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We represent the free energy functional by a diagrammatic series with tensorial coefficients indexed by powers of length scale. For hard cores, we obtain Percus' exact functional in one dimension and the Kierlik-Rosinberg form of…

Soft Condensed Matter · Physics 2015-05-27 Gavin Leithall , Matthias Schmidt

The mass density distribution of Newtonian self-gravitating systems is studied analytically in field theoretical method. Modeling the system as a fluid in hydrostatical equilibrium, we apply Schwinger's functional derivative on the average…

Astrophysics of Galaxies · Physics 2021-07-21 Yang Zhang , Qing Chen , Shuguang Wu

Ground-state Kohn-Sham density functional theory provides, in principle, the exact ground-state energy and electronic spin-densities of real interacting electrons in a static external potential. In practice, the exact density functional for…

Chemical Physics · Physics 2022-07-11 Aaron D. Kaplan , Mel Levy , John P. Perdew

Hard-sphere fluids confined between parallel plates a distance $D$ apart are studied for a wide range of packing fractions, including also the onset of crystallization, applying Monte Carlo simulation techniques and density functional…

Statistical Mechanics · Physics 2011-10-10 Debabrata Deb , Alexander Winkler , Mohammad Hossein Yamani , Martin Oettel , Peter Virnau , Kurt Binder

A recently proposed "DFT+dispersion" treatment (Rajchel et al., Phys. Rev. Lett., 2010, 104, 163001) is described in detail and illustrated by more examples. The formalism derives the dispersion-free density functional theory (DFT)…

Electrostatic correlations between ions dissolved in water are known to impact their transport properties in numerous ways, from conductivity to ion selectivity. The effects of these correlations on the solvent itself remain, however, much…

Soft Condensed Matter · Physics 2024-01-31 Paul Robin

It is shown that the DFT exchange and correlation functionals satisfy an expression that couples exchange and correlation functionals and functional derivatives evaluated at three different densities and for two particle numbers. This…

Materials Science · Physics 2015-05-30 Daniel P. Joubert

Parametric correlations are studied in several classes of covariant density functional theories (CDFTs) using a statistical analysis in a large parameter hyperspace. In the present manuscript, we investigate such correlations for two…

Nuclear Theory · Physics 2020-03-17 A. Taninah , S. E. Agbemava , A. V. Afanasjev , P. Ring

We introduce a density functional formalism to study the ground-state properties of strongly-correlated dipolar and ionic ultracold bosonic and fermionic gases, based on the self-consistent combination of the weak and the strong coupling…

In this article we obtain a fundamental measure functional for the model of aligned hard hexagons in the plane. Our aim is not just to provide a functional for a new, admittedly academic, model, but to investigate the structure of…

Soft Condensed Matter · Physics 2007-11-26 Jose A. Capitan , Jose A. Cuesta

We show that generalized spherical harmonics are well suited for representing the space and orientation molecular density in the resolution of the molecular density functional theory. We consider the common system made of a rigid solute of…

Chemical Physics · Physics 2017-10-11 Lu Ding , Maximilien Levesque , Daniel Borgis , Luc Belloni

Dynamical signatures are known to precede jamming in hard-particle systems, but static structural signatures have proven more elusive. The observation that compressing hard-particle packings towards jamming causes growing hyperuniformity…

Statistical Mechanics · Physics 2016-09-21 Steven Atkinson , Frank H. Stillinger , Salvatore Torquato

The standard model of classical Density Functional Theory for pair potentials consists of a hard-sphere functional plus a mean-field term accounting for long ranged attraction. However, most implementations using sophisticated Fundamental…

Computational Physics · Physics 2021-01-04 James F. Lutsko , Cédric Schoonen

Standard approximations for the exchange-correlation functional are known to deviate from linear dependence of the energy on the electron and spin numbers (in -space). Violation of this flat-plane condition underlies the failure of all…

Classical Physics · Physics 2013-10-28 Ali M. Malek , Robert Balawender

This is a comprehensive review of the strong-interaction limit of density functional theory. It covers the derivation of the limiting strictly correlated electrons (SCE) functional from exact Hohenberg-Kohn DFT, basic aspects of SCE physics…

Chemical Physics · Physics 2022-02-22 Gero Friesecke , Augusto Gerolin , Paola Gori-Giorgi

The recently developed "internal" Density Functional Theory provides an existence theorem for a local potential that contains the center-of-mass correlations effects. The knowledge of the corresponding energy functional would provide a much…

Nuclear Theory · Physics 2015-06-05 Jeremie Messud

We propose a simple and accurate method for computing analytically the mass correlation function for cold dark matter and scale-free models that fits N-body simulations over a range that extends from the linear to the strongly non-linear…

Astrophysics · Physics 2009-10-31 R. R. Caldwell , Roman Juszkiewicz , Paul J. Steinhardt , Francois Bouchet

By combining aspects of the coherent and self intermediate scattering functions, measured by dynamical light scattering on a suspension of hard sphere-like particles, we show that the arrest of particle number density fluctuations spreads…

Soft Condensed Matter · Physics 2015-05-13 W. van Megen , V. A. Martinez , G. Bryant

The complex nature of electron-electron correlations is made manifest in the very simple but non-trivial problem of two electrons confined within a sphere. The description of highly non-local correlation and self-interaction effects by…

Other Condensed Matter · Physics 2016-08-16 J. Jung , P. García-González , J. E. Alvarellos , R. W. Godby

We introduced a new electron density n({\epsilon}) by projecting the spatial electron density n(r) onto the energy coordinate {\epsilon} defined with the external potential \upsion (r) of interest. Then, a density functional theory (DFT)…

Chemical Physics · Physics 2018-02-20 Hideaki Takahashi
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