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Derivation of the canonical (or Boltzmann) distribution based only on quantum dynamics is discussed. Consider a closed system which consists of mutually interacting subsystem and heat bath, and assume that the whole system is initially in a…

Statistical Mechanics · Physics 2009-10-30 Hal Tasaki

The paper demonstrates that the canonical probability distribution of the occupancy numbers of a bosonic system is multinomial, and shows how the thermodynamics of the canonical system descends from this distribution. The categorical…

Statistical Mechanics · Physics 2025-11-25 Arnaldo Spalvieri

The microcanonical ensemble has long been a starting point for the development of thermodynamics from statistical mechanics. However, this approach presents two problems. First, it predicts that the entropy is only defined on a discrete set…

Statistical Mechanics · Physics 2017-06-07 William Griffin , Michael Matty , Robert H. Swendsen

It is shown that in equilibrium a canonical ensemble of particles with two-particle interaction the Gibbs distribution function may be expressed uniquely through a pair distribution function. It means, that for given values of the particle…

Statistical Mechanics · Physics 2007-05-23 M. I. Kalinin

It is shown that a small system in thermodynamic equilibrium with a finite thermostat can have a q-exponential probability distribution which closely depends on the energy nonextensivity and the particle number of the thermostat. The…

Statistical Mechanics · Physics 2008-11-13 Congjie Ou , Wei Li , Jiulin Du , Francois Tsobnang , Jincan Chen , Alain Le Mehaute , Qiuping A. Wang

We describe a finite inhomogeneous three dimensional system of classical particles which interact through short and (or) long range interactions by means of a simple analytic spin model. The thermodynamic properties of the system are worked…

Nuclear Theory · Physics 2009-10-31 J. Richert , P. Wagner , M. Henkel , J. M. Carmona

The emergence of statistical mechanics from quantum dynamics is a central problem in quantum many-body physics. Deriving observables aligned with the prediction of the canonical ensemble for a quantum system relies on the presence of a bath…

Statistical Mechanics · Physics 2026-01-05 Nikolay V. Gnezdilov , Andrei I. Pavlov

Traditional derivation of Gibbs canonical distribution and the justification of thermodynamics are based on the assumption concerning an isoenergetic ergodicity of a system of $n$ weakly interacting identical subsystems and passage to the…

Exactly Solvable and Integrable Systems · Physics 2007-05-23 V. V. Kozlov

For quantum systems that are weakly coupled to a much 'bigger' environment, thermalization of possibly far from equilibrium initial ensembles is demonstrated: for sufficiently large times, the ensemble is for all practical purposes…

Statistical Mechanics · Physics 2015-05-19 Peter Reimann

We establish an analytical criterion for dynamical thermalization within harmonic systems, applicable to both classical and quantum models. Specifically, we prove that thermalization of various observables, such as particle energies in…

Statistical Mechanics · Physics 2025-07-29 Marco Cattaneo , Marco Baldovin , Dario Lucente , Paolo Muratore-Ginanneschi , Angelo Vulpiani

In this paper we derive the canonical distribution as a stationary solution of the Liouville equation for the classical dissipative system. Dissipative classical systems can have stationary states look like canonical Gibbs distributions.…

Statistical Mechanics · Physics 2009-11-10 Vasily E. Tarasov

A unified semiclassical framework is presented to describe the evaporative cooling of trapped atomic gases, accounting for both classical and quantum statistics. By combining global thermodynamics with phase-space distributions, general…

Macroscopic thermodynamics of equilibrium is constructed for systems obeying power-law canonical distributions. With this, the connection between macroscopic thermodynamics and microscopic statistical thermodynamics is generalized. This is…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , A. K. Rajagopal

We develop the theory of canonical-dissipative systems, based on the assumption that both the conservative and the dissipative elements of the dynamics are determined by invariants of motion. In this case, known solutions for conservative…

Statistical Mechanics · Physics 2009-11-07 Frank Schweitzer , Werner Ebeling , Benno Tilch

The exact equations of motion for microscopic density of classical particles number with account of inter-particle interactions and external field in closed form are derived. An integral equation for equilibrium distributions of the…

Statistical Mechanics · Physics 2014-07-18 A. Yu. Zakharov

A quantum system at equilibrium is represented by a corresponding classical system, chosen to reproduce thermodynamic and structural properties. The motivation is to allow application of classical strong coupling theories and molecular…

Statistical Mechanics · Physics 2013-03-14 James Dufty , Sandipan Dutta

The distribution of the initial short-time displacements of particles is considered for a class of classical systems under rather general conditions on the dynamics and with Gaussian initial velocity distributions, while the positions could…

Statistical Mechanics · Physics 2007-05-23 R. van Zon , E. G. D. Cohen

We consider one-dimensional, integrable many-body classical and quantum systems in thermal equilibrium. In the classical case, we use the classical limit of the Bethe equations to obtain a self-consistent integral equation whose solution…

Quantum Gases · Physics 2025-03-11 Manuel Valiente

This paper is concerned with the ergodic subspaces of the state spaces of isolated quantum systems. We prove a new ergodic theorem for closed quantum systems which shows that the equilibrium state of the system takes the form of a grand…

Quantum Physics · Physics 2008-11-26 Dorje C. Brody , Daniel W. Hook , Lane P. Hughston

The approach to a substantiation of thermodynamics is offered. A conservative system of interacting elements, which is not in equilibrium, is used as a model. This system is then split into small subsystems that are accepted as being in…

Statistical Mechanics · Physics 2007-05-23 V. M. Somsikov
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