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Penta-graphene is a quasi-two-dimensional carbon allotrope consisting of a pentagonal lattice in which both sp2 and sp3-like carbons are present. Unlike graphene, penta-graphene exhibits a non-zero bandgap, which opens the possibility of…

Here we report a facile method to generate a high density of point defects in graphene on metal foil and show how the point defects affect the electronic structures of graphene layers. Our scanning tunneling microscopy (STM) measurements,…

Mesoscale and Nanoscale Physics · Physics 2013-10-08 Hui Yan , Cheng-Cheng Liu , Ke-Ke Bai , Xuejiao Wang , Mengxi Liu , Wei Yan , Lan Meng , Yanfeng Zhang , Zhongfan Liu , Jia-Cai Nie , Yugui Yao , Lin He

We investigated a suspended bilayer graphene where the bottom (top) layer is doped by boron (nitrogen) substitutional atoms by using Density Functional Theory (DFT) calculations. We found that at high dopant concentration (one B-N pair…

Materials Science · Physics 2016-05-25 Daniele Giofré , Davide Ceresoli , Mario I. Trioni

We study proximity effects in clean nanoscale superconductor-normal metal-superconductor (S$\mid$N$\mid$S) graphene heterostructures using a self-consistent numerical solution to the continuum Dirac Bogoliubov-de Gennes (DBdG) equations. We…

Superconductivity · Physics 2015-05-28 Klaus Halterman , Oriol T. Valls , Mohammad Alidoust

Tuning the charge carrier density of two-dimensional (2D) materials by incorporating dopants into the crystal lattice is a challenging task. An attractive alternative is the surface transfer doping by adsorption of molecules on 2D crystals,…

By means of density functional theory (DFT) calculations we have quantitatively estimated the impact of the spontaneous polarization (SP) of the SiC(0001) substrate on the electronic properties of quasi-freestanding graphene (QFG) decoupled…

Materials Science · Physics 2015-01-27 J. Slawinska , H. Aramberri , J. I. Cerdà

The presence of defects such as vacancies in solids has prominent effects on their mechanical properties. It not only modifies the stiffness and strength of materials, but also changes their morphologies. The latter effect is extremely…

Mesoscale and Nanoscale Physics · Physics 2015-08-13 Zhigong Song , Zhiping Xu

Graphene is an ideal platform to study many-body effects due to its semimetallic character and the possibility to dope it over a wide range. Here we study the width of graphene's occupied $\pi$-band as a function of doping using…

Strongly Correlated Electrons · Physics 2016-08-10 Søren Ulstrup , Malte Schüler , Marco Bianchi , Felix Fromm , Christian Raidel , Thomas Seyller , Tim Wehling , Philip Hofmann

We demonstrated doping in 2D monolayer graphene via local electrical stressing. The doping, confirmed by the resistance-voltage transfer characteristics of the graphene system, is observed to continuously tunable from N-type to P-type as…

Materials Science · Physics 2015-05-27 Tianhua Yu , Chen-Wei Liang , Changdong Kim , Bin Yu

In view of the many quantum field theoretical descriptions of graphene in $2+1$ dimensions, we present another field theoretical feature of graphene, in the presence of defects. Particularly, we shall be interested in gapped graphene in the…

High Energy Physics - Theory · Physics 2015-06-30 V. K. Oikonomou

The interaction between substitutional nitrogen atoms in graphene is studied by performing first principles calculations. The nearest neighbor interaction between nitrogen dopants is highly repulsive because of the strong electrostatic…

Materials Science · Physics 2015-03-19 Hongjun Xiang , Bing Huang , Zhenyu Li , Su-Huai Wei , Jinlong Yang , Xingao Gong

Crystallographic defects play a key role in determining the properties of crystalline materials. The new class of two-dimensional materials, foremost graphene, have enabled atomically resolved studies of defects, such as vacancies, grain…

Materials Science · Physics 2015-06-22 Ossi Lehtinen , Nilesh Vats , Gerardo Algara-Siller , Pia Knyrim , Ute Kaiser

The doping of graphene to tune its electronic structure is essential for its further use in carbon based electronics. Adapting strategies from classical silicon based semiconductor technology, we use the incorporation of heteroatoms in the…

A significant advance toward achieving practical applications of graphene as a two-dimensional material in nanoelectronics would be provided by successful synthesis of both n-type and p-type doped graphene. However reliable doping and a…

Mesoscale and Nanoscale Physics · Physics 2013-10-24 Yu-Fen Lu , Shun-Tsung Lo , Jheng-Cyuan Lin , Wenjing Zhang , Jing-Yu Lu , Fan-Hung Liu , Chuan-Ming Tseng , Yi-Hsien Lee , Chi-Te Liang , Lain-Jong Li

Strains strongly affect the properties of low-dimensional materials, such as graphene. By combining in situ, in operando, reflection high energy electron diffraction experiments with first-principles calculations, we show that large…

Materials Science · Physics 2013-09-03 Nils Blanc , Fabien Jean , Arkady V. Krasheninnikov , Gilles Renaud , Johann Coraux

The electrical, magnetic, thermal and optical characteristics of Gallium (Ga) doped silicene are investigated using density functional theory (DFT). The effect of doping is studied by tuning dopant concentrations as well as examining varied…

Materials Science · Physics 2022-04-05 Nzar Rauf Abdullah , Botan Jawdat Abdullah , Vidar Gudmundsson

DFT calculation of various atomic species on graphene sheet is investigated as prototypes for formation of nano-structures on carbon nanotube (CNT) wall. We investigate computationally adsorption energies and adsorption sites on graphene…

Materials Science · Physics 2009-11-13 Akira Ishii , Masana Yamamoto , Hiroki Asano , Katsutoshi Fujiwara

Doped graphene sheets are pseudochiral two-dimensional Fermi liquids with abnormal electron-electron interaction physics. We address graphene's Fermi liquid properties quantitatively using a microscopic random-phase-approximation theory and…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Marco Polini , Reza Asgari , Yafis Barlas , T. Pereg-Barnea , A. H. MacDonald

For carbon-based materials, in contrast to metal surfaces, the relationship between strain and reactivity is not yet established, even though there are literature reports on strained graphene. Knowledge of such relationships would be…

Defects change essentially not only electronic but also chemical properties of graphene being centers of its chemical activity. Their functionalization is a way to modify electronic and crystal structure of graphene which may be important…

Materials Science · Physics 2009-01-05 D. W. Boukhvalov , M. I. Katsnelson