Related papers: Geometry-induced phase transition in fluids: capil…
We consider theoretically liquid rise against gravity in capillaries with height-dependent cross-section. For a conical capillary made from a hydrophobic surface and dipped in a liquid reservoir, the equilibrium liquid height depends on the…
We numerically investigate the meniscus-guided coating of a binary fluid mixture containing a solute and a volatile solvent that phase separates via spinodal decomposition. Motivation is the evaporation-driven deposition of material during…
A new approach to the modelling of wetting fronts in porous media on the Darcy scale is developed, based on considering the types (modes) of motion the menisci go through on the pore scale. This approach is illustrated using a simple model…
We present a theoretical study of capillary condensation of fluids adsorbed in mesoporous disordered media. Combining mean-field density functional theory with a coarse-grained description in terms of a lattice-gas model allows us to…
We consider condensation in a capillary groove of width $L$ and depth $D$, formed by walls that are completely wet (contact angle $\theta=0$), which is in a contact with a gas reservoir of the chemical potential $\mu$. On a mesoscopic…
An outstanding characteristic of porous media, desired in many applications, is the large surface area, which facilitates solid-fluid interactions, making porous media an extreme case in colloid and interface science. In two-fluid systems,…
The established macroscopic equations of motion for two phase immiscible displacement in porous media are known to be physically incomplete because they do not contain the surface tension and surface areas governing capillary phenomena.…
We present a macroscopic theory of capillary condensation in slits formed by parallel walls of unequal length. Using the concept of an edge contact angle, we identify four distinct condensation states and derive Kelvin-like relations for…
This is a summarising investigation of the events of the phase transition of the first order that occur in the critical region below the liquid-gas critical point. The grand partition function has been completely integrated in the…
We calculate the meniscus location in tapered capillaries under the influence of pressure difference and dielectrophoretic forces with and without gravity. We find that the meniscus location can be a discontinuous function of the pressure…
We use confocal microscopy to directly visualize the simultaneous flow of both a wetting and a non-wetting fluid through a model three-dimensional (3D) porous medium. We find that, for small flow rates, both fluids flow through unchanging,…
Recent X-ray imaging experiments have revealed that multiphase flow through porous media involves transient fluctuations in local occupancy, even under fixed macroscopic steady-state conditions where capillary forces dominate at the pore…
We investigate phase separation of near-critical binary mixtures between parallel symmetric walls in the strong adsorption regime. We take into account the renormalization effect due to the critical fluctuations using the recent local…
We investigate the dependence of the order parameter profile, local and total susceptibilities on both the temperature and external magnetic field within the mean-filed Ginzburg-Landau Ising type model. We study the case of a film geometry…
We study the influence of wetting on the capillary condensation for a simple fluid in a pore-like geometry, where the reference system is an infinitely long slit. The Corner Transfer Matrix Renormalization Group method has been extended to…
An ultralow-temperature binary mixture of Bose-Einstein condensates adsorbed at an optical wall can undergo a wetting phase transition in which one of the species excludes the other from contact with the wall. Interestingly, while hard-wall…
Condensation in linear wedges formed by semi-infinite walls is a well-established critical phenomenon characterized by the continuous growth of an adsorbed liquid layer as bulk two-phase coexistence is approached. In this study, we…
The excess adsorption $\Gamma $ in two-dimensional Ising strips $(\infty \times L)$ subject to identical boundary fields, at both one-dimensional surfaces decaying in the orthogonal direction $j$ as $-h_1j^{-p}$, is studied for various…
Capillary-driven transport offers a simple, self-sustained alternative to externally pumped microfluidic systems, yet achieving precise control of such flows remains challenging. We experimentally and theoretically investigate capillary…
We consider the location and order of capillary condensation transitions occurring in deep grooves of width $L$ and depth $D$. For walls that are completely wet by liquid (contact angle $\theta=0$) the transition is continuous and its…