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Defect-free graphene is impermeable to gases and liquids but highly permeable to thermal protons. Atomic-scale defects such as vacancies, grain boundaries and Stone-Wales defects are predicted to enhance graphene's proton permeability and…

The type and distribution of oxygen functional groups in graphene oxide (GO) and reduced graphene oxide (RGO) remain still a subject of great debate. Local analytic techniques are required to access the chemistry of these materials at a…

Materials Science · Physics 2016-12-13 Anna Tararan , Alberto Zobelli , Ana M. Benito , Wolfgang K. Maser , Odile Stéphan

For two decades, two-dimensional carbon species, including graphene, have been the core of research in pursuing next-generation logic applications beyond the silicon technology. Yet the opening of a gap in a controllable range of doping,…

Intrinsic layered structure of graphite is the source of ongoing and expanding search of ways of obtaining low-cost and promising graphite thin layers. We report on a novel method of obtaining and separating rubbed graphite sheets by using…

Materials Science · Physics 2015-06-23 Manuel R. Mailian , Aram R. Mailian

Coherent motion of the electrons in the Bloch states is one of the fundamental concepts of the charge conduction in solid state physics. In layered materials, however, such a condition often breaks down for the interlayer conduction, when…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Youngwook Kim , Hoyeol Yun , Seung-Geol Nam , Minhyeok Son , Dong Su Lee , Dong Chul Kim , S. Seo , Hee Cheul Choi , Hu-Jong Lee , Sang Wook Lee , Jun Sung Kim

Due to its exceptionally outstanding electrical, mechanical and thermal properties, graphene is being explored for a wide array of applications and has attracted enormous academic and industrial interest. Graphene and its derivatives have…

Materials Science · Physics 2015-09-22 Yanbin Cui , S. I. Kundalwal , S. Kumar

Using first-principles calculations, we show that the formation of carbohydrate directly from carbon and water is energetically favored when graphene membrane is subjected to aqueous environment with difference in chemical potential across…

Mesoscale and Nanoscale Physics · Physics 2010-03-17 Wei L. Wang , Efthimios Kaxiras

Solid mixed conductors with significant ionic as well as electronic conduction play a pivotal role for mass transfer and storage as required in battery electrodes. Single-phase materials with simultaneously high electronic and ionic…

Mesoscale and Nanoscale Physics · Physics 2017-09-11 M. Kühne , F. Paolucci , J. Popovic , P. M. Ostrovsky , J. Maier , J. H. Smet

The electronic structure and optical response of electrically gated bilayer graphene are studied by first-principles approaches. We have obtained the induced band gap that is in good agreement with experiment when the applied electric field…

Mesoscale and Nanoscale Physics · Physics 2015-03-13 Li Yang

This review provides a critical overview of current developments on nanoelectronic biochemical sensors based on graphene. Composed of a single layer of conjugated carbon atoms, graphene has outstanding high carrier mobility and low…

Materials Science · Physics 2020-12-14 Xiaoyan Zhang , Qiushi Jing , Shen Ao , Grégory F. Schneider , Dmitry Kireev , Zhengjun Zhang , Wangyang Fu

Controlled modification of graphene properties is essential for its proposed electronic applications. Here we describe a possibility of tuning electrical properties of graphene via electron beam irradiation. We show that by controlling the…

Materials Science · Physics 2015-10-28 G. Liu , D. Teweldebrhan , A. A. Balandin

Optical microfibers finds new applications in various fields of industry, which in turn requires wear resistance, environmental friendliness and ease of use. However, optical microfibers are fragile. Here we report a new method to prolong…

Applied Physics · Physics 2024-09-04 A. Novikova , A. Katiyi , A. Halstuch , A. Karabchevsky

We present transport measurements on a bilayer graphene sheet with homogeneous back gate and split top gate. The electronic transport data indicates the capability to direct electron flow through graphene nanostructures purely defined by…

Mesoscale and Nanoscale Physics · Physics 2012-10-10 S. Dröscher , C. Barraud , K. Watanabe , T. Taniguchi , T. Ihn , K. Ensslin

A simple optical method is presented for identifying and measuring the effective optical properties of nanometer-thick, graphene-based materials, based on the use of substrates consisting of a thin dielectric layer on silicon. High contrast…

A friction based method is proposed for obtaining graphite layers. Freestanding thin structures of graphite containing several layers of graphene are obtained by rubbing a graphite rod on the surfaces of NaCl substrate and then dissolving…

Materials Science · Physics 2014-11-26 Manuel Mailian , Kamran ul Hasan , Aram Mailian

We demonstrate that single layer graphene exhibits the electronic structure of a bilayer when it is connected to two gated bilayers. The energy gap characteristic for gated bilayer is induced in the single layer and it persists for…

Mesoscale and Nanoscale Physics · Physics 2019-07-31 Wlodzimierz Jaskolski

Selective ion transport is a hallmark of biological ion channel behavior but is a major challenge to engineer into artificial membranes. Here, we demonstrate, with all-atom molecular dynamics simulations, that bare graphene nanopores yield…

Mesoscale and Nanoscale Physics · Physics 2017-08-22 Subin Sahu , Michael Zwolak

Graphene oxide (GO), the functionalized graphene with oxygenated groups (mainly epoxy and hydroxyl), has attracted resurgent interests in the past decade owing to its large surface area, superior physical and chemical properties, and easy…

Materials Science · Physics 2020-01-14 Xiaoming Huang , Lizhao Liu , Si Zhou , Jijun Zhao

Graphynes are 2D porous structures deriving from graphene featuring triangular and regularly distributed subnanometer pores, which may be exploited to host small gaseous species. First principles adsorption energies of molecular hydrogen…

Chemical Physics · Physics 2015-10-06 Massimiliano Bartolomei , Estela Carmona-Novillo , Giacomo Giorgi

The realization of optoelectronic devices on paper has been an outstanding challenge due to the large surface roughness and incompatible nature of paper with optical materials. Here, we demonstrate a new class of optoelectronic devices on a…

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