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We have obtained experimentally the low frequency Raman spectra of p-dihlorbenzol nanoparticles. Nanoparticle sizes are determined with the help of electron microscope. It was found that in the lattice vibration spectra from 70 nm the…

Mesoscale and Nanoscale Physics · Physics 2010-04-23 M. A. Korshunov

Using Raman scattering, the solid solution nanoparticles of paradibrombenzol/paradihlorbenzol are investigated. It is found that in a spectrum of nanoparticles of solid solution frequencies of spectral lines are reduced in comparison with…

Mesoscale and Nanoscale Physics · Physics 2009-10-21 M. A. Korshunov

P-dibromobenzene nanoparticles in a case of paradihlorbenzol molecules have been synthesized. Raman spectrums of these nanoparticles are measured. At diffusion of molecules of paradihlorbenzol in a pdibromobenzene nanoparticle solid…

Mesoscale and Nanoscale Physics · Physics 2009-10-21 M. A. Korshunov

In crystalline nanoparticles the Raman peak is downshifted with respect to the bulk material and has asymmetric broadening. These effects are straightly related to the finite size of nanoparticles, giving the perspective to use the Raman…

Mesoscale and Nanoscale Physics · Physics 2018-09-05 S. V. Koniakhin , O. I. Utesov , I. N. Terterov , A. V. Siklitskaya , D. Solnyshkov , A. G. Yashenkin

Raman spectroscopy is used to probe the structure and electronic properties of nanotubes dispersed in a liquid phase. We show that the radial breathing modes are upshifted in suspensions due to the molecular pressure of the solvent. On the…

Other Condensed Matter · Physics 2016-08-16 Nicolas Izard , Alain Pénicaud , Eric Anglaret

We measured low-frequency Raman spectra of paradibromobenzene nanoparticles. With the reduction of the nanoparticles size frequencies of lines become smaller and the doubling of the most intensive lines takes place. Additional lines with…

Mesoscale and Nanoscale Physics · Physics 2013-11-28 M. A. Korshunov

The mixed crystal of a para-dibromobenzene with a para-chloronitrobenzene is investigated at concentration of components from 0% up to 60% of a para-chloronitrobenzene by the method of Low-Frequency Raman spectroscopy. It is shown, that in…

Optics · Physics 2007-05-23 M. A. Korshunov

Distribution of centrosymmetrical molecules of an impurity (p-diclorobenzene) in monocrystals of solid solutions in two different matrixes with centrosymmetrical (p-dibrombenzene) and noncentrosymmetrical (p-bromchlorbenzene) molecules by…

Optics · Physics 2007-05-23 M. A. Korshunov

Modern materials science requires efficient processing and characterization techniques for low dimensional systems. Raman spectroscopy is an important non-destructive tool, which provides enormous information on these materials. This…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 A. Singha , P. Dhar , Anushree Roy

{\gamma}-graphdiyne is a 2D carbon structure beyond graphene: it is formed by sp and sp2 carbon atoms organized as hexagonal rings connected by linear links, and it is predicted to be a semiconductor. The lateral confinement of…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Patrick Serafini , Alberto Milani , Matteo Tommasini , Chiara Castiglioni , Carlo S. Casari

The interest of micro and tip-enhanced Raman spectroscopy to analyze nanosized and nanostructured materials, chiefly semiconductors, oxides and pristine or functionalized carbon nanotubes, is reviewed at the light of the contributions to…

Materials Science · Physics 2007-06-07 Philippe Colomban , Gwénael Gouadec

Raman spectrums of nanoparticles of a p-dibromobenzene with size of 300 nanometers and 50 nanometers are measured. It is found that frequencies of lines of stretching vibrations of C-Br at reduction of the sizes of nanoparticles below 300…

Mesoscale and Nanoscale Physics · Physics 2009-10-21 M. A. Korshunov

Microscopic description of Raman spectra in nanopowders of nonpolar crystals is accomplished by developing the theory of disorder-induced broadening of optical vibrational eigenmodes. Analytical treatment of this problem is performed, and…

Mesoscale and Nanoscale Physics · Physics 2020-11-25 Oleg I. Utesov , Andrey G. Yashenkin , Sergei V. Koniakhin

For many 2D materials, optical and Raman spectra are richly structured, and convey information on a range of parameters including nanosheet size and defect content. By contrast, the equivalent spectra for h-BN are relatively simple, with…

A theoretical model supported by experimental results explains the dependence of the Raman scattering signal on the evolution of structural parameters along the amorphization trajectory of polycrystalline graphene systems. Four parameters…

Investigation of organic molecular films by a method Raman of a spectroscopy is carried out. It is shown, that values of frequencies of lines in a spectrum of the lattice oscillations of the molecular films are depressed in comparison with…

Optics · Physics 2007-05-23 M. A. Korshunov

Using a method of a Raman effect of light the heterodiffusion in molecular crystals is investigated by the example of p-dichlorobenzene in a p-dibromobenzene. The installation diagram and a procedure of a determination of diffusivities…

Optics · Physics 2007-05-23 M. A. Korshunov

Influence of decrease of the sizes of crystallites of para-dichlorbenzol on Raman spectrums is studied. Lattice oscillations frequencies are calculated. On this basis the modification of lattice parameters for particles smaller than 5$\mu $…

Optics · Physics 2007-05-23 M. A. Korshunov

A double nanohole in a metal film was used to trap nanoparticles (20 nm diameter) and simultaneously record their Raman spectrum using the trapping laser as the excitation source. This allowed for the identification of characteristic Stokes…

Optics · Physics 2015-10-28 Steven Jones , Ahmed A. Al Balushi , Reuven Gordon

The vibrational spectroscopy of semiconductor nanostructures can provide important information on their structure. In this work, experimental Raman and infrared spectra are compared with vibrational spectra of CdSe/CdS core/shell…

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