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A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterised by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The…

Quantum Physics · Physics 2007-10-25 Dorje C. Brody , Daniel W. Hook , Lane P. Hughston

A question that is currently highly debated is whether the microcanonical entropy should be expressed as the logarithm of the phase volume (volume entropy, also known as the Gibbs entropy) or as the logarithm of the density of states…

Statistical Mechanics · Physics 2015-05-28 Michele Campisi

It is generally believed that, in the thermodynamic limit, the microcanonical description as a function of energy coincides with the canonical description as a function of temperature. However, various examples of systems for which the…

Statistical Mechanics · Physics 2016-01-13 Tiziano Squartini , Joey de Mol , Frank den Hollander , Diego Garlaschelli

We present a review of recent work on the statistical mechanics of non equilibrium processes based on the analysis of large deviations properties of microscopic systems. Stochastic lattice gases are non trivial models of such phenomena and…

Probability · Mathematics 2015-12-18 L. Bertini , A. De Sole , D. Gabrielli , G. Jona-Lasinio , C. Landim

The lack of a procedure to determine equilibrium thermodynamic properties of a small system interacting with a bath is frequently seen as a weakness of conventional statistical mechanics. A typical example for such a small system is a…

Chemical Physics · Physics 2022-12-16 Mohammad Rahbar , Christopher J. Stein

We show that entropy is globally concave with respect to energy for a rich class of mean field interactions, including regularizations of the the point-vortex model in the plane, plasmas and self-gravitating matter in 2D, as well as the…

Mathematical Physics · Physics 2022-11-30 Robert J. Berman

The so-called $\chi^{2}$-superstatistics of Beck and Cohen (BC) is employed to investigate the infinite-range Blume-Capel model, a well-known representative system displaying inequivalence of canonical and microcanonical phase diagrams.…

Statistical Mechanics · Physics 2017-02-07 Nelson A. Alves , Rafael B. Frigori

For the spherical model with nearest-neighbour interactions, the microcanonical entropy s(e,m) is computed analytically in the thermodynamic limit for all accessible values of the energy e and the magnetization m per spin. The entropy…

Statistical Mechanics · Physics 2009-12-11 Michael Kastner

I discuss the effects of fermionic condensation in systems of constant density of states. I show that the condensation leads to a correction of the chemical potential and of the Fermi distribution in canonical Fermi systems at low…

Statistical Mechanics · Physics 2007-05-23 Dragos-Victor Anghel

We consider a general class of statistical mechanical models of coherent structures in turbulence, which includes models of two-dimensional fluid motion, quasi-geostrophic flows, and dispersive waves. First, large deviation principles are…

Probability · Mathematics 2007-05-23 R. S. Ellis , K. Haven , B. Turkington

When addressing the thermodynamics of finite-sized systems, one must specify whether one wants to fix conserved charges to a sharp value or whether one is content to fix their thermodynamic average. In other words, contrary to the…

High Energy Physics - Phenomenology · Physics 2016-09-01 Michael Engelhardt

This short paper presents a nontechnical introduction to the problem of nonequivalent microcanonical and canonical ensembles. Both the thermodynamic and the macrostate levels of definition of nonequivalent ensembles are introduced. The many…

Statistical Mechanics · Physics 2007-05-23 H. Touchette , R. S. Ellis , B. Turkington

The Renyi statistics in the canonical and microcanonical ensembles is examined in the general case and in particular for the ideal gas. In the microcanonical ensemble the Renyi statistics is equivalent with the Boltzmann-Gibbs statistics.…

Statistical Mechanics · Physics 2015-05-14 A. S. Parvan , T. S. Biro

Boltzmann's microcanonical entropy is the link between statistical physics and thermodynamics, forasmuch as the behavior of any thermodynamic quantity is directly related to the number of microscopic configurations. Accordingly, in this…

Statistical Mechanics · Physics 2022-11-24 L. S. Ferreira , L. N. Jorge , C. J. DaSilva , A. A. Caparica

We examine the minimization of information entropy for measures on the phase space of bounded domains, subject to constraints that are averages of grand canonical distributions. We describe the set of all such constraints and show that it…

Mathematical Physics · Physics 2019-10-02 Stamatis Dostoglou , Alexander Hughes , Jianfei Xue

A system composed of identical spins and described by a quantum mechanical pure state is analyzed within the statistical framework presented in Part I of this work. We explicitly derive the typical values of the entropy, of the energy, and…

Quantum Physics · Physics 2010-07-22 Barbara Fresch , Giorgio J. Moro

The present study regards the zeroth order mean field approximation of a dipole-type interaction model, which is analytically solved in the canonical and microcanonical ensembles. After writing the canonical partition function, the free and…

Statistical Mechanics · Physics 2018-03-16 Atenas Boris , Curilef Sergio

We study a quantum spin system on the $d$-dimensional hypercubic lattice $\Lambda$ with $N=L^d$ sites with periodic boundary conditions. We take an arbitrary translation invariant short-ranged Hamiltonian. For this system, we consider both…

Statistical Mechanics · Physics 2018-08-02 Hal Tasaki

The approach is developed for the description of isolated Fermi-systems with finite number of particles, such as complex atoms, nuclei, atomic clusters etc. It is based on statistical properties of chaotic excited states which are formed by…

Statistical Mechanics · Physics 2009-08-18 V. V. Flambaum , F. M. Izrailev

We discuss a generalized quantum microcanonical ensemble. It describes isolated systems that are not necessarily in an eigenstate of the Hamilton operator. Statistical averages are obtained by a combination of a time average and a maximum…

Quantum Physics · Physics 2009-11-13 Jan Naudts , Erik Van der Straeten