Related papers: On the relation between kinetically constrained mo…
Despite decades of research, it remains to be established whether the transformation of a liquid into a glass is fundamentally thermodynamic or dynamic in origin. While observations of growing length scales are consistent with thermodynamic…
How does nonequilibrium activity modify the approach to a glass? This is an important question, since many experiments reveal the near-glassy nature of the cell interior, remodelled by activity. However, different simulations of dense…
Facilitated or kinetically constrained spin models (KCSM) are a class of interacting particle systems reversible w.r.t. to a simple product measure. Each dynamical variable (spin) is re-sampled from its equilibrium distribution only if the…
In this chapter we summarize recent developments in the study of kinetically constrained models (KCMs) as models for glass formers. After recalling the definition of the KCMs which we cover we study the possible occurrence of ergodicity…
We develop a real space renormalisation group analysis of disordered models of glasses, in particular of the spin models at the origin of the Random First Order Transition theory. We find three fixed points respectively associated to the…
We investigate the glass and the jamming transitions of hard spheres in finite dimensions $d$, through a revised cell theory, that combines the free volume and the Random First Order Theory (RFOT). Recent results show that in infinite…
According to the Random First Order Transition (RFOT) theory of glasses, the barriers for activated dynamics in supercooled liquids vanish as the temperature of a viscous liquid approaches the dynamical transition temperature from below.…
It was recently discovered that SWAP, a Monte Carlo algorithm that involves the exchange of pairs of particles of differing diameters, can dramatically accelerate the equilibration of simulated supercooled liquids in regimes where the…
The spherical mean field approximation of a spin-1 model with p-body quenched disordered interaction is investigated. Depending on temperature and chemical potential the system is found in a paramagnetic or in a glassy phase and the…
We describe our perspective on the Structural Glass Transition (SGT) problem built on the premise that a viable theory must provide a consistent picture of the dynamics and statics, which are manifested by large increase in shear viscosity…
The dramatic slowdown of glass-forming liquids has been variously linked to increasing dynamic and static correlation lengths. Yet, empirical evidence is insufficient to decide among competing theories. The random first order theory (RFOT)…
We study the glass transition by exploring a broad class of kinetic rules that can significantly modify the normal dynamics of super-cooled liquids, while maintaining thermal equilibrium. Beyond the usual dynamics of liquids, this class…
A disordered spin model suitable for studying inverse freezing in fragile glass-forming systems is introduced. The model is a microscopic realization of the ``random-first order'' scenario in which the glass transition can be either…
Dynamics near the surface of glasses is generally much faster than in the bulk. Neglecting static perturbations of structure at the surface, we use random first order transition theory to show the free energy barrier for activated motion…
We investigate the dynamics of kinetically constrained models of glass formers by analysing the statistics of trajectories of the dynamics, or histories, using large deviation function methods. We show that, in general, these models exhibit…
We generalize the simplest kinetically constrained model of a glass-forming liquid by softening kinetic constraints, allowing them to be violated with a small finite rate. We demonstrate that this model supports a first-order dynamical…
Kinetically constrained models (KCMs) are models of glass formers based on the concept of dynamic facilitation. This concept accounts for many of the characteristics of the glass transition. KCMs usually display a combination of simple…
We analyze kinetically constrained 0-1 spin models (KCSM) on rooted and unrooted trees of finite connectivity. We focus in particular on the class of Friedrickson-Andersen models FA-jf and on an oriented version of them. These tree models…
I present a new method to analyze Glauber dynamics of the Sherrington-Kirkpatrick (SK) spin glass model. The method is based on ideas used in the classical kinetic theory of fluids. I apply it to study spin correlations in the high…
A unified treatment of structural relaxation in a deeply supercooled glassy liquid is developed which extends the existing mode coupling theory (MCT) by incorporating the effects of activated events by using the concepts from the random…