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Electron-electron interactions and correlations form the basis of difficulties encountered in the theoretical solution of problems dealing with multi-electron systems. Accurate treatment of the electron-electron problem is likely to unravel…

Quantum Physics · Physics 2022-03-24 E. O. Jobunga

This paper focuses on the time-harmonic electromagnetic (EM) scattering problem in a general medium which may possess a nontrivial topological structure. We model this by an inhomogeneous and possibly anisotropic medium with embedded…

Analysis of PDEs · Mathematics 2024-08-14 Huaian Diao , Hongyu Liu , Qingle Meng , Li Wang

An efficient method of interpretation of the crystal field effect in non-metallic f-electron systems, the {\it enhanced angular overlap model} (EAOM), is presented. The method is established on the ground of perturbation expansion of the…

Materials Science · Physics 2007-05-23 Z. Gajek

Some issues that arise when modeling elastic energy for binary alloys are discussed within the context of a Keating model and density functional calculations. The Keating model is based on atomistic modeling of elastic interactions in…

Materials Science · Physics 2015-12-30 Arvind Baskaran , Christian Ratsch , Peter Smereka

We derive expressions for the dynamical matrix of a crystalline solid with total potential energy described by an embedded-atom-method (EAM) potential. We make no assumptions regarding the number of atoms per unit cell. These equations can…

Materials Science · Physics 2018-12-10 D. M. Riffe , Jake D. Christensen , R. B. Wilson

In radiation damage cascade displacement spikes ions and electrons can reach very high temperatures and be out of thermal equilibrium. Correct modelling of cascades with molecular dynamics should allow for the non-adiabatic exchange of…

Materials Science · Physics 2015-10-29 Daniel Mason

We present a second-nearest-neighbor Modified Embedded Atom Method (2NN--MEAM) potential for Scandium (Sc) and Aluminum-Scandium (Al--Sc) alloys that unifies cohesive, thermodynamic, and solidification behavior within a single transferable…

Materials Science · Physics 2025-12-11 Avik Mahata

We introduce EChemDID, a model to describe electrochemical driving force in reactive molecular dynamics simulations. The method describes the equilibration of external electrochemical potentials (voltage) within metallic structures and…

Materials Science · Physics 2015-09-02 Nicolas Onofrio , Alejandro Strachan

In this work, molecular mechanics simulations were performed using a modified embedded-atom method (MEAM) potential to generate the stress-strain responses of a series of n-alkane molecules from ethane (C$_2$H$_6$) to undecane…

The development of interatomic potentials that can accurately capture a wide range of physical phenomena and diverse environments is of significant interest, but it presents a formidable challenge. This challenge arises from the numerous…

Materials Science · Physics 2024-07-31 Ngoc Cuong Nguyen , Dionysios Sema

The projection-based quantum embedding method is applied to electronically excited states of valence, Rydberg, and charge-transfer character, valence- and core-ionized states, as well as bound and temporary radical anions. We embed…

Chemical Physics · Physics 2021-06-10 Valentina Parravicini , Thomas-C. Jagau

General formulas describing the multiple scattering of electron by polyatomic molecules have been derived within the framework of the model of non-overlapping atomic potentials. These formulas are applied to different carbon molecules, both…

Atomic Physics · Physics 2018-09-27 A. S. Baltenkov , S. T. Manson , A. Z. Msezane

Accurate modeling in the warm dense matter regime is a persistent challenge with the most detailed models such as quantum molecular dynamics and path integral Monte Carlo being immensely computationally expensive. Density functional theory…

Materials Science · Physics 2024-09-04 Sameen Yunus , David A. Strubbe

The optimized effective potential equations for atoms have been solved by parameterizing the potential. The expansion is tailored to fulfill the known asymptotic behavior of the effective potential at both short and long distances. Both…

Atomic Physics · Physics 2007-05-23 A. Sarsa , F. J. Galvez , E. Buendia

The interactions between atoms and molecules may be described by a potential energy function of the nuclear coordinates. Non-bonded interactions are dominated by repulsive forces at short range and attractive dispersion forces at long…

Atomic and molecular scattering at semiconductor interfaces plays a central role in surface chemistry and catalysis, yet predictive simulations remain challenging due to strong nonadiabatic effects causing the breakdown of the…

Materials Science · Physics 2026-01-16 Xiaohan Dan , Zhuoran Long , Tianyin Qiu , Jan Paul Menzel , Qiang Shi , Victor S. Batista

Materials in which electrons occupy interstitial sites as anions are called electrides and exhibit unusual dimensionality-dependent electronic behavior. These properties make electrides attractive for catalysis, transparent conductors, and…

Materials Science · Physics 2026-01-01 Lee A. Burton

We study property prediction for crystal materials. A crystal structure consists of a minimal unit cell that is repeated infinitely in 3D space. How to accurately represent such repetitive structures in machine learning models remains…

Chemical Physics · Physics 2023-11-08 Yuchao Lin , Keqiang Yan , Youzhi Luo , Yi Liu , Xiaoning Qian , Shuiwang Ji

We report a general macroscopic theory for the electrodynamic response of semi-infinite metals (SIMs). The theory includes the hitherto overlooked capacitive effects due to the finite spatial extension of a surface. The basic structure of…

Mesoscale and Nanoscale Physics · Physics 2020-05-12 Hai-Yao Deng

We show that both confined atoms and electron-atom scattering can be described by a unified basis set method. The central idea behind this method is to place the atom inside a hard potential sphere, enforced by a standard Slater type basis…

Other Condensed Matter · Physics 2015-05-13 Meta van Faassen