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We investigated the high-order harmonic generation (HHG) process of diatomic molecular ion $\mathrm{H}_2^+$ in non-Born-Oppenheimer approximations. The corresponding three-dimensional time-dependent Schr\"odinger equation is solved with…

Atomic Physics · Physics 2017-02-28 Mu-Zi Li , Guang-Rui Jia , Xue-Bin Bian

The attosecond ultrafast ionization dynamics of correlated two- or many-electron systems have, so far, been mainly addressed investigating atomic systems. In the case of single ionization, it is well known that electron-electron correlation…

Efficient computation of molecular energies is an exciting application of quantum computing for quantum chemistry, but current noisy intermediate-scale quantum (NISQ) devices can only execute shallow circuits, limiting existing variational…

We introduce and demonstrate a new approach to measuring coherent electron wave packets using high-harmonic spectroscopy. By preparing a molecule in a coherent superposition of electronic states, we show that electronic coherence opens…

Chemical Physics · Physics 2014-07-09 P. M. Kraus , S. B. Zhang , A. Gijsbertsen , R. R. Lucchese , N. Rohringer , H. J. Wörner

Using the recently developed Coulomb Quantum Orbit Strong-Field Approximation (CQSFA), we perform a systematic analysis of several features encountered in above-threshold ionization (ATI) photoelectron angle-resolved distributions (PADs),…

Atomic Physics · Physics 2017-10-11 A. S. Maxwell , A. Al-Jawahiry , T. Das , C. Figueira de Morisson Faria

Outer sphere electron transfer rates can be calculated from simulation data by sampling the equilibrium statistics of the canonical reaction coordinate -- the vertical energy gap. For these calculations, electron transfer is typically…

Chemical Physics · Physics 2025-09-23 Yoonjae Park , Adam P. Willard

We characterize the effect of quantum interference on the line shapes and measured line positions in atomic spectra. These effects, which occur when the excited state splittings are of order the excited state line widths, represent an…

Strong-field photoelectron momentum imaging of the prototypical biomolecule indole was disentangled in a combined experimental and computational approach. Experimentally, strong control over the molecules enabled the acquisition of…

Atomic Physics · Physics 2021-02-03 Joss Wiese , Jolijn Onvlee , Sebastian Trippel , Jochen Küpper

We present a theoretical study of the influence of resonant enhancement on quantum path dynamics in the generation of harmonics above and below the ionization threshold in helium. By varying the wavelength and intensity of the driving field…

Atomic Physics · Physics 2015-06-23 Seth Camp , Kenneth J. Schafer , Mette B. Gaarde

We investigate quantum radiation reaction in laser-electron interactions across different energy and intensity regimes. Using a fully quantum approach which also accounts exactly for the effect of the strong laser pulse on the electron…

High Energy Physics - Phenomenology · Physics 2016-03-17 Victor Dinu , Chris Harvey , Anton Ilderton , Mattias Marklund , Greger Torgrimsson

We explore the quantum dynamics of heteronuclear atomic collisions in waveguides and demonstrate the existence of a novel mechanism for the resonant formation of polar molecules. The molecular formation probabilities can be tuned by…

Atomic Physics · Physics 2015-05-13 Vladimir S. Melezhik , Peter Schmelcher

Quantum interference is typically detected through the dependence of the interference signal on certain parameters (path length, Aharonov-Bohm flux, etc.), which can be varied in a controlled manner. The destruction of interference by a…

Mesoscale and Nanoscale Physics · Physics 2020-07-15 Iliya Esin , Alessandro Romito , Yuval Gefen

The generation and manipulation of entanglement between isolated particles has precipitated rapid progress in quantum information processing. Entanglement is also known to play an essential role in the optical properties of atomic…

Quantum Physics · Physics 2018-05-16 Gabriel Araneda , Daniel B. Higginbottom , Lukáš Slodička , Yves Colombe , Rainer Blatt

Quantum states are described by wave functions whose phases cannot be directly measured, but which play a vital role in quantum effects such as interference and entanglement. The loss of the relative phase information, termed decoherence,…

Chemical Physics · Physics 2019-12-20 Jia Chen , Cong Hu , John F. Stanton , Stephen Hill , Hai-Ping Cheng , Xiao-Guang Zhang

We experimentally observe a new type of quantum-path interference, in two-dimensions (2D-QPI), in high-harmonic generation (HHG) driven by an orthogonally-polarised highly-bichromatic field. This regime is marked by comparable intensities…

Attosecond science has opened up new frontiers in our understanding of processes happening on the intrinsic timescale of electrons. The ability to manipulate and observe phenomena at the attosecond level has yielded groundbreaking insights…

Quantum Physics · Physics 2024-11-08 Lidice Cruz-Rodriguez , Diptesh Dey , Antonia Freibert , Philipp Stammer

Full control over the dynamics of interacting, indistinguishable quantum particles is an important prerequisite for the experimental study of strongly correlated quantum matter and the implementation of high-fidelity quantum information…

For a molecule, the two-center interference and the molecular scattering phase of the electron are important for almost all the processes that may occur in a laser field. In this study, we investigate their effects in the transfer of linear…

Atomic Physics · Physics 2018-12-19 Hao Liang , Mu-Xue Wang , Xiang-Ru Xiao , Qihuang Gong , Liang-You Peng

Ion channels are protein structures that facilitate the selective passage of ions across the membrane cells of living organisms. They are known for their high conductance and high selectivity. The precise mechanism between these two…

Biological Physics · Physics 2025-02-12 Mateusz Polakowski , Miłosz Panfil

The synthesis of molecular magnets has undergone rapid progress in recent years. Each of the identical molecular units can contain as few as two and up to several dozens of paramagnetic ions (spins). Although these materials appear as…

Strongly Correlated Electrons · Physics 2009-11-11 J. Schnack