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Ferroelectric materials can switch their polarization in response to an applied electric field. In this work, ferroelectricity at the single molecule level is proposed and investigated using density functional theory (DFT) calculations.…

Applied Physics · Physics 2017-05-30 Xinfeng Quan , Geoffrey R. Hutchison

Metal-organic frameworks comprehend a wide class of hybrid organic-inorganic materials with general structure A$_m$BX$_n$, with $A$ and $X$ being organic molecules and B a metal cation. This often results in enhanced structural flexibility…

Materials Science · Physics 2022-04-21 Francesco Foggetti , Alessandro Stroppa , Sergey Artyukhin

Fluid molecular ferroelectrics are a new class of organic materials where ferroelectricity is found in conjunction with 3D fluidity whilst still retaining spontaneous polarization values comparable to their traditional solid state…

Soft Condensed Matter · Physics 2026-02-19 Calum J Gibb , Jordan Hobbs , William C Ogle , Richard J Mandle

We report the development of a combined machine-learning and high-throughput density functional theory (DFT) framework to accelerate the search for new ferroelectric materials. The framework can predict potential ferroelectric compounds…

We present a strategy to design structures for which a polar lattice distortion induces weak ferromagnetism. We identify a large class of multiferroic oxides as potential realizations and use density-functional theory to screen several…

Materials Science · Physics 2013-05-29 Craig J. Fennie

The presence of a switchable spontaneous electric polarization makes ferroelectrics ideal candidates for the use in many applications such as memory and sensors devices. Since known ferroelectrics are rather limited, finding new…

Materials Science · Physics 2016-02-25 Ke Xu , Xue-Zeng Lu , H. J. Xiang

The combination of metallicity and ferroelectricity breaks traditional boundaries, paving new avenues for innovative electronic materials and devices. This breakthrough is particularly notable, as metallicity and ferroelectricity have…

Materials Science · Physics 2024-04-09 Jiagang Zhang , Ting Zhang

Following the groundbreaking discovery of the ferroelectric nematic liquid crystal phase (NF), a series of closely-related new polar phases have also been found. An especially interesting one is the ferroelectric smectic A phase (SmAF) with…

Soft Condensed Matter · Physics 2024-11-14 Aitor Erkoreka , Minjung Huang , Satoshi Aya , Josu Martinez-Perdiguero

Since the recent discoveries, ferroelectric nematics became of upmost interest due to their outstanding ferroelectric properties. In this work, we prepared a series of polar molecules revealing a ferroelectric nematic phase (NF) with a very…

Combining classical electrodynamics and density functional theory (DFT) calculations, we develop a general and rigorous theoretical framework that describes the energetics of metal surfaces under high electric fields. We show that the…

Materials Science · Physics 2019-05-22 Andreas Kyritsakis , Ekaterina Baibuz , Ville Jansson , Flyura Djurabekova

The recent experimental discovery of ferroelectric and splay nematic phases has sparked interest in comprehending the crucial molecular features necessary to stabilize these innovative structures. This study advances the ongoing discourse…

Soft Condensed Matter · Physics 2024-09-17 Agnieszka Chrzanowska , Lech Longa

We investigated the electrical properties of the liquid crystal compound, known as an RM734, exhibiting a ferroelectric nematic phase. The influence of alternating (AC) and direct (DC) current electric fields on the switching process of the…

Soft Condensed Matter · Physics 2025-03-04 Mateusz Mrukiewicz , Paweł Perkowski , Jakub Karcz , Przemysław Kula

Materials with reduced dimensions have been shown to host a wide variety of exotic properties and novel quantum states that often defy textbook wisdom1-5. Ferroelectric polarization and metallicity are well-known examples of mutually…

A material showing a sequence of three ferroelectric liquid crystalline phases below the paraelectric nematic phase has been synthesized and studied. The polar order of molecules appearing due to the dipole-dipole interactions in the NF…

Soft Condensed Matter · Physics 2024-10-16 Grant J. Strachan , Ewa Górecka , Jadwiga Szydłowska , Anna Makal , Damian Pociecha

Using a free-energy based computational model, we have investigated the response of a system comprising two interacting ferroelectric nanospheres, embedded in a dielectric medium, to a static external electric field. The system response is…

Applied Physics · Physics 2019-02-01 John Mangeri , S. Pamir Alpay , Serge Nakhmanson , Olle G. Heinonen

Most properties of solid materials are defined by their internal electric field and charge density distributions which so far are difficult to measure with high spatial resolution. Especially for 2D materials, the atomic electric fields…

A dielectric nonlinear response in model two-phase composites, prepared from a displacive ferroelectric material with a dominant dielectric response due to a single oscillator ferroelectric mode and a dielectric material, is characterized…

Materials Science · Physics 2018-06-26 Matej Hudak , Jana Tothova , Ondrej Hudak

Dabconium hybrid perovskites include a number of recently-discovered ferroelectric phases with large spontaneous polarisations. The origin of ferroelectric response has been rationalised in general terms in the context of hydrogen bonding,…

Materials Science · Physics 2020-06-11 Dominic J. W. Allen , Nicholas C. Bristowe , Andrew L. Goodwin , Hamish H. -M. Yeung

The possibility to combine and finetune properties of functional molecular materials by chemical design is particularly relevant for organic ferroelectrics. In this work, we investigate a class of organic molecular materials that show…

Materials Science · Physics 2025-07-16 H. Mager , M. Litterst , Sophia Klubertz , S. V. Haridas , O. Shyshov , M. von Delius , M. Kemerink

It was recently observed that materials showing most striking multiferroic phenomena are frustrated spin-density-wave magnets. We present a simple phenomenological theory, which describes the orientation of the induced electric polarization…

Strongly Correlated Electrons · Physics 2009-11-11 Maxim Mostovoy
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