Related papers: Geometry-induced phase transition in fluids: capil…
In this two-part study we investigate the phase behaviour of a fluid spatially confined in a semi-infinite rectangular pore formed by three orthogonal walls and connected to a reservoir maintaining constant values of pressure and…
We study the low temperature phase equilibria of a fluid confined in an open capillary slit formed by two parallel walls separated by a distance $L$ which are in contact with a reservoir of gas. The top wall of the capillary is of finite…
In Part II of this study we consider two cases of three-phase coexistence. First, the capped capillary may allow for vapour, drop-like, and slab-like phases to coexist at the same values of temperature and chemical potential. Second, the…
We study the phase equilibria of a fluid confined in an open capillary slit formed when a wall of finite length $H$ is brought a distance $L$ away from a second macroscopic surface. This system shows rich phase equilibria arising from the…
We study phase behaviour of a model fluid confined between two unlike parallel walls in the presence of long range (dispersion) forces. Predictions obtained from macroscopic (geometric) and mesoscopic arguments are compared with numerical…
We show that condensation in a capped capillary slit is a continuous interfacial critical phenomenon, related intimately to several other surface phase transitions. In three dimensions (3d), the adsorption and desorption branches correspond…
We study the order of capillary condensation and evaporation transitions of a simple fluid adsorbed in a deep capillary groove using a fundamental measure density functional theory (DFT). The walls of the capillary interact with the fluid…
We study the formation and the shape of a liquid meniscus in a wedge with opening angle $2\phi$ which is exposed to a vapor phase. By applying a suitable effective interface model, at liquid-vapor coexistence and at a temperature $T_{\phi}$…
In this article we calculate the surface phase diagram of a two-dimensional hard-rod fluid confined between two hard lines. In a first stage we study the semi-infinite system consisting of an isotropic fluid in contact with a single hard…
We present results of a microscopic density functional theory study of wedge filling transitions, at a right-angle wedge, in the presence of dispersion-like wall-fluid forces. Far from the corner the walls of the wedge show a first-order…
We consider the phase equilibria of a fluid confined in a deep capillary groove of width $L$ with identical side walls and a bottom made of a different material. All walls are completely wet by the liquid. Using density functional theory…
The dynamics of saturated vapor between two intersecting walls is examined. It is shown that, if the angle $\phi$ between the walls is sufficiently small, the vapor becomes unstable, and spontaneous condensation occurs in the corner,…
In this work, we extend the model of contact angles that we have previously developed for sessile drops on a wetted surface to the case of a meniscus in a capillary. The underlying physics of our model describe the intermolecular forces…
The properties of the coexisting bulk gas and liquid phases of a polydisperse fluid depend not only on the prevailing temperature, but also on the overall parent density. As a result, a polydisperse fluid near a wall will exhibit…
We study the adsorption of simple fluids at smoothly structured, completely wet, walls and show that a meniscus osculation transition occurs when the Laplace and geometrical radii of curvature of locally parabolic regions coincide.…
Capillary imbibition underpins many processes of fundamental and applied relevance in fluid mechanics. A limitation to the flow is the coupling to the confining solid, which induces friction forces. Our work proposes a general theoretical…
We investigate the phase diagram of a two-component associating fluid mixture in the presence of selectively adsorbing substrates. The mixture is characterized by a bulk phase diagram which displays peculiar features such as closed loops of…
Liquid dropout and retention in gas-condensate reservoirs, specially in the near wellbore region, obstruct gas flowing paths and impact negatively the produced fluid volume and composition. Yet, condensate banking forecasting is commonly…
We present numerical studies of complete, first-order and critical wedge filling transitions, at a right angle corner, using a microscopic fundamental measure density functional theory. We consider systems with short-ranged, cut-off…
A computational framework is developed to address capillary self-focusing in Step Emulsification. The microfluidic system consists of a single shallow and wide microchannel that merges into a deep reservoir. A continuum approach coupled…