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For solar conditions, we numerically integrate the density matrix equation for a thermal electron in the field of a Be-7 ion and other plasma ions and smeared-out electrons. Our results are in agreement with previous calculations that are…

Astrophysics · Physics 2009-10-30 Andrei V. Gruzinov , John N. Bahcall

In this review, we present and discussed the main trends in photovoltaics with emphasize on the conversion efficiency limits. The theoretical limits of various photovoltaics device concepts are presented and analyzed using a flexible…

Materials Science · Physics 2014-02-11 Fahhad H Alharbi , Sabre Kais

Antimony selenide (Sb2Se3) is at the forefront of an emerging class of sustainable photovoltaic materials. Despite notable developments over the past decade, the light-to-electricity conversion efficiency of Sb2Se3 has reached a plateau of…

Materials Science · Physics 2024-06-12 Xinwei Wang , Seán R. Kavanagh , David O. Scanlon , Aron Walsh

The Shockley-Queisser (SQ) limit, introduced by W. Shockley and H. J. Queisser in 1961, is the most well-established fundamental efficiency limit for single-junction photovoltaic solar cells. For widely-studied semiconductors such as Si,…

Applied Physics · Physics 2021-06-09 Qian Zhou , Arfa Karani , Yaxiao Lian , Baodan Zhao , Richard H. Friend , Dawei Di

The theoretical maximum efficiency of a solar cell is typically characterized by a detailed balance of optical absorption and emission for a semiconductor in the limit of unity radiative efficiency and an ideal step-function response for…

Applied Physics · Physics 2021-03-09 Joeson Wong , Stefan T. Omelchenko , Harry A. Atwater

Single-junction photovoltaic cells are considered to be efficient solar energy converters, but even ideal cells cannot exceed the their fundamental thermodynamic efficiency limit, first analysed by Shockley and Queisser (SQ). For moderated…

Optics · Physics 2015-05-21 Assaf Manor , Carmel Rotschild

Establishing the fundamental limit of nanophotonic light-trapping schemes is of paramount importance and is becoming increasingly urgent for current solar cell research. The standard theory of light trapping demonstrated that absorption…

Optics · Physics 2016-07-13 Zongfu Yu , Aaswath Raman , Shanhui Fan

Improving the conversion efficiency of solar energy to electricity is most important to mankind. For single-junction photovoltaic solar-cells, the Shockley-Queisser thermodynamic efficiency limit is extensively due to the heat dissipation,…

Optics · Physics 2015-06-11 Assaf Manor , Leopoldo L. Martin , Carmel Rotschild

We develop a new approach to calculate the obtainable limit of photoconversion efficiency of tandem solar cells (SCs) and applied it to SCs with both vertical and lateral designs at AM0 and AM1.5 conditions. To get the maximum efficiency,…

Materials Science · Physics 2013-09-13 A. V. Sachenko , V. P. Kostylyov , N. P. Kulish , I. O. Sokolovskyi , A. I. Shkrebtii

The Shockley-Queisser (SQ) limit provides a convenient metric for predicting light-to-electricity conversion efficiency of a solar cell based on the band gap of the light-absorbing layer. In reality, few materials approach this radiative…

Computational Physics · Physics 2020-05-22 Sunghyun Kim , José A. Márquez , Thomas Unold , Aron Walsh

Concentrating solar power, particularly parabolic trough system with solar concentrations less than 50, requires spectrally selective solar absorbers that are thermally stable at high temperatures of 400degC above to achieve high…

Applied Physics · Physics 2020-12-16 Hassan Alshehri , Qing Ni , Sydney Taylor , Ryan McBurney , Hao Wang , Liping Wang

Light trapping in solar cells allows for increased current and voltage, as well as reduced materials cost. It is known that in geometrical optics, a maximum 4n^2 absorption enhancement factor can be achieved by randomly texturing the…

Optics · Physics 2015-04-07 Vidya Ganapati , Owen D. Miller , Eli Yablonovitch

We analyze standard theoretical models of solar energy conversion developed to study solar cells and photosynthetic systems. We show that the assumption that the energy transfer to the reaction center/electric circuit is through a decay…

Quantum Physics · Physics 2017-01-31 David Gelbwaser-Klimovsky , Alán Aspuru-Guzik

For commercial one-sun solar modules, up to 80% of the incoming sunlight may be dissipated as heat, potentially raising the temperature 20 C - 30 C higher than the ambient. In the long term, extreme self-heating erodes efficiency and…

In this study, the theoretical maximum efficiency $\eta_{max}$ and the Boltzmann-type factor giving the concentration ratio of excited-to-ground state pigment-molecules for photosynthetic systems under irradiation with arbitrary photon flux…

Statistical Mechanics · Physics 2025-12-17 Tetsuo Yabuki

We evaluate entropy production in a photovoltaic cell that is modeled by four electronic levels resonantly coupled to thermally populated field modes at different temperatures. We use a formalism recently proposed, the so-called multiple…

Mesoscale and Nanoscale Physics · Physics 2017-05-22 Mohammad H. Ansari

We derive the photovoltaic conversion efficiency limit for two-terminal tandem solar cells with a perovskite top cell and silicon bottom cell with an embedded spectrum splitter. For large-bandgap top-cells a spectrum splitter strongly…

Optics · Physics 2020-12-24 Verena Neder , Stefan W. Tabernig , Albert Polman

The incoherence of sunlight has long been suspected to have an impact on solar cell energy conversion efficiency, although the extent of this is unclear. Existing computational methods used to optimize solar cell efficiency under incoherent…

Optics · Physics 2014-01-16 Aline Herman , Michael Sarrazin , Olivier Deparis

It has gradually been recognized that incoming sunlight can be trapped within a high refractive index semiconductor, n~3.5, owing to the narrow 16degree escape cone. The solar light inside a semiconductor is 4n^2 times brighter than…

Optics · Physics 2024-05-16 Eli Yablonovitch , Zunaid Omair

Light fusion increases the efficiency of solar cells by converting photons with lower energy than the bandgap into higher energy photons. The solar cell converts the product photons to current. We use Monte Carlo simulation to predict that…

Mesoscale and Nanoscale Physics · Physics 2021-12-20 Benedicta Sherrie , Alison M. Funston , Laszlo Frazer