Electronic excited state of protonated aromatic molecules: protonated Fluorene
Atomic and Molecular Clusters
2015-06-03 v1 Chemical Physics
Abstract
The photo-fragmentation spectrum of protonated fluorene has been recorded in the visible spectral region, largely red shifted as compared to the first excited state absorption of neutral fluorene. The spectrum shows two different vibrational progressions, separated by 0.19 eV that are assigned to the absorption of two isomers. As in protonated linear PAHs, comparison with ab-initio calculations indicates that the red shift is due to the charge transfer character of the excited state.
Keywords
Cite
@article{arxiv.1111.7305,
title = {Electronic excited state of protonated aromatic molecules: protonated Fluorene},
author = {Ivan Alata and Michel Broquier and Claude Dedonder and Christophe Jouvet and Ernesto Marceca},
journal= {arXiv preprint arXiv:1111.7305},
year = {2015}
}