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We demonstrate that several metastable excited states in Hf$~$II, Hf$~$IV and W$~$VI ions may be good clock states since they are sufficiently long-living and are not sensitive to the perturbations. Cooling E1 transitions are available.…

Atomic Physics · Physics 2022-09-20 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

Today's most accurate clocks are based on laser spectroscopy of electronic transitions in single trapped ions and feature fractional frequency uncertainties below $1\times10^{-18}$. Scaling these systems to multiple, simultaneously…

Attempts are made to unify gravity with the other three fundamental forces of nature. As suggested by higher dimensional models, this unification may require space and time variation of some dimensionless fundamental constants. In this…

Atomic Physics · Physics 2023-02-15 Yan-Mei Yu , B. K. Sahoo , Bing-Bing Suo

We perform detailed calculations of the electronic structure of the Os$^{16+}$ ion and demonstrate that it has several metastable states which can be used for very accurate optical clocks. The clocks are highly sensitive to manifestations…

Atomic Physics · Physics 2024-02-21 V. A. Dzuba , V. V. Flambaum

Hyperfine-induced electric dipole contributions may significantly increase probabilities of otherwise very weak electric octupole and magnetic quadrupole atomic clock transitions (e.g. transitions between $s$ and $f$ electron orbitals).…

Atomic Physics · Physics 2016-06-01 V. A. Dzuba , V. V. Flambaum

Highly charged ions of heavy actinides from uranium to einsteinium are studied theoretically to find optical transitions sensitive to the variation of the fine structure constant. A number of promising transitions have been found in ions…

Atomic Physics · Physics 2024-05-21 V. A. Dzuba , V. V. Flambaum

We study a wide range of neutral atoms and ions suitable for ultra-precise atomic optical clocks with naturally suppressed black body radiation shift of clock transition frequency. Calculations show that scalar polarizabilities of clock…

Atomic Physics · Physics 2015-06-22 Alexander Kozlov , Vladimir Dzuba , Victor Flambaum

Highly charged ions (HCIs) combine compact electronic structure with strong relativistic effects, offering both robustness against external perturbations and enhanced sensitivity to variations of the fine-structure constant. Recent advances…

Atomic Physics · Physics 2026-02-17 S. G. Porsev , M. S. Safronova

We propose here a few selective highly charged ions (HCIs), namely Ni$^{12+}$ and Cu$^{13+}$, Pd$^{12+}$ and Ag$^{13+}$, that not only promise to be very high accurate optical clocks below $10^{-19}$ uncertainties, but also offer quality…

Atomic Physics · Physics 2018-04-25 Yan-mei Yu , B. K. Sahoo

We study ultranarrow $5s_{1/2}$ - $4f_{5/2}$ transitions in Nd$^{13+}$ and Sm$^{15+}$ and demonstrate that they lie in the optical region. The transitions are insensitive to external perturbations. At the same time they are sensitive to the…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

We evaluate the electric quadrupole moments of the ${^1}\!S_0$ and ${^3}\!P_0$ clock states of $^{27}$Al$^+$ and $^{115}$In$^+$. To capture all dominant contributions, our analysis extends through third order of perturbation theory and…

Atomic Physics · Physics 2017-04-11 K. Beloy , D. R. Leibrandt , W. M. Itano

Highly charged ions (HCIs) are promising candidates for the next generation of atomic clocks, owing to their tightly bound electron cloud, which significantly suppresses the common environmental disturbances to the quantum oscillator. Here…

For the past 15 years, tremendous progress within the fields of laser stabilization, optical frequency combs and atom cooling and trapping have allowed the realization of optical atomic clocks with unrivaled performances. These instruments…

Atomic Physics · Physics 2018-04-09 Marion Delehaye , Clément Lacroûte

Recent theoretical works have proposed atomic clocks based on narrow optical transitions in highly charged ions. The most interesting candidates for searches of new physics are those which occur at rare orbital crossings where the shell…

We perform calculations of electronic structure of Cm$^{15+}$ and Bk$^{16+}$ ions and demonstrate that they have transitions which combine the features of atomic optical clocks with the enhanced sensitivity to the variations of the fine…

Atomic Physics · Physics 2024-02-21 V. A. Dzuba , V. V. Flambaum

The influence of oscillating quadrupole fields on atomic energy levels is examined theoretically and general expressions for the quadrupole matrix elements are given. The results are relevant to any ion-based clock in which one of the clock…

Quantum Physics · Physics 2019-03-06 Kyle J. Arnold , R. Kaewuan , T. R. Tan , M. D. Barrett

Iridium ions near $4f$-$5s$ level crossings are the leading candidates for a new type of atomic clocks with a high projected accuracy and a very high sensitivity to the temporal variation of the fine structure constant $\alpha$. To identify…

Atomic Physics · Physics 2015-08-12 U. I. Safronova , V. V. Flambaum , M. S. Safronova

The exquisite control exhibited over quantum states of individual particles has revolutionized the field of precision measurement, as exemplified by the most accurate atomic clock realized in single trapped ions. Whereas many-atom lattice…

An active optical clock based on highly charged Nd$^{9+}$ ion is proposed for the first time. The clock can offer ultra-narrow linewidth at the $\upmu$Hz-level which is more than two-order of magnitude below the currently recorded laser…

Atomic Physics · Physics 2021-07-23 Yan-mei Yu , Duo Pan , Shaolong Chen , Hua Guan , Kelin Gao , Jingbiao Chen

Optical atomic clocks represent the state-of-the-art in the frontier of modern measurement science. In this article we provide a detailed review on the development of optical atomic clocks that are based on trapped single ions and many…

Atomic Physics · Physics 2015-02-10 Andrew D. Ludlow , Martin M. Boyd , Jun Ye , Ekkehard Peik , Piet O. Schmidt