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Molecular hydrogen in the bulk of graphite has been studied by path-integral molecular dynamics simulations. Finite-temperature properties of H_2 molecules adsorbed between graphite layers were analyzed in the temperature range from 300 to…

Materials Science · Physics 2011-08-12 Carlos P. Herrero , Rafael Ramirez

Evidence is accumulating for the crucial role of a solid's free electrons in the dynamics of solid-liquid interfaces. Liquids induce electronic polarization and drive electric currents as they flow; electronic excitations, in turn,…

Mesoscale and Nanoscale Physics · Physics 2023-06-27 Xiaoqing Yu , Alessandro Principi , Klaas-Jan Tielrooij , Mischa Bonn , Nikita Kavokine

We have observed periodically repeated steps in the resistance vs. temperature characteristics of doped Highly Oriented Pyrolytic Graphite and exfoliated doped multi-layer graphene. The observations consist of a series of regularly spaced…

Superconductivity · Physics 2013-07-03 Grover Larkins , Yuriy Vlasov , Kiar Holland

Water at solid surfaces is key for many processes ranging from biological signal transduction to membrane separation and renewable energy conversion. However, under realistic conditions, which often include environmental and surface charge…

Graphane is a quasi-two-dimensional material consisting of a single layer of fully hydrogenated graphene, with a C:H ratio of 1. We study nuclear quantum effects in the so-called chair-graphane by using path-integral molecular dynamics…

Chemical Physics · Physics 2020-08-24 Carlos P. Herrero , Rafael Ramirez

Graphite, as a well-known carbon-based solid, is a paradigmatic example of the so-called van der Waals layered materials, which display a large anisotropy in their physical properties. Here we study quantum effects in structural and elastic…

Materials Science · Physics 2021-09-16 Carlos P. Herrero , Rafael Ramirez

The conductance through a quantum point contact created by a sharp and hard metal tip on the graphite surface has features which to our knowledge have not been encountered so far in metal contacts or in nanowires. In this paper we first…

Materials Science · Physics 2009-10-31 C. Kilic , H. Mehrez , S. Ciraci

We examine the applicability of various model profiles for the liquid/vapor interface by X-ray reflectivities on water and ethanol and their mixtures at room temperature. Analysis of the X-ray reflecivities using various density profiles…

Soft Condensed Matter · Physics 2014-04-30 Wei Bu , Doseok Kim , David Vaknin

This work describes the development of a third-generation charge optimized many-body (COMB3) potential for Al-C and its application to the investigation of aluminum/graphene nanostructures. In particular, the new COMB3 potential was used to…

Materials Science · Physics 2019-12-04 Difan Zhang , Alexandre F. Fonseca , Tao Liang , Simon R. Phillpot , Susan B. Sinnott

We discuss Molecular Dynamics (MD) computer simulations of tetracosane (C24H50) monolayer physisorbed onto a graphite surface. The alkane molecules are simulated with explicit hydrogens, and the graphite substrate is represented as an…

Materials Science · Physics 2008-10-29 L. Firlej , B. Kuchta , M. W. Roth , M. J. Connolly , Carlos Wexler

An anisotropic interlayer potential that can accurately describe the van der Waals interaction of the water-graphene interface is presented. The force field is benchmarked against the many-body dispersion-corrected density functional…

Chemical Physics · Physics 2022-12-22 Zhicheng Feng , Yuanpeng Yao , Jianxin Liu , Bozhao Wu , Ze Liu , Wengen Ouyang

Accurate estimation of surface wettability for various degrees of hydrophobicity becomes increasingly important in the molecular design of membrane. In this paper, we develop simple yet physically realistic model for estimating contact…

Soft Condensed Matter · Physics 2018-01-08 Meysam Makaremi , Myung S. Jhon , Meagan S. Mauter , Lorenz T. Biegler

Hydrogen adsorption by graphite is examined by classical molecular dynamics simulation using a modified Brenner REBO potential. Such interactions are typical in chemical sputtering experiments, and knowledge of the fundamental behavior of…

Soft Condensed Matter · Physics 2009-11-11 A. Ito , H. Nakamura

Understanding interfacial heat transfer between polymers and water is crucial for the design of biomaterials, drug delivery platforms, and nanofluidic systems. In this study, we employed all atom molecular dynamics (MD) simulations to…

Soft Condensed Matter · Physics 2025-12-04 Shadi Babaei , Yekta Cheraghali , Claire Loison , Ali Rajabpour , Samy Merabia

We report a study on the relationship between structure and electron transport properties of nanoscale graphene/pentacene interfaces. We fabricated graphene/pentacene interfaces from 10-30 nm thick needle-like pentacene nanostructures down…

Mesoscale and Nanoscale Physics · Physics 2023-05-05 Michel Daher Mansour , Jacopo Oswald , Davide Beretta , Michael Stiefe , Roman Furrer , Michel Calame , Dominique Vuillaume

Thermal properties of graphene monolayers are studied by path-integral molecular dynamics (PIMD) simulations, which take into account the quantization of vibrational modes in the crystalline membrane, and allow one to consider anharmonic…

Materials Science · Physics 2017-09-18 Carlos P. Herrero , Rafael Ramirez

In order to realise the potential of graphene nanocomposites it is vital to control the degree of dispersion and achieve a strong graphene polymer interface. Herein, we developed a facile grafting to functionalisation approach for graphene…

Molecular-level insight into interfacial water at buried electrode interfaces is essential in elucidating many phenomena of electrochemistry, but spectroscopic probing of the buried interfaces remains challenging. Here, using…

Modification of surfaces to enable dropwise condensation is a promising approach for achieving high condensation rates. In this work, we present an experimental study on condensation of water on copper surfaces coated with an ultrathin, 5…

We demonstrate the direct dry transfer of large area Chemical Vapor Deposition graphene to several polymers (low density polyethylene, high density polyethylene, polystyrene, polylactide acid and…