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We suggest and analyze a novel technique for efficient and robust creation of dense ultracold molecular ensembles in their ground rovibrational state. In our approach a molecule is brought to the ground state through a series of…

Quantum Physics · Physics 2009-11-13 Elena Kuznetsova , Philippe Pellegrini , Robin Côté , M. D. Lukin , S. F. Yelin

We report the creation of ultracold ground state $^{6}\textrm{Li}^{40}\textrm{K}$ polar molecules with high efficiency. Starting from weakly-bound molecules state, stimulated Raman adiabatic passage (STIRAP) is adopted to coherently…

Quantum Gases · Physics 2023-10-06 Canming He , Xiaoyu Nie , Victor Avalos , Sofia Botsi , Sunil Kumar , Anbang Yang , Kai Dieckmann

We report efficient all-optical creation of an ultracold gas of alkaline-earth-metal dimers, $^{88}\rm{Sr}_2$, in their absolute ground state. Starting with weakly bound singlet molecules formed by narrow-line photoassociation in an optical…

Atomic Physics · Physics 2021-11-01 K. H. Leung , E. Tiberi , B. Iritani , I. Majewska , R. Moszynski , T. Zelevinsky

We identify a route for the production of $^{87}$Rb$^{133}$Cs molecules in the $\textrm{X} \, ^1\Sigma^+$ rovibronic ground state that is compatible with efficient mixing of the atoms in optical lattices. We first construct a model for the…

We develop a complete theoretical description of photoassociative Stimulated Raman Adiabatic Passage (STIRAP) near a Feshbach resonance in a thermal atomic gas. We show that it is possible to use low intensity laser pulses to directly…

Quantum Physics · Physics 2015-05-13 Elena Kuznetsova , Susanne F. Yelin , Marko Gacesa , Philippe Pellegrini , Robin Côté

One possibility for the creation of ultracold, high-phase-space-density quantum gases of molecules in the rovibrational ground state relies on first associating weakly-bound molecules from quantum-degenerate atomic gases on a Feshbach…

We report the creation of ultracold samples of $^{39}$K$^{133}$Cs molecules in their rovibrational ground state. By investigating potentially suitable excited states using one- and two-photon spectroscopy, we have identified a pathway to…

Using the technique of stimulated Raman adiabatic passage (STIRAP) we have coherently transferred ultracold 87Rb2 Feshbach molecules into a more deeply bound vibrational quantum level. Our measurements indicate a high transfer efficiency of…

Other Condensed Matter · Physics 2009-11-11 K. Winkler , F. Lang , G. Thalhammer , P. v. d. Straten , R. Grimm , J. Hecker Denschlag

Ultracold paramagnetic and polar diatomic molecules are among the promising systems for quantum simulation of lattice-spin models. Unfortunately, their experimental observation is still challenging. Based on our recent \textit{ab-initio}…

We associate Sr atom pairs on sites of a Mott insulator optically and coherently into weakly-bound ground-state molecules, achieving an efficiency above 80\%. This efficiency is 2.5 times higher than in our previous work [S. Stellmer, B.…

Quantum Gases · Physics 2017-07-25 Alessio Ciamei , Alex Bayerle , Chun-Chia Chen , Benjamin Pasquiou , Florian Schreck

A narrow-linewidth, dual-wavelength laser system is vital for the creation of ultracold ground state molecules via stimulated Raman adiabatic passage (STIRAP) from a weakly bound Feshbach state. Here we describe how a relatively simple…

Atomic Physics · Physics 2015-05-21 P. D. Gregory , P. K. Molony , M. P. Köppinger , A. Kumar , Z. Ji , B. Lu , A. L. Marchant , S. L. Cornish

In this work we model and realize stimulated Raman adiabatic passage (STIRAP) in the diatomic $\mathrm{^{23}Na^{40}K}$ molecule from weakly bound Feshbach molecules to the rovibronic ground state via the…

We produce ultracold dense trapped samples of 87Rb133Cs molecules in their rovibrational ground state, with full nuclear hyperfine state control, by stimulated Raman adiabatic passage (STIRAP) with efficiencies of 90%. We observe the onset…

We report the comprehensive theoretical investigation of the Sr-SrOH system identifying it as a promising route to production of ultracold asymmetric top molecules. Combining high-level ab initio electronic structure calculations with…

Atomic Physics · Physics 2025-08-21 Maciej B. Kosicki , Mateusz Borkowski , Marcin Umiński , Piotr S. Żuchowski

We present spectra of ultracold $^7$Li$^{85}$Rb molecules in their electronic ground state formed by spontaneous decay of weakly bound photoassociated molecules. Beginning with atoms in a dual species magneto-optical trap (MOT), weakly…

Atomic Physics · Physics 2014-12-24 John Lorenz , Adeel Altaf , Sourav Dutta , Yong P. Chen , D. S. Elliott

We propose an improved photoassociation scheme to produce ultracold molecules in their vibronic ground state for the generic case where non-adiabatic effects facilitating transfer to deeply bound levels are absent. Formation of molecules is…

Atomic Physics · Physics 2008-10-28 Christiane P. Koch , Robert Moszynski

We consider a method of sub-wavelength superlocalization and patterning of atomic matter waves via a two dimensional stimulated Raman adiabatic passage (2D STIRAP) process. An atom initially prepared in its ground level interacts with a…

We report the creation of a sample of over 1000 ultracold $^{87}$RbCs molecules in the lowest rovibrational ground state, from an atomic mixture of $^{87}$Rb and Cs, by magnetoassociation on an interspecies Feshbach resonance followed by…

We have studied the formation of ultracold RbSr molecules with laser pulses. After discussing the advantages of the Mott insulator phase for the control with pulses, we present two classes of strategies. The first class involves two…

We report on a resonantly coupled 2(1) - 4 (1) photoassociation resonance in LiRb. This pair of states displays interesting decay physics that hint at interference-like effects caused by two different decay paths. We observe decay to…

Atomic Physics · Physics 2016-12-28 I. C. Stevenson , D. Blasing , Y. P. Chen , D. S. Elliott
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