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When molecules interact with intense light sources of femtosecond or shorter duration the rotational degrees of freedom are frozen during the response to the strong nonperturbative interaction. We show how the frozen degrees of freedom…

Atomic Physics · Physics 2007-09-25 C. B. Madsen , A. S. Mouritzen , T. K. Kjeldsen , L. B. Madsen

We study the signature of two-center interferences in molecular high-order harmonic spectra, with an emphasis on the spectral phase. With the help of both ab initio computations based on the time-dependent Schr\"odinger equation and the…

Present photoionization experiments cannot measure molecular frame photoelectron angular distributions (MFPAD) from the outermost valence electrons of molecules. We show that details of the MFPAD can be retrieved with high-order harmonics…

Atomic Physics · Physics 2009-05-24 Anh-Thu Le , R. R. Lucchese , M. T. Lee , C. D. Lin

The many-body state of carriers confined in a quantum dot is controlled by the balance between their kinetic energy and their Coulomb correlation. In coupled quantum dots, both can be tuned by varying the inter-dot tunneling and…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Massimo Rontani , Filippo Troiani , Ulrich Hohenester , Elisa Molinari

We explore the laser-induced ionization dynamics of N2 and CO2 molecules subjected to a few-cycle, linearly polarized, 800\,nm laser pulse using effective two-dimensional single active electron time-dependent quantum simulations. We show…

Atomic Physics · Physics 2012-10-02 Michel Peters , Tung Nguyen-Dang , Eric Charron , Arne Keller , Osman Atabek

We use a quantum trajectory-based semi-classical method to account for Coulomb interaction between the photoelectron and the parent ion in the classically forbidden, sub-barrier region during strong-field tunneling ionization processes. We…

Atomic Physics · Physics 2017-11-21 Tian-Min Yan , D. Bauer

Fundamental understanding of interatomic forces in molecules must emerge from quantum mechanics, yet widely used empirical force fields rely on simplified mechanistic approximations that often fail to capture the complexity of many-body…

We report the experimental observation of quantum interference in the nuclear wave-packet dynamics driving ultrafast excitation-energy transfer in argon dimers below the threshold of interatomic Coulombic decay (ICD). Using time-resolved…

Atomic and Molecular Clusters · Physics 2023-07-05 Meng Han , Jacqueline Fedyk , Jia-Bao Ji , Victor Despré , Alexander I. Kuleff , Hans Jakob Wörner

In strong-field ionization interferences between electron trajectories create a variety of interference structures in the final momentum distributions. Among them, the interferences between electron pathways that are driven directly to the…

We survey the inclusion of interferometric elements in nonlinear spectroscopy performed with quantum light. Controlled interference of electromagnetic fields coupled to matter can induce constructive or destructive contributions of…

Quantum Physics · Physics 2021-06-16 Shahaf Asban , Konstantin E. Dorfman , Shaul Mukamel

Cathodoluminescence spectroscopy has recently emerged as a novel platform for nanoscale control of nonclassical features of light. Here, we propose a theoretical model for cathodoluminescence from a multi-level quantum emitter. Employing a…

Quantum Physics · Physics 2025-02-03 H. B. Crispin , N. Talebi

We study the effects of electron-electron correlations and confinement potential on the far-infrared spectrum of a lateral two-electron quantum dot molecule by exact diagonalization. The calculated spectra directly reflect the lowered…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. Marlo , A. Harju , R. M. Nieminen

We developed a general theoretical approach and a user-ready computer code that permit to study the dynamics of collisional energy transfer and ro-vibrational energy exchange in complex molecule-molecule collisions. The method is a mixture…

Chemical Physics · Physics 2024-02-06 Carolin Joy , Bikramaditya Mandal , Dulat Bostan , Marie-Lise Dubernet , Dmitri Babikov

Quantum interference in coherent transport through single molecular rings may provide a mechanism to control current in molecular electronics. We investigate its applicability by using a single-particle Green function method combined with…

Mesoscale and Nanoscale Physics · Physics 2009-08-11 San-Huang Ke , Weitao Yang , Harold U. Baranger

High spin magnetic molecules are promising candidates for quantum information processing because they intrinsically have multiple sublevels for information storage and computational operations. However, due to their susceptibility to the…

Quantum Physics · Physics 2021-02-11 Ye-Xin Wang , Zheng Liu , Yu-Hui Fang , Shen Zhou , Shang-Da Jiang , Song Gao

Using a three-dimensional quasiclassical technique we explore the double ionization pathways of a diatomic molecule driven by an intense infrared (800nm) ultrashort laser pulse. For intensities corresponding to the tunneling regime, we find…

Atomic Physics · Physics 2009-02-26 Agapi Emmanouilidou

The local interaction of charges and light in organic solids is the basis of distinct and fundamental effects. We here observe, at the single molecule scale, how a focused laser beam can locally shift by hundreds-time their natural…

Charge migration is the electronic response that immediately follows localized ionization or excitation in a molecule, before the nuclei have time to move. It typically unfolds on sub-femtosecond time scales and most often corresponds to…

Atomic and Molecular Clusters · Physics 2022-03-07 Francois Mauger , Aderonke Folorunso , Kyle Hamer , Cristel Chandre , Mette Gaarde , Kenneth Lopata , Kenneth Schafer

Recent technological advances allowed the coherent optical manipulation of high-energy electron wavepackets with attosecond precision. Here we theoretically investigate the collision of optically-modulated pulsed electron beams with atomic…

Atomic Physics · Physics 2021-04-21 Yuya Morimoto , Peter Hommelhoff , Lars Bojer Madsen

In this work we report ab initio calculations for the $H_2^+$ molecule interacting with ultrashort intense laser pulses. We analyse several observables that can, in principle, be available experimentally, in order to get a deeper…

Atomic Physics · Physics 2017-05-25 R. E. F. Silva