of topological order in graphene is in great demand for the realization of quantum spin Hall states. Recently, it is theoretically proposed that the spin textures of surface states in topological insulator can be directly…

Mesoscale and Nanoscale Physics · Physics 2017-07-06 Liang Zhang , Ben-Chuan Lin , Yan-Fei Wu , Jun Xu , Dapeng Yu , Zhi-Min Liao

We predict a new family of robust two-dimensional (2D) topological insulators in van der Waals heterostructures comprising graphene and chalcogenides BiTeX (X=Cl, Br and I). The layered structures of both constituent materials produce a…

Materials Science · Physics 2014-12-25 Liangzhi Kou , Shu-Chun Wu , Claudia Felser , Thomas Frauenheim , Changfeng Chen , Binghai Yan

Van der Waals heterostructures have been used to tailor atomic layers into various artificial materials through interactions at heterointerfaces. The interplay between the band gap created by the band folding of the interfacial potential…

Interfaces between exfoliated topological insulator Bi2Se3 and several transition metals deposited by sputtering were studied by XPS, SIMS, UPS and contact I-V measurements. Chemically clean interfaces can be achieved when coating Bi2Se3…

Mesoscale and Nanoscale Physics · Physics 2015-11-12 Weiguang Ye , A. B. Pakhomov , Shuigang Xu , Huanhuan Lu , Zefei Wu , Yu Han , Tianyi Han , Yingying Wu , Gen Long , Jiangxiazi Lin , Gu Xu , Yuan Cai , Lu-Tao Weng , Ning Wang

We use first-principles simulations to investigate the topological properties of Bi$_2$Se$_3$ thin films deposited on amorphous SiO2, Bi$_2$Se$_3$/a-SiO$_2$, which is a promising substrate for topological insulator (TI) based device…

Materials Science · Physics 2016-12-21 I. S. S. de Oliveira , W. L. Scopel , R. H. Miwa

Bi2Se3 is one of a handful of known topological insulators. Here we show that copper intercalation in the van der Waals gaps between the Bi2Se3 layers, yielding an electron concentration of ~ 2 x 10^20cm-3, results in superconductivity at…

The Cu-doped topological insulator Bi$_2$Se$_3$ has recently been found to undergo a superconducting transition upon cooling, raising the possibilities that it is the first known "topological superconductor" or realizes a novel non-Abelian…

Superconductivity · Physics 2009-12-18 L. Wray , S. Xu , J. Xiong , Y. Xia , D. Qian , H. Lin , A. Bansil , Y. Hor , R. J. Cava , M. Z. Hasan

The spin-helical surface states in three-dimensional topological insulator (TI), such as Bi2Se3, are predicted to have superior efficiency in converting charge current into spin polarization. This property is said to be responsible for the…

Materials Science · Physics 2016-08-03 Jia Zhang , Julian P. Velev , Xiaoqian Dang , Evgeny Y. Tsymbal

Topological insulators are a recently discovered class of materials with fascinating properties: While the inside of the solid is insulating, fundamental symmetry considerations require the surfaces to be metallic. The metallic surface…

Prototypical three-dimensional topological insulators of the Bi$_2$Se$_3$ family provide a beautiful example of the appearance of the surface states inside the bulk band gap caused by spin-orbit coupling-induced topology. The surface states…

Mesoscale and Nanoscale Physics · Physics 2020-10-27 Klaus Zollner , Jaroslav Fabian

Using high-resolution angle-resolved photoemission spectroscopy and scanning tunneling microscopy/spectroscopy, the atomic and low energy electronic structure of the Sr-doped superconducting topological insulators (SrxBi2Se3) was studied.…

Topological insulators(1-8) are a novel form of matter which features metallic surface states with quasirelativistic dispersion similar to graphene(9). Unlike graphene, the locking of spin and momentum and the protection by time-reversal…

Mesoscale and Nanoscale Physics · Physics 2012-07-23 M. R. Scholz , J. Sánchez-Barriga , D. Marchenko , A. Varykhalov , A. Volykhov , L. V. Yashina , O. Rader

Three-dimensional (3-D) topological insulators (TI) are characterized by the presence of metallic surface states and a bulk band gap. Recently theoretical and experimental studies have shown an induced gap in the surface state bands of TI…

Mesoscale and Nanoscale Physics · Physics 2012-12-21 Jiwon Chang , Leonard F. Register , Sanjay K. Banerjee

We have studied the electron transport properties of topological insulator-related material Bi2Se3 near the superconducting Pb-Bi2Se3 interface, and found that a superconducting state is induced over an extended volume in Bi2Se3. This state…

Superconductivity · Physics 2012-06-28 Fan Yang , Fanming Qu , Jie Shen , Yue Ding , Jun Chen , Zhongqing Ji , Guangtong Liu , Jie Fan , Changli Yang , Liang Fu , Li Lu

Nontrivial topological superconductivity has received enormous research attentions due to its potential for diverse applications in topological quantum computing. The intrinsic issue concerning the correlation between a topological…

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