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We present the frequency-dependant (dynamic) dielectric response of a group of topical polycrystalline zeolitic imidazolate-based metal-organic framework (MOF) materials in the extended infrared spectral region. Using synchrotron-based FTIR…

The properties of semiconductors and functional dielectrics are defined by their response in electric fields, which may be perturbed by defects and the strain they generate. In this work, we demonstrate how diffraction-based X-ray…

Materials Science · Physics 2024-11-12 Trygve Magnus Ræder , Urko Petralanda , Thomas Olsen , Hugh Simons

Ferroic transition metal oxides, which exhibit spontaneous elastic, electrical, magnetic or toroidal order, exhibit functional properties that find use in ultrastable solid-state memories to sensors and medical imaging technologies. To…

Materials Science · Physics 2015-03-20 Andrew T. Mulder , Nicole A. Benedek , James M. Rondinelli , Craig J. Fennie

The switching dynamics of ferroelectric materials is a crucial intrinsic property which directly affects the operation and performance of ferroelectric devices. In conventional ferroelectric materials, the typical ferroelectric switching…

Materials Science · Physics 2023-08-02 Ri He , Hua Wang , Fucai Liu , Shi Liu , Houfang Liu , Zhicheng Zhong

In this work, we use density functional theory calculations to demonstrate how spontaneous electric polarizations can be induced \textit{via} a hybrid improper ferroelectric mechanism in iodide perovskites, a family well-known to display…

Materials Science · Physics 2018-06-27 Joshua Young , James M. Rondinelli

Layered van der Waals crystals of topologically non-trivial and trivial semimetals with antiferromagnetic (AFM) ordering of magnetic sublattice are known to exhibit a negative magnetoresistance that is well correlated with AFM magnetization…

Using a combination of Density Functional Theory, mean-field analysis and exact diagonalization calculations we reveal the emergence of a dimerized charge ordered state in TMTTF$_2$-PF$_6$ organic crystal. The interplay between charge and…

Strongly Correlated Electrons · Physics 2015-03-19 Gianluca Giovannetti , Sanjeev Kumar , Jean-Paul Pouget , Massimo Capone

Stacking ferroelectricity (SFE) has been discovered in a wide range of van der Waals materials and holds promise for applications, including photovoltaics and high-density memory devices. We show that the microscopic origin of out-of-plane…

Materials Science · Physics 2024-05-13 Benjamin T. Zhou , Vedangi Pathak , Marcel Franz

The interplay between band and atomic aspects in materials with co-existing wide-band and flat-band states, or wide-band and effectively dispersionless electronic states is increasingly expected to lead to novel behavior. Using dynamical…

Strongly Correlated Electrons · Physics 2025-08-12 M. S. Laad , S. R. Hassan

The first switchable electric polarization in metals was recently discovered in bilayer and trilayer WTe2. Strangely, despite the tininess of the ordered polarization, the ferroelectricity survives up to 350 K, rendering the mechanism of…

Materials Science · Physics 2025-07-25 Fangyuan Gu , Ruoshi Jiang , Wei Ku

The influence of magnetic dipole interactions (MDIs) on the magnetic properties of local-moment spin systems is investigated. The eigenvalues and eigenvectors of the MDI tensor are determined for a wide variety of spin lattices and magnetic…

Strongly Correlated Electrons · Physics 2016-01-18 David C. Johnston

Recent experimental realization of ferroelectric nematic liquid crystalline phases stimulated material development and numerous experimental studies of these new phases, guided by their fundamental and applicative interest. In this…

Soft Condensed Matter · Physics 2022-08-18 Nerea Sebastián , Martin Čopič , Alenka Mertelj

The magnetic and dielectric properties of \aa kermanite Sr$_2$CoSi$_2$O$_7$ single crystals in high magnetic fields were investigated. We have observed finite induced electric polarization along the c axis in high fields, wherein all Co…

Strongly Correlated Electrons · Physics 2012-08-30 M. Akaki , H. Iwamoto , T. Kihara , M. Tokunaga , H. Kuwahara

The orthorhombically distorted perovskite NaMnF$_{3}$ has been predicted to become ferroelectric if an $a=c$ distortion of the bulk $Pnma$ structure is imposed. In order to test this prediction, NaMnF$_{3}$ thin films were grown on…

Materials Science · Physics 2017-04-05 Amit KC , Pavel Borisov , Vladimir V. Shvartsman , David Lederman

Van der Waals (vdW) materials have greatly expanded our design space of heterostructures by allowing individual layers to be stacked at non-equilibrium configurations, for example via control of the twist angle. Such heterostructures not…

Mesoscale and Nanoscale Physics · Physics 2022-02-04 Xirui Wang , Kenji Yasuda , Yang Zhang , Song Liu , Kenji Watanabe , Takashi Taniguchi , James Hone , Liang Fu , Pablo Jarillo-Herrero

Using direct variational method with 2-parametric trial function and Landau-Ginzburg-Devonshire thermodynamical approach, we derived analytical expressions for polarization spatial redistribution in the ferroelectrics caused by the biased…

Materials Science · Physics 2010-04-16 Anna N. Morozovska

Multiferroicity and magnetodielectric coupling in metal-organic-frameworks (MOFs) is rare and so far restricted mainly to formate-based systems with perovskite structure. In the course of this work we designed a tetragonal framework…

Materials Science · Physics 2017-10-31 Tathamay Basu , A. Jesche , B. Bredenkotter , M. Grzywa , D. Denysenko , D. Volkmer , A. Loidl , S. Krohns

We study the low temperature transport characteristics of a disordered metal in the presence of electron-electron interactions. We compare Hartree-Fock and dynamical mean field theory (DMFT) calculations to investigate the scattering…

Strongly Correlated Electrons · Physics 2011-09-20 E. C. Andrade , E. Miranda , V. Dobrosavljevic

Hafnia ferroelectrics combine technological promise and unprecedented behaviors. Their peculiarity stems from the many active extrinsic mechanisms that contribute to their properties and from a continuously growing number of novel intrinsic…

Materials Science · Physics 2023-11-15 Hugo Aramberri , Jorge Íñiguez

Crystalline materials with broken inversion symmetry can exhibit a spontaneous electric polarization, which originates from a microscopic electric dipole moment. Long-range polar or anti-polar order of such permanent dipoles gives rise to…