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Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

Quantum Physics · Physics 2025-10-08 Smitarani Mishra , Shaon Sahoo

A new axiomatic characterization with a minimum of conditions for entropy as a function on the set of states in quantum mechanics is presented. Traditionally unspoken assumptions are unveiled and replaced by proven consequences of the…

Mathematical Physics · Physics 2014-07-02 Bernhard Baumgartner

We develop the argument that the Gibbs-von Neumann entropy is the appropriate statistical mechanical generalisation of the thermodynamic entropy, for macroscopic and microscopic systems, whether in thermal equilibrium or not, as a…

Quantum Physics · Physics 2008-01-23 O. J. E. Maroney

The von Neumann entropy is a key quantity in quantum information theory and, roughly speaking, quantifies the amount of quantum information contained in a state when many identical and independent i.i.d. copies of the state are available,…

Quantum Physics · Physics 2019-06-05 P. Boes , J. Eisert , R. Gallego , M. P. Mueller , H. Wilming

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

Thermodynamics teaches that if a system initially off-equilibrium is coupled to work sources, the maximum work that it may yield is governed by its energy and entropy. For finite systems this bound is usually not reachable. The maximum…

Statistical Mechanics · Physics 2009-11-10 A. E. Allahverdyan , R. Balian , Th. M. Nieuwenhuizen

Observational entropy -- a quantity that unifies Boltzmann's entropy, Gibbs' entropy, von Neumann's macroscopic entropy, and the diagonal entropy -- has recently been argued to play a key role in a modern formulation of statistical…

Quantum Physics · Physics 2026-03-24 Teruaki Nagasawa , Kohtaro Kato , Eyuri Wakakuwa , Francesco Buscemi

Thermodynamics can be formulated in either of two approaches, the phenomenological approach, which refers to the macroscopic properties of systems, and the statistical approach, which describes systems in terms of their microscopic…

Quantum Physics · Physics 2019-05-01 Mirjam Weilenmann , Lea Krämer Gabriel , Philippe Faist , Renato Renner

We introduce an ergotropy-based formulation of quantum thermodynamics, which provides a strong connection between average heat and von Neumann entropy. By adopting this formulation, we can reinterpret the infinitesimal average heat in terms…

Quantum Physics · Physics 2025-11-26 J. M. Z. Choquehuanca , P. A. C. Obando , M. S. Sarandy , F. M. de Paula

Thermodynamics describes large-scale, slowly evolving systems. Two modern approaches generalize thermodynamics: fluctuation theorems, which concern finite-time nonequilibrium processes, and one-shot statistical mechanics, which concerns…

Statistical Mechanics · Physics 2018-05-30 Nicole Yunger Halpern , Andrew J. P. Garner , Oscar C. O. Dahlsten , Vlatko Vedral

Many physicists think that the maximum entropy formalism is a straightforward application of Bayesian statistical ideas to statistical mechanics. Some even say that statistical mechanics is just the general Bayesian logic of inductive…

Statistical Mechanics · Physics 2007-05-23 Cosma Rohilla Shalizi

Heisenberg's uncertainty principle is formulated for a set of generalized measurements within the framework of majorization theory, resulting in a partial uncertainty order on probability vectors that is stronger than those based on…

Quantum Physics · Physics 2012-10-26 M. Hossein Partovi

Thermalization of isolated many-body systems is demonstrated by generalizing an approach originally due to von Neumann: For arbitrary initial states with a macroscopically well-defined energy, quantum mechanical expectation values become…

Statistical Mechanics · Physics 2015-07-02 Peter Reimann

We derive a universal inequality that provides a lower bound on the ensemble-averaged von Neumann entropy change in a quantum system subject to continuous measurement and dissipation. Our result clarifies how entropy production is…

Quantum Physics · Physics 2025-06-17 Kohei Kobayashi

We study the entropy of small subsystems in thermalizing quantum many-body systems governed by local Hamiltonians. Assuming the eigenstate thermalization hypothesis, we derive an analytical formula for the von Neumann entropy of…

Statistical Mechanics · Physics 2025-02-03 Yichen Huang

We study an entropy measure for quantum systems that generalizes the von Neumann entropy as well as its classical counterpart, the Gibbs or Shannon entropy. The entropy measure is based on hypothesis testing and has an elegant formulation…

Quantum Physics · Physics 2014-02-19 F. Dupuis , L. Kraemer , P. Faist , J. M. Renes , R. Renner

In this note we lay some groundwork for the resource theory of thermodynamics in general probabilistic theories (GPTs). We consider theories satisfying a purely convex abstraction of the spectral decomposition of density matrices: that…

Quantum Physics · Physics 2015-11-06 Howard Barnum , Jonathan Barrett , Marius Krumm , Markus P. Müller

Entanglement measures find frequent application in the study of topologically ordered systems, where the presence of topological order is reflected in an additional contribution to the entanglement of the system. Obtaining this topological…

Strongly Correlated Electrons · Physics 2014-05-07 Claudio Castelnovo

The concept of entropy is fundamental to thermalization, yet appears at odds with basic principles in quantum mechanics. Statistical mechanics relies on the maximization of entropy for a system at thermal equilibrium. However, an isolated…

This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized…

Quantum Physics · Physics 2015-08-14 Marius Krumm
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