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Using the molecular dynamics method, dynamics of hydrogen bond (HB) networks emerging on the surface of a graphene sheet during its functionalization with hydroxyl groups OH are simulated. It is demonstrated that two OH groups form an…

Mesoscale and Nanoscale Physics · Physics 2020-12-30 Alexander V. Savin

First-principles DFT levels of calculations have been carried out in order to study the structural stability and electronic properties of hydrogen passivated graphene (H-graphene) clusters. Two different shaped clusters, rectangular and…

Materials Science · Physics 2014-05-02 Deepak B Karki , Narayan P Adhikari

Density functional theory has been employed to study graphene on the (111), (100) and (110) surfaces of silicon (Si) substrates. There are several interesting findings. First, carbon atoms in graphene form covalent bonds with Si atoms, when…

Materials Science · Physics 2021-07-14 Y. W. Sun , D. Holec , D. Gehringer , L. Li , O. Fenwick , D. J. Dunstan , C. J. Humphreys

With first-principles DFT calculations, the interaction between graphene and SiO2 surface has been analyzed by constructing the different configurations based on {\alpha}-quartz and cristobalite structures. The single layer graphene can…

Materials Science · Physics 2015-05-28 X. F. Fan , W. T. Zheng , Z. X. Shen , Jer-Lai Kuo

A single-walled carbon nanotube presents a seamless cylindrical graphene surface and is thus an ideal adsorption substrate for investigating the physics of atoms and molecules in two dimensions and approaching the one-dimensional limit.…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Boris Dzyubenko , Hao-Chun Lee , Oscar E. Vilches , David H. Cobden

Recent studies on graphene hydrogenation processes showed that hydrogenation occurs via island growing domains, however how the substrate can affect the hydrogenation dynamics and/or pattern formation has not been yet properly investigated.…

Diffusion Monte Carlo (DMC) calculations were performed for an accurate description of the nature of the O$_2$ adsorption on a single layer graphene. We investigated the stable orientation of O$_2$ at a specific adsorption site as well as…

Materials Science · Physics 2019-08-28 Hyeondeok Shin , Ye Luo , Anouar Benali , Yongkyung Kwon

Graphene growth by chemical vapor deposition has received a lot of attention recently owing to the ease with which large area films can be grown, but growth of large domain or equivalently large grain size has not been reported yet. In this…

Materials Science · Physics 2010-10-20 Xuesong Li , Carl W. Magnuson , Archana Venugopal , Eric M. Vogel , Rodney S. Ruoff , Luigi Colombo

A mild annealing procedure was recently proposed for the scalable enhancement of graphene oxide (GO) properties with the oxygen content preserved, which was demonstrated to be attributed to the thermally driven phase separation. In this…

Chemical Physics · Physics 2015-02-10 Pengzhan Sun , Yanlei Wang , He Liu , Kunlin Wang , Dehai Wu , Zhiping Xu , Hongwei Zhu

We demonstrate that graphene coating can provide an efficient protection from oxidation by posing a high energy barrier to the path of oxygen atom, which could have penetrated from the top of graphene to the reactive surface underneath.…

Mesoscale and Nanoscale Physics · Physics 2012-04-25 M. Topsakal , H. Şahin , S. Ciraci

The type and distribution of oxygen functional groups in graphene oxide (GO) and reduced graphene oxide (RGO) remain still a subject of great debate. Local analytic techniques are required to access the chemistry of these materials at a…

Materials Science · Physics 2016-12-13 Anna Tararan , Alberto Zobelli , Ana M. Benito , Wolfgang K. Maser , Odile Stéphan

We present a magneto-transport study of graphene samples into which a mild disorder was introduced by exposure to ozone. Unlike the conductivity of pristine graphene, the conductivity of graphene samples exposed to ozone becomes very…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 J. Moser , H. Tao , S. Roche , F. Alsina , C. M. Sotomayor Torres , A. Bachtold

Graphane is a two-dimensional system consisting of a single layer of fully saturated (sp$^3$ hybridization) carbon atoms. In an ideal graphane structure C-H bonds exhibit an alternating pattern (up and down with relation to the plane…

Materials Science · Physics 2009-10-23 Marcelo Z. S. Flores , Pedro A. S. Autreto , Sergio B. Legoas , Douglas S. Galvao

Two-dimensional materials represented by graphene and transition metal dichalcogenides undergo charge transfer (CT) processes and become hole-doped in strong mineral acids. Nonetheless, their mechanisms remain unclear or controversial. This…

Materials Science · Physics 2021-10-06 Kwnaghee Park , Sunmin Ryu

When it is oxidized, graphite can be easily exfoliated forming graphene oxide (GO). GO is a critical intermediate for massive production of graphene, and it is also an important material with various application potentials. With many…

Materials Science · Physics 2009-12-31 Wenhua Zhang , Vincenzo Carravetta , Zhenyu Li , Yi Luo , Jinlong Yang

Bosonic atoms deposited on atomically thin substrates represent a playground for exotic quantum many-body physics due to the highly-tunable, atomic-scale nature of the interaction potentials. The ability to engineer strong interparticle…

Mesoscale and Nanoscale Physics · Physics 2024-02-26 Sang Wook Kim , Mohamed Elsayed , Nathan S. Nichols , Taras Lakoba , Juan Vanegas , Carlos Wexler , Valeri N. Kotov , Adrian Del Maestro

We have investigated theoretically the adsorption of molecules onto graphene with divacancy defects. Using ab-initio density functional calculations, we have found that O2, CO, N2, B2 and H2O molecules all interact strongly with a divacancy…

Materials Science · Physics 2015-05-13 Biplab Sanyal , Olle Eriksson , Ulf Jansson , Helena Grennberg

We studied the interaction between a single hydrogen atom and a single graphene using classical molecular dynamics simulation with modified Brenner REBO potential. Three interactions, which are adsorption, reflection, penetration, were…

Materials Science · Physics 2007-10-16 Atsushi Ito , Arimichi Takayama , Hiroaki Nakamura

We perform a density functional theory study of the effects of oxygen adsorption on the structural and electronic properties of Gr/Co(0001) and Gr/Co/Ir(111) interfaces. In both interfaces, the graphene-Co distance increases with increasing…

Materials Science · Physics 2022-08-05 Dario A. Leon , Andrea Ferretti , Daniele Varsano , Elisa Molinari , Claudia Cardoso

We report the results of our first-principles investigation on the interaction of the nucleobases adenine (A), cytosine (C), guanine (G), thymine (T), and uracil (U) with graphene, carried out within the density functional theory framework,…

Materials Science · Physics 2007-07-05 S. Gowtham , Ralph H. Scheicher , Rajeev Ahuja , Ravindra Pandey , Shashi P. Karna
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