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Constrained density functional theory (CDFT) is used to evaluate the energy level alignment of a benzene molecule as it approaches a graphene sheet. Within CDFT the problem is conveniently mapped onto evaluating total energy differences…

Mesoscale and Nanoscale Physics · Physics 2016-01-27 Subhayan Roychoudhury , Carlo Motta , Stefano Sanvito

The electronic and optical properties of mono, di, tri, and tetravacancies in graphene are studied in comparison to each other, using density functional theory. In addition, oxidized monovacancies are considered for different oxygen…

Mesoscale and Nanoscale Physics · Physics 2013-11-12 N. Singh , T. P. Kaloni , Udo Schwingenschlögl

We present a density-functional theory study addressing the on-surface adsorption of oxygen at the Pd(11N) (N =3,5,7) vicinal surfaces, which exhibit (111) steps and (100) terraces of increasing width. We find the binding to be…

Materials Science · Physics 2007-05-23 Yongsheng Zhang , Jutta Rogal , Karsten Reuter

Structure of monolayers built during adsorption process is strongly related to the properties of adsorbed particles. The most important factor is their shape. For example, adsorption of elongated molecules on patterned surfaces may produce…

Materials Science · Physics 2013-06-28 Jakub Barbasz , Michał Cieśla

We present density functional theory calculations of the binding energies of one, two and three fluorine adatoms on the same side of monolayer graphene. We show that fluorine dimers on graphene in a spin-singlet state are stable against…

Materials Science · Physics 2017-09-18 F Marsusi , N D Drummond

Nitrogen-doped graphene was recently synthesized and was reported to be a catalyst for hydrogen dissociative adsorption under a perpendicular applied electric field (F). In this work, the diffusion of H atoms on N-doped graphene, in the…

Materials Science · Physics 2012-02-15 Z. M. Ao , A. D. Hernández-Nieves , F. M. Peeters , S. Li

We argue, for a wide class of systems including graphene, that in the low temperature, high density, large separation and strong screening limits the drag resistivity behaves as d^{-4}, where d is the separation between the two layers. The…

Mesoscale and Nanoscale Physics · Physics 2015-03-20 B Amorim , N M R Peres

We investigate the chemisorptions of oxygen molecules on bilayer graphene (BLG) and its electrically modified charge-doping effect using conductivity measurement of the field effect transistor channeled with BLG. We demonstrate that the…

Mesoscale and Nanoscale Physics · Physics 2011-08-10 Yoshiaki Sato , Kazuyuki Takai , Toshiaki Enoki

We investigate the adsorption of graphene sheets on h-BN substrates by means of first-principles calculations in the framework of adiabatic connection fluctuation-dissipation theory in the random phase approximation. We obtain adhesion…

Mesoscale and Nanoscale Physics · Physics 2011-12-14 B. Sachs , T. O. Wehling , M. I. Katsnelson , A. I. Lichtenstein

We use low-energy electron microscopy to investigate how graphene is removed from Ru(0001) and Ir(111) by reaction with oxygen. We find two mechanisms on Ru(0001). At short times, oxygen reacts with carbon monomers on the surrounding Ru…

Materials Science · Physics 2010-12-14 Elena Starodub , Norman C. Bartelt , Kevin F. McCarty

We describe a mechanism that explains the formation of hydrocarbons and hydrocarbyls from hydrogenated graphene/graphite; hard C-C bonds are weakened and broken by the synergistic effect of chemisorbed hydrogen and high temperature…

Mesoscale and Nanoscale Physics · Physics 2014-08-22 Jose I. Martinez , Jose A. Martin-Gago , Jose Cernicharo , Pedro L. de Andres

We investigate the electronic properties of graphene upon water adsorption and study the influence of the SiO2 substrate in this context using density functional calculations. Perfect suspended graphene is rather insensitive to H2O…

Mesoscale and Nanoscale Physics · Physics 2008-11-26 Tim O. Wehling , Mikhail I. Katsnelson , Alexander I. Lichtenstein

Graphene on silicon carbide (SiC) bears great potential for future graphene electronic applications because it is available on the wafer-scale and its properties can be custom-tailored by inserting various atoms into the graphene/SiC…

Materials Science · Physics 2018-11-07 T. A. de Jong , E. E. Krasovskii , C. Ott , R. M. Tromp , S. J. van der Molen , J. Jobst

Domain walls in ferroelectric oxides provide fertile ground for the development of next-generation nanotechnology. Examples include domain-wall-based memory, memristors, and diodes, where the unusual electronic properties and the quasi-2D…

First-principles and semi-empirical tight binding calculations were performed to understand the adsorption of oxygen on the surface of two dimensional (2D) and zigzag stanene nano-ribbons. The intrinsic spin-orbit interaction is considered…

Materials Science · Physics 2016-10-27 M. Modarresi , W. B. Kuang , T. P. Kaloni , M. R. Roknabadi , G. Schreckenbach

Nitrogen doped graphene and carbon nanotubes are popularly in focus as metal-free electro-catalysts for oxygen reduction reactions (ORR) central to fuel-cells. N doped CNTs have been also reported to chemisorb mutually, promising a route to…

Materials Science · Physics 2015-04-17 Joydeep Bhattacharjee

Graphene exhibits extraordinary electronic and mechanical properties, and extremely high thermal conductivity. Being a very stable atomically thick membrane that can be suspended between two leads, graphene provides a perfect test platform…

Graphene is one of the most promising 2D materials for various applications due to its unique electronic properties and high thermal stability. In previous studies, it was shown that when graphene is deposited onto some transition metal…

Materials Science · Physics 2018-02-13 Tianbai Li , Jory A. Yarmoff

Using the density functional theory calculations, we show that the oxygen functional groups exhibit unexpected spontaneously dynamic behaviors on the interior surface of single-walled carbon nanotubes (SWCNT). Two types of dynamic oxygen…

Materials Science · Physics 2021-12-03 Guangdong Zhu , Zhijing Huang , Liang Zhao , Yusong Tu

In this letter we report on transport measurements of epitaxial graphene on SiC(0001) with oxygen adsorption. In a $50\times 50 \mu\mathrm{m^2}$ size Hall bar we observe the half-integer quantum Hall effect with a transverse resistance…

Mesoscale and Nanoscale Physics · Physics 2012-07-13 E. Pallecchi , M. Ridene , D. Kazazis , C. Mathieu , F. Schopfer , W. Poirier , D. Mailly , A. Ouerghi