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Absorption, excitation and emission spectra of cadmium fluoride crystals doped with rare-earth ions were investigated. In contrast to alkaline-earth fluorides the absorption spectra due to 4f - 5d transitions of Ce$^{3+}$, Pr$^{3+}$ and…

Materials Science · Physics 2015-06-17 Evgeny Radzhabov , Roman Shendrik

We have studied the absorption spectra of x-ray irradiation-induced Ce2+ and Pr2+ ions in crystals of alkaline-earth fluorides. We have calculated absorption spectra of divalent praseodymium ions in SrF2 crystals doped with Pr2+ for the…

Materials Science · Physics 2015-07-13 R. Shendrik , A. S. Myasnikova , E. A. Radzhabov , A. I. Nepomnyashchikh

Time-resolved emission, excitation as well as emission decay curves of CaF$_2$, SrF$_2$, BaF$_2$ doped with HoF$_3$ were investigated. Most intensive emission bands near 168 nm, having long decay time, belong to spin-forbidden transitions…

Materials Science · Physics 2012-11-05 E. A. Radzhabov , V. Nagirnyi , A. I. Nepomnyashchikh

We use neutron scattering to study the Pr$^{3+}$ crystalline electric field (CEF) excitations in the filled skutterudite PrOs$_4$As$_{12}$. By comparing the observed levels and their strengths under neutron excitation with the theoretical…

Strongly Correlated Electrons · Physics 2008-10-22 Songxue Chi , Pengcheng Dai , T. Barnes , H. J. Kang , J. W. Lynn , R. Bewley , F. Ye , M. B. Maple , Z. Henkie , A. Pietraszko

We report studies of the Yb$^{3+}$ site distribution in Er$^{3+}$ co-doped upconverting alkaline earth fluoride nanoparticles using high-resolution absorption measurements. Similar to bulk crystals, Yb$^{3+}$ single ion cubic (O$_h$), and…

Materials Science · Physics 2020-04-30 Sangeetha Balabhadra , Michael F. Reid , Vladimir Golovko , Jon-Paul R. Wells

CaF$_2$:Yb$^{2+}$ and SrF$_2$:Yb$^{2+}$ crystals have been investigated by a two-color UV + IR transient photoluminescence enhancement technique. The enhancement gives information about both changes in internal energy levels of the excitons…

Materials Science · Physics 2015-03-19 P. S. Senanayake , J. P. R. Wells , M. F. Reid , G. Berden , A. Meijerink , R. J. Reeves

We investigate the intermolecular interactions between laser-cooled CaF and Ca, in their ground and excited electronic states, aiming to understand atom-exchange reaction pathways. Using state-of-the-art \textit{ab initio} quantum chemistry…

Atomic Physics · Physics 2025-10-28 Dibyendu Sardar , John L. Bohn

We study from first principles two lanthanum silicate nitride compounds, LaSi$_{3}$N$_{5}$ and La$_{3}$Si$_{6}$N$_{11}$, pristine as well as doped with Ce$^{3+}$ ion, in view of explaining their different emission color, and characterising…

Materials Science · Physics 2017-09-04 Yongchao Jia , Anna Miglio , Samuel Poncé , Xavier Gonze , Masayoshi Mikami

We use inelastic neutron scattering to study the crystalline electric field (CEF) excitations of Ce$^{3+}$ in CeFeAsO$_{1-x}$F$_{x}$($x=0,0.16$). For nonsuperconducting CeFeAsO, the Ce CEF levels have three magnetic doublets in the…

Photoluminescence, thermally stimulated luminescence (TSL) and EPR characteristics of the Ce3+ doped single crystals of multicomponent Y1Lu2GaxAl5-xO12 and Lu3GaxAl5-xO12 garnets with different Ga contents (x = 0, 1, 2, 3, 4, 5) excited in…

The photo-fragmentation spectrum of protonated fluorene has been recorded in the visible spectral region, largely red shifted as compared to the first excited state absorption of neutral fluorene. The spectrum shows two different…

Atomic and Molecular Clusters · Physics 2015-06-03 Ivan Alata , Michel Broquier , Claude Dedonder , Christophe Jouvet , Ernesto Marceca

We report inelastic neutron scattering measurements of crystal field transitions in PrFeAsO, PrFeAsO0.87F0.13, and NdFeAsO0.85F0.15. Doping with fluorine produces additional crystal field excitations, providing evidence that there are two…

We have studied the magnetism of the Pr3+ ions in PrFeAsO_1-xF_x (x = 0; 0.15) and its interaction with the Fe magnetic order (for x = 0). Specific heat data confirm the presence of a first excited crystal electric field (CEF) level around…

Superconductivity · Physics 2015-06-05 U. Stockert , N. Leps , L. Wang , G. Behr , S. Wurmehl , B. Büchner , R. Klingeler

In this paper results of scintillation properties measurements of pure and Ce3+-doped strontium fluoride crystals are presented. We measure light output, scintillation decay time profile and temperature stability of light output. X-ray…

Materials Science · Physics 2016-06-07 R. Shendrik , E. A. Radzhabov , A. I. Nepomnyashchikh

The crystalline electric field (CEF) energy level scheme of the heavy fermion superconductor CeCoIn_5 has been determined by means of inelastic neutron scattering (INS). Peaks observed in the INS spectra at 8 meV and 27 meV with incident…

Optical absorption spectra of Cr$^{3+}$-Cr$^{2+}$ pair center in KZnF$_{3}$:Cr$^{3+}$,Cr$^{2+}$ crystal were investigated in wide temperature range. Broad band at 30800 cm$^{-1}$ is attributed to cation-cation (e_g)-electron transfer…

Strongly Correlated Electrons · Physics 2009-10-31 M. V. Eremin , S. I. Nikitin , S. Yu. Prosvirnin , N. I. Silkin , R. V. Yusupov

Erbium ions in crystals show considerable promise for the technologies that will form the backbone of future networked quantum information technology. Despite advances in leveraging erbium's fibre-compatible infrared transition for…

The scattering of conduction electrons by crystalline electric field (CEF) excitations may enhance their effective quasiparticle mass similar to scattering from phonons. A wellknown example is Pr metal where the isotropic exchange…

Strongly Correlated Electrons · Physics 2009-11-13 G. Zwicknagl , P. Thalmeier , P. Fulde

We apply moderate-high-energy inelastic neutron scattering (INS) measurements to investigate Yb$^{3+}$ crystalline electric field (CEF) levels in the triangular spin-liquid candidate YbMgGaO$_4$. Three CEF excitations from the ground-state…

We show in this article the improvements which can be obtained in the description of the luminescence properties of Pr3+ doped materials by using an extension of the Judd-Ofelt theory in order to relax some strong selection rules and…

Atomic Physics · Physics 2026-04-24 Maxence Lepers , G. Hovhannesyan , Y. Guyot , R. Moncorgé , M. Velazquez
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