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In search of a reliable methodology for the prediction of light absorption and emission of Ce$^{3+}$-doped luminescent materials, 13 representative materials are studied with first-principles and semiempirical approaches. In the…

Materials Science · Physics 2017-08-22 Yongchao Jia , Samuel Poncé , Anna Miglio , Masayoshi Mikami , Xavier Gonze

In this work we have studied the defect structure and corresponding defect concentration investigations through the theoretical, experimental and computational works on B2-type Fe-Al alloys. We have used ab initio framework in order to…

Materials Science · Physics 2021-01-19 Halil İbrahim Sözen , Tilmann Hickel , Jörg Neugebauer

Topological insulators embody a new state of matter characterized entirely by the topological invariants of the bulk electronic structure rather than any form of spontaneously broken symmetry. Unlike the 2D quantum Hall or quantum…

Pure Topological Insulating materials preserve a unique electronic state comprising of bulk insulating gap and conducting surface states. Here we use bulk Bi2Se3 single crystals possessing Se vacancy defects as a prototype topological…

Materials Science · Physics 2019-08-13 Amit Jash , Kamalika Nath , T. R. Devidas , A. Bharathi , S. S. Banerjee

Beta-phase gallium oxide (beta-Ga2O3) is prone to the spontaneous formation of donor defects but poses a formidable challenge in achieving high-quality p-type doping, mainly due to its exceptionally low valence band maximum (VBM). In this…

Materials Science · Physics 2025-01-24 Chenxi Nie , Kai Liu , Chengxuan Ke , Xisong Jiang , Yifeng He , Yonghong Deng , Yanhua Yan , Guangfu Luo

Two-dimensional (2D) $\beta$-TeO$_2$ has gained attention as a promising material for optoelectronic and power device applications, thanks to its transparency and high hole mobility. However, the underlying mechanism behind its $p$-type…

Mesoscale and Nanoscale Physics · Physics 2025-01-08 Rafael Costa-Amaral , Soungmin Bae , Vu Thi Ngoc Huyen , Yu Kumagai

We study the formation energies of native point defects in GaN through density-functional theory. In our first-principles scheme, the band edges are positioned in accord with hybrid density functional calculations, thus yielding a band-gap…

Materials Science · Physics 2017-04-12 Giacomo Miceli , Alfredo Pasquarello

Superconducting CuxBi2Se3 has attracted significant attention as a candidate topological superconductor. Besides inducing superconductivity, the introduction of Cu atoms to this material has also been observed to produce a number of unusual…

The carrier type and density in Bi2Se3 single crystals are systematically tuned by introducing a calcium (Ca) dopant. A carrier density of ~1x1017 cm-3 which corresponds to ~25 meV in the Fermi energy is obtained in both n- and p-type…

Materials Science · Physics 2015-05-19 Zhiyong Wang , Tao Lin , Peng Wei , Xinfei Liu , Randy Dumas , Kai Liu , Jing Shi

Topological insulators possess a non-conductive bulk and present surface states, henceforth, they are electrically conductive along their boundaries. Bismuth selenide ($Bi_2Se_3$) is one of the most promising topological insulators.…

We theoretically investigate defect formation energies in LaO$X$S$_2$ ($X=$Sb, Bi) using first-principles calculation. We find that the oxygen vacancy is relatively stable, where its formation energy is higher in $X=$ Sb than in $X=$ Bi. An…

Materials Science · Physics 2022-03-23 Masayuki Ochi , Kazuhiko Kuroki

We report molecular beam epitaxy growth of Sr-doped Bi$_2$Se$_3$ films on (111) BaF$_2$ substrate, aimed to realize unusual superconducting properties inherent to Sr$_x$Bi$_2$Se$_3$ single crystals. Despite wide range of the compositions,…

Using the density functional tight binding method (DFTB) and the GFN1-xTB (Geometries, Frequencies, and Noncovalent interactions Tight Binding) Hamiltonian, we have investigated the structural, electronic and magnetic properties of vacancy…

Materials Science · Physics 2025-09-25 Taoufik Sakhraoui , František Karlický

We studied native point defects in CaS by DFT+ Hubbard U method. The effect of the localization of the d orbitals of Ca pseudopotential has been included. The Hubbard U corrected d-orbital for Ca sites are playing a role assisting the…

Materials Science · Physics 2015-07-23 Bolong Huang

Using first-principles electronic structure calculations we identify the anion vacancies in II-VI and chalcopyrite Cu-III-VI2 semiconductors as a class of intrinsic defects that can exhibit metastable behavior. Specifically, we predict…

Materials Science · Physics 2009-11-11 S. Lany , A. Zunger

Bi$_2$Se$_3$ is a topological insulator whose unique properties result from topological surface states (TSS) in the band gap. The adsorption of Cs onto a Bi$_2$Se$_3$ surface is investigated by low energy ion scattering and work function…

Mesoscale and Nanoscale Physics · Physics 2019-01-09 Haoshan Zhu , Weimin Zhou , Jory A. Yarmoff

We study the stability and electronic properties of intrinsic point defects, vacancy and self-interstitial, in mono- and bi-layer phosphorene. We calculate the formation energies, quasiparticle defect states and charge transition levels…

Materials Science · Physics 2020-07-01 Sudipta Kundu , Mit H. Naik , Manish Jain

Nematic superconductivity is a novel class of superconductivity characterized by spontaneous rotational-symmetry breaking in the superconducting gap amplitude and/or Cooper-pair spins with respect to the underlying lattice symmetry. Doped…

Superconductivity · Physics 2018-12-27 Shingo Yonezawa

The gapped Dirac-like surface states of compensated magnetic topological insulator MnBi$_{2-x}$Sb$_x$Te$_4$ (MBST) are a promising host for exotic quantum phenomena such as the quantum anomalous Hall effect and axion insulating states.…

Mesoscale and Nanoscale Physics · Physics 2023-12-08 Felix Lüpke , Marek Kolmer , Jiaqiang Yan , Hao Chang , Paolo Vilmercati , Hanno H. Weitering , Wonhee Ko , An-Ping Li

In this work we aim at understanding the effect of n-type and p-type substitutional doping in the case of matrix-embedded and freestanding Si nanocrystals. By means of ab-initio calculations we identify the preferential positioning of the…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 Roberto Guerra , Stefano Ossicini