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We develop a modified Poisson-Nernst-Planck model which includes both the long-range Coulomb and short-range hard-sphere correlations in its free energy functional such that the model can accurately describe the ion transport in complex…

Computational Physics · Physics 2021-05-21 Manman Ma , Zhenli Xu , Liwei Zhang

A model for ionic solutions with an attractive short-range pair interaction between the ions is presented. The short-range interaction is accounted for by adding a quadratic non-local term to the Poisson-Boltzmann free energy. The model is…

Soft Condensed Matter · Physics 2009-10-31 Yoram Burak , David Andelman

This paper is concerned with a strongly degenerate convection-diffusion equation in one space dimension whose convective flux involves a non-linear function of the total mass to one side of the given position. This equation can be…

Numerical Analysis · Mathematics 2010-07-12 Fernando Betancourt , Raimund Bürger , Kenneth H. Karlsen

The continuous charge density of the r^{-4} radial astroelectron is found analytically from the Maxwell-Lorentz equations. The electric charge is not a basic concept, but is the nonlinear field distribution associated with the elementary…

General Physics · Physics 2008-07-08 I. E. Bulyzhenkov

The general solution to the nonlinear Poisson-Boltzmann equation for two parallel charged plates, either inside a symmetric elecrolyte, or inside a 2q:-q asymmetric electrolyte, is found in terms of Weierstrass elliptic functions. From this…

Classical Physics · Physics 2010-10-26 Xiangjun Xing

We show that charge-sign-dependent asymmetric hydration can be modeled accurately using linear Poisson theory but replacing the standard electric-displacement boundary condition with a simple nonlinear boundary condition. Using a single…

Chemical Physics · Physics 2015-06-23 Jaydeep P. Bardhan , Matthew G. Knepley

In this paper, the initial value problem for the Debye--Hueckel drift-diffusion equation is studied. This equation was introduced as a model describing plasma behavior and is also known as a simulation model of MOSFET, and so its solution…

Analysis of PDEs · Mathematics 2026-04-29 Masakazu Yamamoto

At mesoscopic scales electrolyte solutions are modeled by the fluctuating generalized Poisson-Nernst-Planck (PNP) equations [J.-P. P\'eraud et al., Phys. Rev. F, 1(7):074103, 2016]. However, at length and time scales larger than the Debye…

Computational Physics · Physics 2019-04-10 Aleksandar Donev , Andrew J. Nonaka , Changho Kim , Alejandro L. Garcia , John B. Bell

Particles transported in fluid flows, such as cells, polymers, or nanorods, are rarely spherical. In this study, we numerically and theoretically investigate the dispersion of an initially localized patch of passive elongated Brownian…

Fluid Dynamics · Physics 2021-09-15 Ajay Harishankar Kumar , Stuart J. Thomson , Thomas R. Powers , Daniel M. Harris

The Poisson-Boltzmann (PB) equation provides a mean-field theory of electrolyte solutions at interfaces and in confinement, describing how ions reorganize close to charged surfaces to form the so-called electrical double layer (EDL), with…

Soft Condensed Matter · Physics 2024-09-10 Cecilia Herrero , Laurent Joly

We study one dimensional mixtures of two-component Bose-Einstein condensates in the limit where the intra-species and inter-species interaction constants are very close. Near the mixing-demixing transition the polarization and the density…

Quantum Gases · Physics 2018-04-20 T. Congy , A. M. Kamchatnov , N. Pavloff

We formulate a general mean-field theory of a flat electric double layer in ionic liquids and electrolyte solutions with ions possessing static polarizability and a permanent dipole moment on a charged electrode. We establish a new…

Statistical Mechanics · Physics 2021-08-17 Yu. A. Budkov , S. V. Zavarzin , A. L. Kolesnikov

We introduce a simple and efficient model to describe the potential energy surface of lithium diffusing in a solid-state ionic conductor. First, we assume that the Li atoms are fully ionized and we neglect the weak dependence of the…

Materials Science · Physics 2019-02-07 Leonid Kahle , Aris Marcolongo , Nicola Marzari

We revisit the popular notion of effective or renormalized charge, which is a concept of central importance in the field of highly charged colloidal or polyelectrolyte solutions. Working at the level of a linear Debye-H\"uckel like theory…

Soft Condensed Matter · Physics 2009-11-07 Emmanuel Trizac , Lyderic Bocquet , Miguel Aubouy

We investigate electric-field effects in dilute electrolytes with nonlinear polarization. As a first example of such systems, we add a dipolar component with a relatively large dipole moment $\mu_0$ to an aqueous electrolyte. As a second…

Soft Condensed Matter · Physics 2024-01-12 Akira Onuki

This paper addresses the linear and nonlinear three-dimensional propagation of an electron wave in a collisionless plasma that may be inhomogeneous, nonstationary, anisotropic and even weakly magnetized. The wave amplitude, together with…

Plasma Physics · Physics 2016-11-03 Didier Bénisti

In order to characterize nuclear matter under extreme conditions, we calculate all diffusion transport coefficients related to baryon, electric and strangeness charge for both a hadron resonance gas and a simplified kinetic model of the…

High Energy Physics - Phenomenology · Physics 2018-06-15 Moritz Greif , Jan A. Fotakis , Gabriel S. Denicol , Carsten Greiner

We prove existence of global weak solutions for the Nernst-Planck-Poisson problem which describes the evolution of concentrations of charged species $X_1, ..., X_P$ subject to Fickian diffusion and chemical reactions in the presence of an…

Analysis of PDEs · Mathematics 2016-04-01 Dieter Bothe , André Fischer , Michel Pierre , Guillaume Rolland

We prove the existence and uniqueness of the complexified Nonlinear Poisson-Boltzmann Equation (nPBE) in a bounded domain in $\mathbb{R}^3$. The nPBE is a model equation in nonlinear electrostatics. The standard convex optimization argument…

Analysis of PDEs · Mathematics 2021-06-11 Brian Choi , Jie Xu , Trevor Norton , Mark Kon , Julio E. Castrillon-Candas

We present several aspects of the screening of charged macromolecules in an electrolyte. After a review of the basic mean field approach, based on the linear Debye-Huckel theory, we consider the case of highly charged macromolecules, where…

Soft Condensed Matter · Physics 2012-04-27 Gabriel Tellez