Related papers: The different paths to entropy
In a recent paper, Dunkel and Hilbert [Nature Physics 10, 67-72 (2014)] use an entropy definition due to Gibbs to provide a 'consistent thermostatistics' which forbids negative absolute temperatures. Here we argue that the Gibbs entropy…
The notion of entropy penetrates much of science. A key feature of the all-important notion of Boltzmann-Gibbs-Shannon entropy is its extensivity (additivity over independent subsystems). However, there is a need for other quantities. In…
Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…
Recently a number of approaches has been developed to connect the microscopic dynamics of particle systems to the macroscopic properties of systems in nonequilibrium stationary states, via the theory of dynamical systems. This way a direct…
Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…
We have presented first an axiomatic derivation of Boltzmann entropy on the basis of two axioms consistent with two basic properties of thermodynamic entropy. We have then studied the relationship between Boltzmann entropy and information…
The physical foundations of a variety of emerging technologies --- ranging from the applications of quantum entanglement in quantum information to the applications of nonequilibrium bulk and interface phenomena in microfluidics, biology,…
The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…
Counting ad infinitum is the holographic observable to a statistical dynamics with finite states under independent repeated sampling. Entropy provides the infinitesimal probability for an observed frequency $\hat{\boldsymbol{\nu}}$ w.r.t. a…
We prove characterization theorems for relative entropy (also known as Kullback-Leibler divergence), q-logarithmic entropy (also known as Tsallis entropy), and q-logarithmic relative entropy. All three have been characterized axiomatically…
In this article we discuss a model used to introduce the concept of entropy with secondary school students. It can be used to discuss with students the reversibility of time, the tendency towards homogeneity and the link between probability…
This paper critically reviews the entropy model proposed by Adam and Gibbs in 1965 for explaining the dramatic temperature dependence of glass-forming liquids' average relaxation time, one of the most influential models during the last…
A definition of entropy via the Kolmogorov algorithmic complexity is discussed. As examples, we show how the meanfield theory for the Ising model, and the entropy of a perfect gas can be recovered. The connection with computations are…
The concept of entropy forms the backbone of the principles of thermodynamics. R.C. Tolman initiated the correlation between gravity and thermodynamics. The development of black hole thermodynamics and the generalized second law of…
Entropy is the distinguishing and most important concept of our efforts to understand and regularize our observations of a very large class of natural phenomena, and yet, it is one of the most contentious concepts of physics. In this…
We give a notion of entropy for general gemetric structures, which generalizes well-known notions of topological entropy of vector fields and geometric entropy of foliations, and which can also be applied to singular objects, e.g. singular…
Many thermodynamic relations involve inequalities, with equality if a process does not involve dissipation. In this article we provide equalities in which the dissipative contribution is shown to involve the relative entropy (a.k.a.…
We first present open questions related to the foundations of thermodynamics and statistical physics. We then argue that in principle one can not have "closed systems", and that a universal background should exist. We propose that the…
Partial differential equations are ubiquitous in almost all applications of mathematics, where they provide a natural mathematical description of many phenomena involving change in physical, chemical, biological, and social processes. The…
Shannon and Khinchin showed that assuming four information theoretic axioms the entropy must be of Boltzmann-Gibbs type, $S=-\sum_i p_i \log p_i$. Here we note that in physical systems one of these axioms may be violated. For non-ergodic…