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We study theoretically the effects of short-range electron-electron interactions on the electronic structure of graphene, in the presence of single substitutional impurities. Our computational approach is based on the $\pi$ orbital…

Mesoscale and Nanoscale Physics · Physics 2015-11-30 Faluke Aikebaier , Anna Pertsova , Carlo M. Canali

Raman spectroscopy is a fast, non-destructive means to characterize graphene samples. In particular, the Raman spectra show a significant dependence on doping. While the change in position and width of the G peak can be explained by the…

Materials Science · Physics 2015-05-13 D. M. Basko , S. Piscanec , A. C. Ferrari

The band gap of periodically-doped graphene with hydrogen is investigated. It is found through a tight-binding model (TB) that for certain periodicities, called here NGPs (non-gap periodicities), no gap is opened at the Dirac point. This…

Materials Science · Physics 2010-12-15 Juan Maria Garcia-Lastra

In this work we investigate doping and temperature dependences of electronic structure of system with strong electronic correlations and strong electron-phonon interaction modeling cuprates in the frameworks of the three-band p-d-Holstein…

Strongly Correlated Electrons · Physics 2016-12-09 I. A. Makarov , S. G. Ovchinnikov

Nitrogen-doped epitaxial graphene grown on SiC(000?1) was prepared by exposing the surface to an atomic nitrogen flux. Using Scanning Tunneling Microscopy (STM) and Spectroscopy (STS), supported by Density Functional Theory (DFT)…

The conductivity of graphene on a boron nitride substrate exhibits features in the terahertz (THz) and infrared (IR) frequency regimes that are associated with the periodic moir\'e pattern formed by the weakly coupled two-dimensional…

Mesoscale and Nanoscale Physics · Physics 2015-10-14 Ashley M. DaSilva , Jeil Jung , Shaffique Adam , Allan H. MacDonald

Since lattice strain and charge density affect various material properties of graphene, a reliable and efficient method is required for quantification of the two variables. While Raman spectroscopy is sensitive and non-destructive, its…

Mesoscale and Nanoscale Physics · Physics 2020-08-10 Gwanghyen Ahn , Sunmin Ryu

We demonstrate electrochemical top gating of graphene by using a solid polymer electrolyte. This allows to reach much higher electron and hole doping than standard back gating. In-situ Raman measurements monitor the doping. The G peak…

At low energy, electrons in doped graphene sheets behave like massless Dirac fermions with a Fermi velocity which does not depend on carrier density. Here we show that modulating a two-dimensional electron gas with a long-wavelength…

Mesoscale and Nanoscale Physics · Physics 2009-06-29 M. Gibertini , A. Singha , V. Pellegrini , M. Polini , G. Vignale , A. Pinczuk , L. N. Pfeiffer , K. W. West

The properties of graphene-like BC$_6$N semiconductor are studied using density functional theory taking into account the attractive interaction between B and N atoms. In the presence of a strong attractive interaction between B and N…

Mesoscale and Nanoscale Physics · Physics 2021-08-03 Nzar Rauf Abdullah , Botan Jawdat Abdullah , Chi-Shung Tang , Vidar Gudmundsson

The density of states and the band diagrams were computed for diamond, cubic boron nitrde (cBN), and hexagonal boron nitride (hBN) using a Korringa-Kohn-Rostoker (KKR) scheme to investigate the shift of the Fermi level by impurity-atom…

Materials Science · Physics 2014-12-11 Koji Kobashi

Man-made artificial graphene has attracted significant attention in the past few years due to the possibilities to construct designer Dirac fermions with unexpected topological properties and applications in nanoelectronics. Here we use a…

Materials Science · Physics 2014-12-10 Matti Ropo , Sami Paavilainen , Jaakko Akola , Esa Räsänen

Among the different strategies used to induce the opening of a band gap in graphene, one common practice is through chemical doping. While a gap may me opened in this way, disorder-induced scattering is an unwanted side-effect that impacts…

Mesoscale and Nanoscale Physics · Physics 2016-06-22 James A Lawlor , Claudia G Rocha , Vanessa Torres , Andrea Latgé , Mauro Ferreira

We demonstrated doping in 2D monolayer graphene via local electrical stressing. The doping, confirmed by the resistance-voltage transfer characteristics of the graphene system, is observed to continuously tunable from N-type to P-type as…

Materials Science · Physics 2015-05-27 Tianhua Yu , Chen-Wei Liang , Changdong Kim , Bin Yu

Doping of semiconductor is necessary for various device applications. Exploiting chemistry at its reactive edges was shown to be an effective way to dope an atomically thin graphene nanoribbon (GNR) for realizing new devices in recent…

Mesoscale and Nanoscale Physics · Physics 2011-07-26 Yijian Ouyang , Stefano Sanvito , Jing Guo

We report a Raman spectroscopy study of graphene field-effect transistors (GFET) with a controlled amount of defects introduced in graphene by exposure to electron-beam irradiation. Raman spectra are taken at T = 8 K over a range of back…

Materials Science · Physics 2015-06-22 Isaac Childres , Luis A. Jauregui , Yong P. Chen

Graphene physisorbed on a metal has its characteristic Dirac cones preserved in the band-structure, but the Fermi level of the system is shifted due to the interaction with the substrate. Based on density functional calculations with van…

Materials Science · Physics 2012-01-26 J. Slawinska , I. Zasada

Zigzag edges of neutral armchair-oriented Graphene Nano-Ribbons show states strongly localized at those edges. They behave as free radicals that can capture electrons during processing, increasing ribbon's stability. Thus, charging and its…

Mesoscale and Nanoscale Physics · Physics 2019-07-26 E. Louis , E. San-Fabian , G. Chiappe , J. A. Verges

Recent experimental findings and theoretical predictions suggest that nitrogen-doped CVD-grown graphene may give rise to electronic band gaps due to impurity distributions which favour segregation on a single sublattice. Here we demonstrate…

Mesoscale and Nanoscale Physics · Physics 2016-02-09 Thomas Aktor , Antti-Pekka Jauho , Stephen R. Power

Stanene is a quantum spin hall insulator and a promising material for electronic and optoelectronic devices. Density functional theory (DFT) calculations are performed to study the band gap opening in stanene by elemental mono- (B, N) and…

Materials Science · Physics 2017-01-02 Priyanka Garg , Indrani Choudhuri , Arup Mahata , Biswarup Pathak