On the completeness of describing an equilibrium canonical ensemble using a pair distribution function
Statistical Mechanics
2007-05-23 v1
Abstract
It is shown that in equilibrium a canonical ensemble of particles with two-particle interaction the Gibbs distribution function may be expressed uniquely through a pair distribution function. It means, that for given values of the particle number , volume , and temperature , the pair distribution function contains as many information about the system as a full Gibbs distribution. The latter is represented as a series expansion in the pair distribution function. A recurrence relation system is constructed, which allows all terms of this expansion to be calculated successively.
Cite
@article{arxiv.cond-mat/0405256,
title = {On the completeness of describing an equilibrium canonical ensemble using a pair distribution function},
author = {M. I. Kalinin},
journal= {arXiv preprint arXiv:cond-mat/0405256},
year = {2007}
}
Comments
10 pages, no figures