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Ubiquitous graphene is a stricly 2D material representing an ideal adsorbing platform due to its large specific surface area as well as its mechanical strength and resistance to both thermal and chemical stresses. However, graphene as a…

Materials Science · Physics 2016-10-06 Massimiliano Bartolomei , Giacomo Giorgi

Graphene nanoribbons (GNRs) are promising two-dimensional materials with various technological applications, in particular for the armchair GNR families that have a semiconductor character. Recently, methods that allowed for the control of…

With advanced synthetic techniques, a wide variety of well-defined graphene nano-ribbons (GNRs) can be produced with atomic precision. Hence, finding the relation between their structures and properties becomes important for the rational…

In a bridge configuration, a single graphene nanoribbon (GNR) is positioned with a picometer precision over a trench in between two monoatomic steps on an Au(111) surface. This GNR molecular wire adopts a deformed conformation towards the…

Mesoscale and Nanoscale Physics · Physics 2022-10-07 Umamahesh Thupakula , Xavier Bouju , Jesús Castro-Esteban , Erik Dujardin , Diego Peña , Christian Joachim

In this work we address the effects on the conductance of graphene nanoribbons (GNRs) at which organic molecules are side-attached on the ribbon ends. For simplicity, only armchair (AGNRs) and zigzag (ZGNRs) nanoribbons are considered and…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 L. Rosales , M. Pacheco , Z. Barticevic , A. Latge , P. A. Orellana

We investigate high-field transport in graphene nanoribbons (GNRs) on SiO2, up to breakdown. The maximum current density is limited by self-heating, but can reach >3 mA/um for GNRs ~15 nm wide. Comparison with larger, micron-sized graphene…

Mesoscale and Nanoscale Physics · Physics 2011-06-29 Albert D. Liao , Justin Z. Wu , Xinran Wang , Kristof Tahy , Debdeep Jena , Hongjie Dai , Eric Pop

Deterministic bottom-up approaches for synthesizing atomically well-defined graphene nanoribbons (GNRs) largely rely on the surface-catalyzed activation of selected labile bonds in a molecular precursor followed by step growth…

Graphene nanoribbons (GNRs) with widths down to 16 nm have been characterized for their current-carrying capacity. It is found that GNRs exhibit an impressive breakdown current density, on the order of 10^8 A/cm2. The breakdown current…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Raghunath Murali , Yinxiao Yang , Kevin Brenner , Thomas Beck , James D. Meindl

Graphene is a promising contender to succeed the throne of silicon in electronics. To this goal, large-scale epitaxial growth of graphene on substrates should be developed. Among various methods along this line, epitaxial growth of graphene…

A single-crystal sheet of graphene is synthesized on the low-symmetry substrate Ir(110) by thermal decomposition of C$_2$H$_4$ at 1500 K. Using scanning tunneling microscopy, low-energy electron diffraction, angle-resolved photoemission…

Graphene, a flat monolayer of carbon atoms tightly packed into a two-dimensional honeycomb lattice (a one atom thick graphite sheet), is presently the hottest material in nanoscience and nanotechnology. Its challenging hypothetical…

Materials Science · Physics 2008-11-19 Abdelkader Kara , Christel Leandri , Benedicte Ealet , Hamid Oughaddou , Bernard Aufray , Guy Le Lay

Graphene is formed on SiC(000-1) surfaces (the so-called C-face of the crystal) by annealing in vacuum, with the resulting films characterized by atomic force microscopy, Auger electron spectroscopy, scanning Auger microscopy and Raman…

Materials Science · Physics 2015-05-13 Luxmi , P. J. Fisher , N. Srivastava , R. M. Feenstra , Yugang Sun , J. Kedzierski , P. Healey , Gong Gu

The on-surface synthesis of nano-graphenes has led the charge in prototyping structures with perspectives beyond silicon-based technology. Following reports of open-shell systems in graphene-nanoribbons (GNR), a flurry of research…

Mesoscale and Nanoscale Physics · Physics 2022-08-12 Aleš Cahlík , Danyang Liu , Berk Zengin , Mert Taskin , Johannes Schwenk , Fabian Donat Natterer

We demonstrate a method for synthesizing large scale single layer graphene by thermal annealing of ruthenium single crystal containing carbon. Low energy electron diffraction indicates the graphene grows to as large as millimeter dimensions…

Materials Science · Physics 2007-09-19 Y. Pan , N. Jiang , J. T. Sun , D. X. Shi , S. X. Du , Feng Liu , H. -J. Gao

Graphene, consisting of an inert, thermally stable material with an atomically flat, dangling bond-free surface is by essence an ideal template layer for van der Waals heteroepitaxy of two-dimensional materials such as silicene. However,…

Electron spin resonance (ESR) investigation of graphene nanoribbons (GNRs) prepared through longitudinal unzipping of multiwalled carbon nanotubes (MWCNTs) indicates the presence of C-related dangling bond centers, exhibiting paramagnetic…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 S. S. Rao , A. Stesmans , D. V. Kosynkin , A. Higginbotham , J. M. Tour

The influence of substrate steps on the bottom-up synthesis of atomically precise graphene nanoribbons (GNRs) on an Au(111) surface is investigated. A straight surface step is found to promote the assembly of long and compact arrays of…

Chemical Physics · Physics 2019-09-10 Chuanxu Ma , Zhongcan Xiao , Wenchang Lu , Jingsong Huang , Kunlun Hong , Jerzy Bernholc , An-Ping Li

A novel two-dimensional carbon allotrope, rectangular graphyne (R-graphyne) with tetra-rings and acetylenic linkages, is proposed by first-principles calculations. Although the bulk R-graphyne exhibits metallic property, the nanoribbons of…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 Wen-Jin Yin , Yue-E Xie , Li-Min Liu , Ru-Zhi Wang , Leo Lau , Jian-Xin Zhong , Yuan-Ping Chen

Graphene has many advantageous properties, but its lack of an electronic band gap makes this two dimensional material impractical for many nanoelectronic applications, for example field effect transistors. This problem can be circumvented…

Mesoscale and Nanoscale Physics · Physics 2009-12-17 Peter Nemes Incze , Gabor Magda , Katalin Kamaras , Laszlo Peter Biro

We show by first-principles calculations that the electronic properties of zigzag graphene nanoribbons (Z-GNRs) adsorbed on Si(001) substrate strongly depend on ribbon width and adsorption orientation. Only narrow Z-GNRs with even rows of…

Materials Science · Physics 2009-12-07 Zhuhua Zhang , Wanlin Guo