On one-to-one correspondence of Gibbs distribution and reduced two-particle distribution function
Abstract
In this article it is shown that in an equilibrium classical canonical ensemble of molecules with two-body interaction and external field full Gibbs distribution can be uniquely expressed in terms of a reduced two-particle distribution function. This means that while a number of particles and a volume are fixed the reduced two-particle distribution function contains as much information about the equilibrium system as the whole canonical distribution. The latter is represented as an absolutely convergent power series relative to the reduced two-particle distribution function. As an example a linear term of this expansion is calculated. It is also shown that Gibbs distribution function can de expressed in terms of reduced distribution function of the first order and pair correlation function.That is the later two functions contain the whole information about system under consideration.
Keywords
Cite
@article{arxiv.0810.4792,
title = {On one-to-one correspondence of Gibbs distribution and reduced two-particle distribution function},
author = {M. I. Kalinin},
journal= {arXiv preprint arXiv:0810.4792},
year = {2008}
}
Comments
This work was reported on International conference "Mathematical physics and its applications" in Samara, Russia, 7-13 september 2008