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While doping and defects are often considered detrimental to material performance, at the nanoscale, modifications are needed to create novel properties beneficial for device applications. In this work, we focus on optimizing graphene as a…

Applied Physics · Physics 2025-05-21 Raju Kumar Yadav , Prince Philip , Boddepalli SanthiBhushan

Graphene has been widely studied for various applications due to its outstanding electrical and mechanical properties. However, its potential in thermoelectric applications has been limited by a low Seebeck coefficient and high thermal…

Materials Science · Physics 2024-04-04 Laura Caputo , Viet-Hung Nguyen , Jean-Christophe Charlier

A first-principles investigation of the electronic and quantum transport properties of double-walled carbon nanotubes doped with nitrogen and boron atoms is presented. Concentric nanotube sidewalls separated by the typical graphitic van der…

Materials Science · Physics 2016-03-24 Alejandro Lopez-Bezanilla

It is important to understand the electronic interaction between single-walled carbon nanotubes (SWNTs) and graphene in order to use them efficiently in multifunctional hybrid devices. Here we deposited SWNT bundles on graphene-covered…

Materials Science · Physics 2014-08-21 Rahul Rao , Neal Pierce , Archi Dasgupta

Using density functional theory (DFT), this work explores barium zirconate doped with nitrogen. In addition, we used density functional theory (DFT) to study the BaZrO$_3$'s electrical, optical, and structural properties, and we found that…

Materials Science · Physics 2024-06-11 Iftkhar Ahmad

We have investigated antidot lattices, which were prepared on exfoliated graphene single layers via electron-beam lithography and ion etching, by means of scanning Raman spectroscopy. The peak positions, peak widths and intensities of the…

Mesoscale and Nanoscale Physics · Physics 2011-07-01 S. Heydrich , M. Hirmer , C. Preis , T. Korn , J. Eroms , D. Weiss , C. Schüller

We present a theoretical study of the structural and electronic properties of graphene monolayer functionalized with boron and nitrogen atoms substituting carbon atoms. Our study is based on the ab initio calculations in the framework of…

Materials Science · Physics 2013-07-29 Magdalena Woinska , Karolina Z. Milowska , Jacek A. Majewski

We show by first-principles calculations that p-doped graphane is a conventional superconductor with a critical temperature (Tc) above the boiling point of liquid nitrogen. The unique strength of the chemical bonds between carbon atoms and…

Materials Science · Physics 2018-09-12 G. Savini , A. C. Ferrari , F. Giustino

We study the transition from ballistic to diffusive and localized transport in graphene nanoribbons in the presence of binary disorder, which can be generated by chemical adsorbates or substitutional doping. We show that the interplay…

Mesoscale and Nanoscale Physics · Physics 2009-06-18 Petra Dietl , Georgo Metalidis , Dmitri Golubev , Pablo San-Jose , Elsa Prada , Henning Schomerus , Gerd Schön

Using density functional theory (DFT), we study charge transfer between hexagonal boron nitride (h-BN) point defects and graphene in h-BN/graphene heterostructures for a range of intrinsic defects -- nitrogen vacancy, boron vacancy,…

Materials Science · Physics 2023-11-09 Madhava Krishna Prasad , Oras A. Al-Ani , Jonathan P. Goss , Jonathan D. Mar

Graphene has demonstrated great promise for future electronics technology as well as fundamental physics applications because of its linear energy-momentum dispersion relations which cross at the Dirac point. However, accessing the physics…

We have demonstrated that the island nucleation in the initial stage of epitaxial thin film growth can be tuned by substrate surface charge doping. This charge effect was investigated using spin density functional theory calculation in…

Materials Science · Physics 2015-06-19 Wenmei Ming , Feng Liu

We have performed a density functional study of graphene adsorbed on Au(111) surface using both a local density approximation and a semiempirical van der Waals approach proposed by Grimme, known as the DFT-D2 method. Graphene physisorbed on…

Materials Science · Physics 2015-05-27 J. Slawinska , P. Dabrowski , I. Zasada

Nitrogen doping of the carbon is an important method to improve the performance and durability of catalysts for proton exchange membrane fuel cells by platinum-nitrogen and carbon-nitrogen bonds. This study shows that p-phenyl groups and…

It is well known that impurities play a central role in the linear and nonlinear response of graphene at optical and terahertz frequencies. In this work, we calculate the bands and intraband dipole connection elements for nitrogen-doped…

Mesoscale and Nanoscale Physics · Physics 2021-10-13 Roozbeh Anvari , Eugene Zaremba , Marc M. Dignam

Catalyst-free vertically aligned graphene nanoflakes possessing a large amount of high density edge planes were functionalized using nitrogen species in a low energy N+ ion bombardment process to achieve pyridinic, cyanide and nitrogen…

Materials Science · Physics 2012-05-15 Ajay Kumar , Abhijit Ganguly , Pagona Papakonstantinou

We explain the robust p-type doping observed for quasi-free standing graphene on hexagonal silicon carbide by the spontaneous polarization of the substrate. This mechanism is based on a bulk property of SiC, unavoidable for any hexagonal…

Materials Science · Physics 2015-05-30 J. Ristein , S. Mammadov , Th. Seyller

Experimental setups for charge transport measurements are typically not compatible with the ultra-high vacuum conditions for chemical doping, limiting the charge carrier density that can be investigated by transport methods. Field-effect…

Mesoscale and Nanoscale Physics · Physics 2024-04-12 Ayse Melis Aygar , Oliver Durnan , Bahar Molavi , Sam N. R. Bovey , Alexander Grüneis , Thomas Szkopek

Atherosclerotic disease develops when there is endothelial dysfunction, making low density lipoproteins (LDL) which are cholesterol carriers traveling in the blood, very likely to penetrate the endothelium layer triggering the formation of…

Chemical Physics · Physics 2020-09-07 L. M. Rivera , A. F. Betancur , D. G. Zarate , D. Torres Torres , L. M. Hoyos , A. G. Garcia

Density functional calculations are used to explain the charge transfer doping mechanism by which species physisorptively bonded to graphene can increase its free hole or electron density, without giving rise to defects, and thus maintain a…

Materials Science · Physics 2017-03-22 Haichang Lu , Yuzheng Guo , John Robertson