Related papers: Capillary condensation in a pore-like geometry
Phase transitions of systems confined in long cylindrical pores (capillary condensation, wetting, crystallization, etc.) are intrinsically not sharply defined but rounded. The finite size of the cross section causes destruction of long…
The dip-coating geometry, where a solid plate is withdrawn from or plunged into a liquid pool, offers a prototypical example of wetting flows involving contact-line motion. Such flows are commonly studied using the lubrication approximation…
Network modelling of water retention and conductivity of porous geomaterials based on filling and emptying of pores requires the use of a computational cell which is a representative volume element of the material. The conditions for the…
In this paper we propose an extension of the Cahn method to binary mixtures and study the problem of wetting near a two-phase critical point without any assumption on the form of intermolecular potentials. A comparison between Cahn's method…
We employ a simple model to describe the phase behavior of 4He and Ar in a hypothetical porous material consisting of a regular array of infinitely long, solid, parallel cylinders. We find that high porosity geometries exhibit two…
We present a quantitative comparison between extensive Monte Carlo simulations and self-consistent field calculations on the phase diagram and wetting behavior of a symmetric, binary (AB) polymer blend confined into a film. The flat walls…
Although complex, hierarchical nanoscale geometries with tailored degrees of disorder are commonly found in biological systems, few simple self-assembly routes to fabricating synthetic analogues have been identified. We present two…
Immiscible fluid-fluid displacement in porous media is of great importance in many engineering applications, such as enhanced oil recovery, agricultural irrigation, and geologic CO2 storage. Fingering phenomena, induced by the interface…
Wetting phenomena play a key role in flows through porous media. Relative permeability and capillary pressure-saturation functions show a high sensitivity to wettability, which has different definitions at the continuum- and pore-scale. At…
Soft particles suspended in fluids flowing through microchannels are often encountered in biological flows such as cells in vessels. They can deform under flow or when subject to mechanical stresses as they interact with themselves.…
A simple model of two-phase flow in porous media is presented. A connection is made to statistical mechanics by applying capillary power as a constraint. Stochastic sampling is then used to test the validity of this approach. Good agreement…
The displacement of a suspension of particles by an immiscible fluid in a capillary tube or in a porous media is a canonical configuration that finds application in a large number of natural and industrial applications, including water…
We argue that in a fluid, or magnet, confined by adsorbing walls which favour liquid, or (+) phase, the solvation (Casimir) force in the vicinity of the critical point is strongly influenced by capillary condensation which occurs below the…
Capillary fingering is a displacement process that can occur when a non-wetting fluid displaces a wetting fluid from a homogeneous disordered porous medium. Here, we investigate how this process is influenced by a pore size gradient. Using…
In this paper we consider a degenerate pseudoparabolic equation for the wetting saturation of an unsaturated two-phase flow in porous media with dynamic capillary pressure-saturation relationship where the relaxation parameter depends on…
The Ising model is studied on a series of hyperbolic two-dimensional lattices which are formed by tessellation of triangles on negatively curved surfaces. In order to treat the hyperbolic lattices, we propose a generalization of the corner…
We have simulated the temporal evolution of pressure due to capillary and viscous forces in two-phase drainage in porous media. We analyze our result in light of macroscopic flow equations for two-phase flow. We also investigate the effect…
Density-functional theory is used to investigate the phase behavior of colloidal binary hard-platelet and hard-rod fluids near a single hard wall or confined in a slit pore. The Zwanzig model, in which the orientations of the particles of…
In this paper, we systematically investigate the wetting behavior of a liquid ring in a cylindrical capillary tube. We obtain analytical solutions of the axisymmetric Young-Laplace equation for arbitrary contact angles. We find that, for…
A fundamental variable characterizing immiscible two-phase flow in porous media is the wetting saturation, which is the ratio between the pore volume filled with wetting fluid and the total pore volume. More generally, this variable comes…