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By means of density functional theory (DFT) calculations we have quantitatively estimated the impact of the spontaneous polarization (SP) of the SiC(0001) substrate on the electronic properties of quasi-freestanding graphene (QFG) decoupled…

Materials Science · Physics 2015-01-27 J. Slawinska , H. Aramberri , J. I. Cerdà

The interaction between substitutional nitrogen atoms in graphene is studied by performing first principles calculations. The nearest neighbor interaction between nitrogen dopants is highly repulsive because of the strong electrostatic…

Materials Science · Physics 2015-03-19 Hongjun Xiang , Bing Huang , Zhenyu Li , Su-Huai Wei , Jinlong Yang , Xingao Gong

The electronic structure, specific heat, and thermal conductivity of silicon embedded in a monolayer graphene nanosheet are studied using Density Functional Theory. Two different shapes of the substitutional Si doping in the graphene are…

Mesoscale and Nanoscale Physics · Physics 2019-10-29 Hunar Omar Rashid , Nzar Rauf Abdullah , Vidar Gudmundsson

When combined with graphene, hexagonal boron nitride (h-BN) is an ideal substrate and gate dielectric with which to build metalh-BN|graphene field-effect devices. We use first-principles density functional theory (DFT) calculations for…

Materials Science · Physics 2011-11-11 Menno Bokdam , Petr A. Khomyakov , Geert Brocks , Zhicheng Zhong , Paul J. Kelly

The charge transport properties of individual, metallic nitrogen doped, single-walled carbon nanotubes are investigated. It is demonstrated that n-type conduction can be achieved by nitrogen doping. Evidence was obtained by appealing to…

Materials Science · Physics 2009-11-11 V. Krstic , G. L. J. A. Rikken , P. Bernier , S. Roth , M. Glerup

The doping of lighter non-metals like boron and nitrogen into graphene represents a promising advancement in the field of nano-electronic devices, particularly in the development of field-effect transistors (FETs). These doped…

Materials Science · Physics 2023-08-16 Vivek Kumar Yadav

The conductivity of carbon nanotube (CNT) networks can be improved markedly by doping with nitric acid. In the present work, CNTs and junctions of CNTs functionalized with NO$_3$ molecules are investigated to understand the microscopic…

Applied Physics · Physics 2018-03-21 T. Ketolainen , V. Havu , E. Ö. Jónsson , M. J. Puska

We study proximity effects in clean nanoscale superconductor-normal metal-superconductor (S$\mid$N$\mid$S) graphene heterostructures using a self-consistent numerical solution to the continuum Dirac Bogoliubov-de Gennes (DBdG) equations. We…

Superconductivity · Physics 2015-05-28 Klaus Halterman , Oriol T. Valls , Mohammad Alidoust

Employing density-functional theory (DFT) calculations, the generalized-stacking-fault energy (GSFE) curves along two crystallographic slips, glide and shuffle, for both pristine graphene and impurity of boron (B) or nitrogen (N) doped…

Materials Science · Physics 2015-03-10 Fanchao Meng , Bin Ouyang , Jun Song

Two-dimensional materials represented by graphene and transition metal dichalcogenides undergo charge transfer (CT) processes and become hole-doped in strong mineral acids. Nonetheless, their mechanisms remain unclear or controversial. This…

Materials Science · Physics 2021-10-06 Kwnaghee Park , Sunmin Ryu

Graphene and carbon nanotubes have extraordinary mechanical and electronic properties. Intrinsic line defects such as local non-hexagonal reconstructions or grain boundaries, however, significantly reduce the tensile strength, but feature…

Materials Science · Physics 2016-07-20 Daniel Berger , Christian Ratsch

Ab-initio calculations have been performed to study the geometry and electronic structure of boron (B) and nitrogen (N) doped graphene sheet. The effect of doping has been investigated by varying the concentrations of dopants from 2 % (one…

Mesoscale and Nanoscale Physics · Physics 2012-09-25 Pooja Rani , V. K. Jindal

We perform a phenomenological analysis of the problem of the electronic doping of a graphene sheet by deposited transition metal atoms, which aggregate in clusters. The sample is placed in a capacitor device such that the electronic doping…

Strongly Correlated Electrons · Physics 2015-03-19 Jaime E. Santos , Nuno M. R. Peres , Joao M. B. Lopes dos Santos , Antonio H. Castro Neto

Using Density functional theory (DFT) in conjunction with a solvation model we have investigated the phenomenon of eletrode-electrolyte interaction at the electrode surface and its consequences on the electrochemical properties like the…

Materials Science · Physics 2022-04-20 Mandira Das , Subhradip Ghosh

Graphene is an ideal platform to study many-body effects due to its semimetallic character and the possibility to dope it over a wide range. Here we study the width of graphene's occupied $\pi$-band as a function of doping using…

Strongly Correlated Electrons · Physics 2016-08-10 Søren Ulstrup , Malte Schüler , Marco Bianchi , Felix Fromm , Christian Raidel , Thomas Seyller , Tim Wehling , Philip Hofmann

We investigate the effects of transition metals (TM) on the electronic doping and scattering in graphene using molecular beam epitaxy combined with in situ transport measurements. The room temperature deposition of TM onto graphene produces…

Mesoscale and Nanoscale Physics · Physics 2010-01-20 K. Pi , K. M. McCreary , W. Bao , Wei Han , Y. F. Chiang , Yan Li , S. -W. Tsai , C. N. Lau , R. K. Kawakami

Nitrogen doped graphene and carbon nanotubes are popularly in focus as metal-free electro-catalysts for oxygen reduction reactions (ORR) central to fuel-cells. N doped CNTs have been also reported to chemisorb mutually, promising a route to…

Materials Science · Physics 2015-04-17 Joydeep Bhattacharjee

Growth of large-scale graphene is still accompanied by imperfections. By means of a four-tip STM/SEM the local structure of graphene grown on SiC(0001) was correlated with scanning electron microscope images and spatially resolved transport…

Mesoscale and Nanoscale Physics · Physics 2015-06-17 Jens Baringhaus , Frederik Edler , Christoph Neumann , Christoph Stampfer , Stiven Forti , Ulrich Starke , Christoph Tegenkamp

Density functional theory (DFT) modeling of the physisorption of four different types of molecules (toluene, bromine dimmer, water and nitrogen dioxide) over and above graphene ripples has been performed. For all types of molecules changes…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 D. W. Boukhvalov

Nitrogen doping in graphene has important implications in graphene-based devices and catalysts. We have performed the density functional theory calculations to study the electronic structures of N-doped graphene with vacancies and…