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Bi-layer graphene with a twist angle \theta\ between the layers generates a superlattice structure known as Moir\'{e} pattern. This superlattice provides a \theta-dependent q wavevector that activates phonons in the interior of the…

Mesoscale and Nanoscale Physics · Physics 2013-03-29 J. Campos-Delgado , L. G. Cançado , C. A. Achete , A. Jorio , J. -P. Raskin

We show how the magneto-phonon resonance, particularly pronounced in sp2 carbon allotropes, can be used as a tool to probe the band structure of multilayer graphene specimens. Even when electronic excitations cannot be directly observed,…

Mesoscale and Nanoscale Physics · Physics 2012-09-11 C. Faugeras , P Kossacki , A. A. L. Nicolet , M. Orlita , M Potemski , A. Mahmood , D. M. Basko

Taking into account the constraints imposed by the lattice symmetry, the phonon dispersion is calculated for graphene with interactions between the first and second nearest neighbors in the framework of the Born-von Karman model. Analytical…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 L. A. Falkovsky

An efficient route to synthesize macroscopic amounts of graphene is highly desired and a bulk characterization of such samples, in terms of the number of layers, is equally important. We present a Raman spectroscopy-based method to…

We present measurements of the $D''$ Raman mode in graphene and carbon nanotubes at different laser excitation energies. The Raman mode around 1050 - 1150\,cm$^{-1}$ originates from a double-resonant scattering process of longitudinal…

We present an analysis of deep-UV Raman measurements of graphite, graphene and carbon nanotubes. For excitation energies above the strong optical absorption peak at the $M$ point in the Brillouin zone ($\approx 4.7\,\text{eV}$), we…

Materials Science · Physics 2015-08-03 Christoph Tyborski , Felix Herziger , Roland Gillen , Janina Maultzsch

Layered materials (LMs), such as graphite, hexagonal boron nitride, and transition-metal dichalcogenides, are at the centre of an ever increasing research effort, due to their scientific and technological relevance. Raman and infrared…

Materials Science · Physics 2021-12-23 Giovanni Pizzi , Silvia Milana , Andrea C. Ferrari , Nicola Marzari , Marco Gibertini

The Raman shift, broadening, and relative Raman intensities of bilayer graphene are computed as functions of the electron concentration. We include dynamic effects for the phonon frequencies and we consider the gap induced in the band…

Materials Science · Physics 2009-09-11 Paola Gava , Michele Lazzeri , A. Marco Saitta , Francesco Mauri

In this work we study the behavior of the optical phonon modes in bilayer graphene devices by applying top gate voltage, using Raman scattering. We observe the splitting of the Raman G band as we tune the Fermi level of the sample, which is…

Mesoscale and Nanoscale Physics · Physics 2012-06-07 D. L. Mafra , P. Gava , L. M. Malard , R. S. Borges , G. G. Silva , J. A. Leon , F. Plentz , F. Mauri , M. A. Pimenta

We use first-principles density-functional calculations to determine the frequency shift of the A$'_1$-${\bf K}$ phonon (Raman D band) in monolayer graphene, as a function of the charge doping. A detailed DFT study on the electron-phonon…

Materials Science · Physics 2007-05-23 Srijan Kumar Saha , U. V. Waghmare , H. R. Krishnamurthy , A. K. Sood

We describe the identification of single- and few- layer boron nitride. Its optical contrast is much smaller than that of graphene but even monolayers are discernable by optimizing viewing conditions. Raman spectroscopy can be used to…

Mesoscale and Nanoscale Physics · Physics 2011-04-08 R. V. Gorbachev , I. Riaz , R. R. Nair , R. Jalil , L. Britnell , B. D. Belle , E. W. Hill , K. S. Novoselov , K. Watanabe , T. Taniguchi , A. K. Geim , P. Blake

The stacking faults (deviates from Bernal) will break the translational symmetry of multilayer graphenes and modify their electronic and optical behaviors to the extent depending on the interlayer coupling strength. This paper addresses the…

Materials Science · Physics 2015-05-13 Zhenhua Ni , Lei Liu , Yingying Wang , Zhe Zheng , Lain-Jong Li , Ting Yu , Zexiang Shen

We investigated the low-frequency Raman spectra of freestanding few-layer graphene (FLG) at varying temperatures (400 - 900 K) controlled by laser heating. At high temperature, we observed the fundamental Raman mode for the lowest-frequency…

Mesoscale and Nanoscale Physics · Physics 2014-08-15 Chun Hung Lui , Zhipeng Ye , Courtney Keiser , Xun Xiao , Rui He

Raman spectroscopy is one of the widely used methods in the analysis of various samples including carbon-based materials. This study aimed to identify the number of layers and defects in graphene using micro-Raman spectroscopy. More…

Optics · Physics 2024-03-21 Somayeh Gholipour , Maryam Bahreini , Mohamad Reza Jafarfard

The in-plane shear modes between neighbor-layers of 2-4 layer graphenes (LGs) and the corresponding graphene scrolls rolled up by 2-4LGs were investigated by Raman scattering. In contrast to that just one shear mode was observed in 3-4LGs,…

Materials Science · Physics 2014-06-11 Ping-Heng Tan , Jiang-Bin Wu , Wen-Peng Han , Wei-Jie Zhao , Xin Zhang , Hui Wang , Yu-Fang Wang

An experimental study of Raman scattering in N-layer graphene as a function of the top layer doping is reported. At high doping level, achieved by a CHF_3 plasma treatment, we observe a splitting of the $G$ band in the spectra of bilayer…

Mesoscale and Nanoscale Physics · Physics 2010-03-23 M. Bruna , S. Borini

Practical applications of graphene require a reliable high-throughput method of graphene identification and quality control, which can be used for large-scale substrates and wafers. We have proposed and experimentally tested a fast and…

Materials Science · Physics 2011-06-21 Craig M. Nolen , Giovanni Denina , Desalegne Teweldebrhan , Bir Bhanu , Alexander A. Balandin

Two-dimensional (2D) layered materials have been extensively studied owing to their fascinating and technologically relevant properties. Their functionalities can be often tailored by the interlayer stacking pattern. Low-frequency (LF)…

Mesoscale and Nanoscale Physics · Physics 2017-10-06 Liangbo Liang , Alexander A. Puretzky , Bobby G. Sumpter , Vincent Meunier

Naturally or artificially stacking extra layers on single layer graphene (SLG) forms few-layer graphene (FLG), which has attracted tremendous attention owing to its exceptional properties inherited from SLG and new features generated by…

Mesoscale and Nanoscale Physics · Physics 2015-07-03 Chunxiao Cong , Ting Yu

The phonon dispersions of monolayer and few-layer graphene (AB bilayer, ABA and ABC trilayers) are investigated using the density-functional perturbation theory (DFPT). Compared with the monolayer, the optical phonon $E_{2g}$ mode at…

Materials Science · Physics 2009-11-13 Jia-An Yan , W. Y. Ruan , M. Y. Chou