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We compute the free energy of confinement ${\cal{F}}$ for a wormlike chain (WLC), with persistence length $l_p$, that is confined to the surface of a cylinder of radius $R$ under an external tension $f$ using a mean field variational…

Soft Condensed Matter · Physics 2023-11-28 Greg Morrison , D. Thirumalai

The transport coefficients of dense polymeric fluids are approximately calculated from the microscopic intermolecular forces. The following finite molecular weight effects are discussed within the Polymer-Mode-Coupling theory (PMC) and…

Condensed Matter · Physics 2009-10-30 Matthias Fuchs , Kenneth S. Schweizer

The study of the noise induced effects on the dynamics of a chain molecule crossing a potential barrier, in the presence of a metastable state, is presented. A two-dimensional stochastic version of the Rouse model for a flexible polymer has…

Statistical Mechanics · Physics 2015-05-13 N. Pizzolato , A. Fiasconaro , B. Spagnolo

The constraints imposed by nano- and microscale confinement on the conformational degrees of freedom of thermally fluctuating biopolymers are utilized in contemporary nano-devices to specifically elongate and manipulate single chains. A…

Soft Condensed Matter · Physics 2010-09-14 F. Thüroff , F. Wagner , E. Frey

The conformational behavior of a polymer in a critical binary solvent confined in a porous medium is studied. The size of the polymer in bulk, which is mainly governed by the correlation length of the solvent density fluctuations, depends…

Soft Condensed Matter · Physics 2007-05-23 Amina Negadi , Arti Dua , Thomas A. Vigis

The paper presents a short overview of the theoretical, numerical and experimental works on the critical behavior of a dilute polymer solution of long-flexible polymer chains confined in semi-infinite space restricted by a surface or in a…

Soft Condensed Matter · Physics 2018-01-08 Zoryana Usatenko , Krzysztof S. Danel

We investigate the nonequilibrium dynamics of semiflexible polymers driven by motor proteins (MPs) in two-dimensional motility assays under harmonic confinement. Using a coarse-grained agent-based model that incorporates stochastic motor…

Soft Condensed Matter · Physics 2025-09-09 Sandip Roy , Abhishek Chaudhuri , Anil Kumar Dasanna

The mechanism behind the NMR surface relaxation and the large $T_1$/$T_2$ ratio of light hydrocarbons confined in the nano-pores of kerogen remains poorly understood, and consequently has engendered much debate. Towards bringing a…

Nonequilibrium molecular dynamics simulations are used to study the shear thinning behavior of immiscible symmetric polymer blends. The phase separated polymers are subjected to a simple shear flow imposed by moving a wall parallel to the…

Soft Condensed Matter · Physics 2009-11-07 Sandra Barsky , Mark O. Robbins

The deformation and break-up of Newtonian/viscoelastic droplets are studied in confined shear flow. Our numerical approach is based on a combination of Lattice-Boltzmann models (LBM) and finite difference schemes, the former used to model…

Soft Condensed Matter · Physics 2016-11-15 A. Gupta , M. Sbragaglia

Brownian dynamics simulations are used to study highly entangled solutions of semiflexible polymers. Bending fluctuations of semiflexible rods are signficantly affected by entanglement only above a concentration $c^{**}$, where $c^{**}\sim…

Soft Condensed Matter · Physics 2009-11-13 Shriram Ramanathan , David C Morse

We used a coarse-grained model to study the geometric and dynamic properties of flexible entangled polymer chains dissolved in explicit athermal solvents. Our simulations successfully reproduced the geometrical properties including the…

Soft Condensed Matter · Physics 2023-06-16 Jiayi Wang , Ping Gao

Dynamics of a polymer chain in solution gets significantly affected by the temperature and the frictional forces arising due to solvent viscosity. Here, using an explicit solvent framework for polymer simulation with the liberty to tune the…

Soft Condensed Matter · Physics 2024-09-11 Suman Majumder , Henrik Christiansen , Wolfhard Janke

We study the diffusion of a linear polymer in the presence of permeable membranes without excluded volume interactions, using scaling theory and Monte Carlo simulations. We find that the average time it takes for a chain with polymerization…

Condensed Matter · Physics 2016-08-31 Hyoungsoo Yoon , J. M. Deutsch

Force-induced deformations of a self-avoiding chain confined inside a cylindrical cavity, with diameter $D$, are probed using molecular dynamics simulations, scaling analysis, and analytical calculations. We obtain and confirm a simple…

Soft Condensed Matter · Physics 2009-11-13 Suckjoon Jun , D. Thirumalai , Bae-Yeun Ha

The motion involved in barrier crossing for protein folding are investigated in terms of the chain dynamics of the polymer backbone, completing the microscopic description of protein folding presented in the previous paper. Local reaction…

Soft Condensed Matter · Physics 2009-10-31 John J. Portman , Shoji Takada , Peter G. Wolynes

The Vicsek model encompasses the paradigm of active dry matter. Motivated by collective behavior of insects in swarms, we have studied finite size effects and criticality in the three dimensional, harmonically confined Vicsek model. We have…

Statistical Mechanics · Physics 2023-01-18 R. González-Albaladejo , A. Carpio , L. L. Bonilla

We study the swelling of a flexible linear chain composed of active particles by analytical theory and computer simulation. Three different situations are considered: a free chain, a chain confined to an external harmonic trap, and a chain…

Soft Condensed Matter · Physics 2015-03-31 Andreas Kaiser , Sonja Babel , Borge ten Hagen , Christian von Ferber , Hartmut Löwen

We use molecular dynamics simulations to study a semidilute, unentangled polymer solution containing well dispersed, weakly attractive nanoparticles (NP) of size ($\sigma_N$) smaller than the polymer radius of gyration $R_g$. We find that…

Soft Condensed Matter · Physics 2018-09-18 Valerio Sorichetti , Virginie Hugouvieux , Walter Kob

The dynamics of loop formation by linear polymer chains has been a topic of several theoretical/experimental studies. Formation of loops and their opening are key processes in many important biological processes. Loop formation in flexible…

Soft Condensed Matter · Physics 2015-05-14 K. P. Santo , K. L. Sebastian
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