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A new thermodynamic limit for the open circuit voltage of solar cells that includes thermalization is obtained in terms of photon entropy. A simple graphical construction makes it possible to link this limit to the existing limits for…
An isolated single-junction solar cell's temperature in outer space depends only on its radiation exchange with its environment. We consider a cell with zero emissivity below its bandgap and unity above it -- an idealization so far…
The fundamental efficiency limit of a single bandgap solar cell is about 31% at one sun with a bandgap of about Eg = 1.35 eV (1), determined by the trade-off of maximising current with a smaller bandgap and voltage with a larger bandgap.…
We introduce a limit for the strength of coupling light into the modes of solar cells. This limit depends on both a cell's thickness and its modal properties. For a cell with refractive index n and thickness d, we obtain a maximal coupling…
Variability of the energy output throughout the day/night poses a major hurdle to the widespread adoption of photovoltaic systems. An integrated photovoltaic (PV) and electrochemical (EC)-storage system offers a solution, but the…
It is currently possible to fabricate crystalline silicon solar cells with the absorber thickness ranging from a few hundreds of micrometers (conventional wafer-based cells) to devices as thin as $1\,\mu\mathrm{m}$. In this work, we use a…
The thermodynamic limit of photovoltaic efficiency for a single-junction solar cell can be readily predicted using the bandgap of the active light absorbing material. Such an approach overlooks the energy loss due to non-radiative…
Light trapping for solar cells can reduce production cost and improve energy conversion efficiency. Understanding some of the basic theoretical constraints on light trapping is therefore of fundamental importance. Here, we develop a general…
Understanding the maximal enhancement of solar absorption in semiconductor materials by light trapping promises the development of affordable solar cells. However, the conventional Lambertian limit is only valid for idealized material…
The Shockley-Queisser (S-Q) theory defines the thermodynamic upper limits for Jsc, Voc, FF, and efficiency of a solar cell. The classical calculation assumes an abrupt onset of absorption at the band-edge, perfect absorption for all…
The Shockley-Queisser limit describes the maximum solar energy conversion efficiency achievable for a particular material and is the standard by which new photovoltaic technologies are compared. This limit is based on the principle of…
Solar photons possessing energy less than the band-gap of a single-junction solar cell can be utilized via the up-conversion (UC) of two or more photons, resulting in the emission of a single above-bandgap photon. Due to the non-linear…
The thermodynamic limit for the efficiency of solar cells is predominantly defined by the energy bandgap of the used semiconductor. In case of organic solar cells both energetics and kinetics of three different species play role: excitons,…
Methods of exceeding the detailed balance limit for a single junction solar cell have included down-converting high energy photons to produce two photons; and carrier multiplication, whereby high energy photons produce more than one…
Photovoltaic materials are recognized for their potential as sustainable energy sources that enable the conversion between light and electrical energy. However, solar cells have been unable to surpass the theoretical limit of 32%, known as…
The hotness of the sun and the coldness of the outer space are inexhaustible thermodynamic resources for human beings. From a thermodynamic point of view, any energy conversion systems that receive energy from the sun and/or dissipate…
A high theoretical efficiency of 47.2% was achieved by a novel combination of In0.51Ga0.49P, GaAs, In0.24Ga0.76As and In0.19Ga0.81Sb subcell layers in a simulated quadruple junction solar cell under 1 sun concentration. The electronic…
We propose a solar thermal energy conversion system consisting of a solar absorber, a thermoradiative cell or negative illumination photodiode, and a photovoltaic cell. Because it is a heat engine, this system can also be paired with…
We theoretically demonstrate the fundamental limit in volume for given materials (e.g. Si, a-Si, CdTe) to fully absorb the solar radiation above bandgap, which we refer as solar superabsorption limit. We also point out the general…
Luminescent solar concentrators (LSCs) are theoretically able to concentrate both direct and diffuse solar radiation with extremely high efficiencies. Photon-multiplier luminescent solar concentrators (PM-LSCs) contain chromophores which…