English

Can the glass transition be explained without a growing static length scale?

Statistical Mechanics 2019-04-02 v2

Abstract

It was recently discovered that SWAP, a Monte Carlo algorithm that involves the exchange of pairs of particles of differing diameters, can dramatically accelerate the equilibration of simulated supercooled liquids in regimes where the normal dynamics is glassy. This spectacular effect was subsequently interpreted as direct evidence against a static, cooperative explanation of the glass transition such as the one offered by the random first-order transition (RFOT) theory. We review several empirical facts that support the opposite view, namely, that a local mechanism cannot explain the glass transition phenomenology. We explain the speedup induced by SWAP within the framework of the RFOT theory. We suggest that the efficiency of SWAP stems from a postponed onset of glassy dynamics, which allows the efficient exploration of configuration space even in the regime where the physical dynamics is dominated by activated events across free-energy barriers. We describe this effect in terms of `crumbling metastability' and use the example of nucleation to illustrate the possibility of circumventing free-energy barriers of thermodynamic origin by a change of the local dynamical rules.

Keywords

Cite

@article{arxiv.1805.12378,
  title  = {Can the glass transition be explained without a growing static length scale?},
  author = {Ludovic Berthier and Giulio Biroli and Jean-Philippe Bouchaud and Gilles Tarjus},
  journal= {arXiv preprint arXiv:1805.12378},
  year   = {2019}
}

Comments

15 pages, 3 figures; v2: improved discussions and clarifications

R2 v1 2026-06-23T02:14:27.334Z