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Related papers: Chain End Mobilities in Polymer Melts - A Computat…

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Polymer-like structures are ubiquitous in nature and synthetic materials. Their configurational and migration properties are often affected by crowded environments leading to non-thermal fluctuations. Here, we study an ideal Rouse chain in…

Soft Condensed Matter · Physics 2024-03-12 Pietro Luigi Muzzeddu , Andrea Gambassi , Jens-Uwe Sommer , Abhinav Sharma

While the dynamics of polymer chains in equilibrium media is well understood by now, the polymer dynamics in active non-equilibrium environments can be very different. Here we study the dynamics of polymers in a viscous medium containing…

Soft Condensed Matter · Physics 2017-06-23 Jaeoh Shin , Andrey G. Cherstvy , Won Kyu Kim , Vasily Zaburdaev

In this paper we establish a new efficient method for simulating polymer-solvent systems which combines a lattice Boltzmann approach for the fluid with a continuum molecular dynamics (MD) model for the polymer chain. The two parts are…

Soft Condensed Matter · Physics 2009-10-31 Patrick Ahlrichs , Burkhard Duenweg

There have been increasing reports that the diffusion coefficient of macromolecules depends on time and fluctuates randomly. Here, a novel method to elucidate the fluctuating diffusivity from trajectory data is developed. The time-averaged…

Statistical Mechanics · Physics 2017-10-25 Tomoshige Miyaguchi

The non-equilibrium structural and dynamical properties of flexible polymers confined in a square microchannel and exposed to a Poiseuille flow are investigated by mesoscale simulations. The chain length and the flow strength are…

Soft Condensed Matter · Physics 2009-11-13 L. Cannavacciuolo , R. G. Winkler , G. Gompper

We generalize a recently investigated lattice model of semiflexible polymers formed under equilibrium polymerization in a solution and conduct a comprehensive investigation of its melting properties. The model is characterized by six…

Condensed Matter · Physics 2007-05-23 Sagar S. Rane , P. D. Gujrati

The reptation concept in polymer dynamics is studied for model chains with added stiffness. The main idea of a chain diffusing inside a tube can be transferred from fully flexible chains. However, the picture, which renormalizes the chain…

Soft Condensed Matter · Physics 2007-05-23 Roland Faller , Florian Mueller-Plathe

Based on a recently established formalism (U. Ebert, J. Stat. Phys. 82, 183 (1996)) we analyze the diffusive motion of a long polymer in a quenched random medium. The medium is modeled by a frozen semidilute polymer system. In the framework…

Statistical Mechanics · Physics 2015-06-25 Stefan Mueller

The predictions of the polymer mode coupling theory for the finite size corrections to the transport coefficients of entangled polymeric systems are tested in comparisons with various experimental data. It is found that quantitative…

Condensed Matter · Physics 2009-10-30 Matthias Fuchs , Kenneth S. Schweizer

Using extensive computer simulations, the behavior of the structural modes --- more precisely, the eigenmodes of a phantom Rouse polymer --- are characterized for a polymer in the three-dimensional repton model, and are used to study the…

Soft Condensed Matter · Physics 2015-03-18 Gerard T. Barkema , Debabrata Panja , J. M. J. van Leeuwen

We study analytically the tracer particle mobility in single-file systems with distributed friction constants. Our system serves as a prototype for non-equilibrium, heterogeneous, strongly interacting Brownian systems. The long time…

Statistical Mechanics · Physics 2015-06-18 Michael A. Lomholt , Tobias Ambjornsson

Synthetic polymers have a distribution of chain lengths which can be characterized by dispersity, D. Macroscopic properties of polymers are influenced by chain mobility in the melt and manipulating D can significantly impact these…

Chemical Physics · Physics 2024-09-30 Taofeek Tejuosho , Sohil Kollipara , Sumant Patankar , Janani Sampath

In this paper, we investigate the microscopic dynamics of a polymer of length $N$ translocating through a narrow pore. Characterization of its purportedly anomalous dynamics has so far remained incomplete. We show that the polymer dynamics…

Soft Condensed Matter · Physics 2007-07-25 Debabrata Panja , Gerard T. Barkema , Robin C. Ball

We study folding in 16-monomer heteropolymers on the square lattice. For a given sequence, thermodynamic properties and stability of the native state are unique. However, the kinetics of folding depends on the model of dynamics adopted for…

Statistical Mechanics · Physics 2009-10-31 Trinh Xuan Hoang , Marek Cieplak

We address the general question of how the molecular weight dependence of chain dynamics in unentangled polymers is modified by blending. By dielectric spectroscopy we measure the normal mode relaxation of polyisoprene in blends with a slow…

Soft Condensed Matter · Physics 2012-02-24 Silvia Arrese-Igor , Angel Alegria , Angel J. Moreno , Juan Colmenero

The transport of polymers with folded configurations across membrane pores is investigated theoretically by analyzing simple discrete stochastic models. The translocation dynamics is viewed as a sequence of two events: motion of the folded…

Statistical Mechanics · Physics 2009-11-13 Stanislav Kotsev , Anatoly B. Kolomeisky

We study the long-time asymptotical behavior of the survival probability P_t of a tagged monomer of an infinitely long Rouse chain in presence of two fixed absorbing boundaries, placed at x = \pm L. Mean-square displacement of a tagged…

Statistical Mechanics · Physics 2008-01-28 G. Oshanin

We present a unified scaling description for the dynamics of monomers of a semiflexible chain under good solvent condition in the free draining limit. We consider both the cases where the contour length $L$ is comparable to the persistence…

Biological Physics · Physics 2015-06-18 Aiqun Huang , Aniket Bhattacharya , Kurt Binder

Many researchers have been encouraged to describe the dynamics of chromosomal loci in chromatin using the classical Rouse model of polymer dynamics by the agreement between the measured mean square displacement (MSD) versus time of…

The Langevin dynamics of a self - interacting chain embedded in a quenched random medium is investigated by making use of the generating functional method and one - loop (Hartree) approximation. We have shown how this intrinsic disorder…

Statistical Mechanics · Physics 2007-05-23 Gabriele Migliorini , Vakhtang G. Rostiashvili , Thomas A. Vilgis
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