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The effective interaction between two planar walls immersed in a fluid is investigated by use of Density Functional Theory in the super-critical region of the phase diagram. A hard core Yukawa model of fluid is studied with special…

Statistical Mechanics · Physics 2017-04-05 Pietro Anzini , Alberto Parola

The subtle interplay between critical phenomena and electrostatics is investigated by considering the effective force acting on two parallel walls confining a near-critical binary liquid mixture with added salt. The ion-solvent coupling can…

Soft Condensed Matter · Physics 2011-09-13 Markus Bier , Andrea Gambassi , Martin Oettel , S. Dietrich

Recent experiments have measured the critical Casimir force acting on a colloid immersed in a binary liquid mixture near its continuous demixing phase transition and exposed to a chemically structured substrate. Motivated by these…

Statistical Mechanics · Physics 2013-11-27 Francesco Parisen Toldin , Matthias Tröndle , S. Dietrich

The Casimir effect in quantum electrodynamics (QED) is perhaps the best-known example of fluctuation-induced long-ranged force acting on objects (conducting plates) immersed in a fluctuating medium (quantum electromagnetic field in vacuum).…

Statistical Mechanics · Physics 2009-07-13 Andrea Gambassi

Recently there is strong experimental and theoretical interest in studying the self-assembly and the phase behavior of patchy and of Janus particles, which form colloidal suspensions. Although in this quest a variety of effective…

Soft Condensed Matter · Physics 2016-05-18 M. Labbé-Laurent , S. Dietrich

Effective colloid-colloid interactions can be tailored through the addition of a complex cosolute. Here we investigate the case of a cosolute made by self-assembling patchy particles. Depending on the valence, these particles can form…

Soft Condensed Matter · Physics 2019-02-08 Nicolás Ariel García , Nicoletta Gnan , Emanuela Zaccarelli

The addition of co-solutes to colloidal suspensions is often employed to induce tunable depletion interactions. In this work we investigate effective colloidal interactions arising from binary co-solute mixtures of hard spheres and patchy…

Soft Condensed Matter · Physics 2021-08-25 Philip H. Handle , Emanuela Zaccarelli , Nicoletta Gnan

If two ore more bodies are immersed in a critical fluid critical fluctuations of the order parameter generate long ranged forces between these bodies. Due to the underlying mechanism these forces are close analogues of the well known…

Soft Condensed Matter · Physics 2009-10-30 M. Krech

Confining in space the equilibrium fluctuations of statistical systems with long-range correlations is known to result into effective forces on the boundaries. Here we demonstrate the occurrence of Casimir-like forces in the non-equilibrium…

Soft Condensed Matter · Physics 2024-03-04 Giuseppe Fava , Andrea Gambassi , Francesco Ginelli

Using quasi-exact numerical density-matrix renormalization-group techniques we calculate the critical Casimir force for a two-dimensional (2D) Ising strip with equal strong surface fields, along the thermodynamic paths corresponding to the…

Statistical Mechanics · Physics 2015-06-17 M. Zubaszewska , A. Maciołek , A. Drzewiński

Recent experiments have demonstrated a fluctuation-induced lateral trapping of spherical colloidal particles immersed in a binary liquid mixture near its critical demixing point and exposed to chemically patterned substrates. Inspired by…

Soft Condensed Matter · Physics 2014-05-09 M. Labbé-Laurent , M. Tröndle , L. Harnau , S. Dietrich

We develop a discretized theory of thermal Casimir interactions to numerically calculate the interactions between fluctuating dielectrics. From a constrained partition function we derive a surface free energy, while handling divergences…

Statistical Mechanics · Physics 2009-11-13 S. Pasquali , F. Nitti , A. C. Maggs

We present a new Monte Carlo method to calculate Casimir forces acting on objects in a near-critical fluid, considering the two basic cases of a wall and a sphere embedded in a two-dimensional Ising medium. During the simulation, the…

Statistical Mechanics · Physics 2014-06-19 Hendrik Hobrecht , Alfred Hucht

We study the behavior of the critical Casimir force and its interplay with the van der Waals force acting between two parallel slabs separated at a distance $L$ from each other confining a non-polar simple fluid or a binary liquid mixture.…

Statistical Mechanics · Physics 2015-07-20 Galin Valchev , Daniel Dantchev

We calculate the effective fluctuation induced force between spherical or disk-like colloids trapped at a flat, fluid interface mediated by thermally excited capillary waves. This Casimir type force is determined by the partition function…

Soft Condensed Matter · Physics 2007-11-13 H. Lehle , M. Oettel

The confinement of long-ranged critical fluctuations in the vicinity of second-order phase transitions in fluids generates critical Casimir forces acting on confining surfaces or among particles immersed in a critical solvent. This is…

Statistical Mechanics · Physics 2015-06-17 O. A. Vasilyev , S. Dietrich

Critical Casimir interactions represent a perfect example of bath-induced forces at mesoscales. These forces may have a relevant role in the living systems as well as a role in the design of nanomachines fueled by environmental…

Mesoscale and Nanoscale Physics · Physics 2023-12-20 Ignacio A. Martinez , Artyom Petrosyan , Sergio Ciliberto

We experimentally demonstrate that critical Casimir forces in colloidal systems can be continuously tuned by the choice of boundary conditions. The interaction potential of a colloidal particle in a mixture of water and 2,6-lutidine has…

Soft Condensed Matter · Physics 2009-10-23 Ursula Nellen , Laurent Helden , Clemens Bechinger

We analyze the depletion interaction between two hard colloids in a hard--sphere solvent and pay special attention to the limit of large size ratio between colloids and solvent particles which is governed by the well--known Derjaguin…

Soft Condensed Matter · Physics 2007-05-23 M. Oettel

When massless excitations are limited or modified by the presence of material bodies one observes a force acting between them generally called Casimir force. Such excitations are present in any fluid system close to its true bulk critical…

Statistical Mechanics · Physics 2016-10-05 Daniel M Dantchev , Vassil M Vassilev , Peter A Djondjorov