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We propose an alternative structure of TiO2 anatase that has a higher energy oxygen p-like valence band maximum than the pristine TiO2 anatase and thus has a much better alignment with the water splitting levels. This alternative structure…

Materials Science · Physics 2017-02-22 Sinisa Coh , Peter Y. Yu , Yuta Aoki , Susumu Saito , Steven G. Louie , Marvin L. Cohen

The electronic structure and the anisotropy of the Al - N {\pi} and {\sigma} chemical bonding of wurtzite AlN has been investigated by bulk-sensitive total fluorescence yield absorption and soft x-ray emission spectroscopies. The measured N…

Materials Science · Physics 2011-12-30 M. Magnuson , M. Mattesini , C. Höglund , J. Birch , L. Hultman

Ab-initio, self-consistent electronic energy bands of rutile TiO2 are reported within the local density functional approximation (LDA). Our first principle, non-relativistic and ground state calculations employed a local density functional…

Materials Science · Physics 2012-03-23 C. E. Ekuma , D. Bagayoko

The quasiparticle electronic structure and optical excitation of anatase TiO$_2$ is determined within the framework of many-body perturbation theory (MBPT) by combining the $G_0W_0$ method and the Bethe-Salpeter Equation (BSE). A modified…

Materials Science · Physics 2021-12-07 Sruthil Lal S. B , D Murali , Matthias Posselt , Assa Aravindh Sasikala Devi , Alok Sharan

Results of first principles augmented spherical wave electronic structure calculations for niobium dioxide are presented. Both metallic rutile and insulating low-temperature NbO2, which crystallizes in a distorted rutile structure, are…

Strongly Correlated Electrons · Physics 2009-11-07 V. Eyert

Nb3O2(OH) has emerged as a highly attractive photocatalyst based on its chemical stability, energetic band positions, and large active lattice sites. Compared to other various photocatalytic semiconductors, it can be synthesized easily.…

Materials Science · Physics 2025-02-17 Wilayat Khan , Alishba Tariq , Jan Minar , Sawera Durrani , Abdul Raziq , Sikander Azam , Khalid Saeed

We report a femtosecond mid-infrared study of the broadband low-energy response of individually separated (6,5) and (7,5) single-walled carbon nanotubes. Strong photoinduced absorption is observed around 200 meV, whose transition energy,…

Mesoscale and Nanoscale Physics · Physics 2010-07-16 Jigang Wang , Matt W. Graham , Yingzhong Ma , Graham R. Fleming , Robert A. Kaindl

In this paper, we report on the co-doping nitrogen and sulfur has been achieved in the TiO2 nanotube array films by treatment with thiourea and calcination under vacuum at 500 {\deg}C for 3 h. The samples were characterized by scanning…

Materials Science · Physics 2011-07-25 Guotian Yan , Min Zhang , Jian Houa , Jianjun Yang

Femtosecond high-order harmonic transient absorption spectroscopy is used to observe electromagnetically induced transparency-like behavior as well as induced absorption in the extreme ultraviolet by laser dressing of the He 2s2p (1Po) and…

Atomic Physics · Physics 2009-11-13 Zhi-Heng Loh , Chris H. Greene , Stephen R. Leone

In two-dimensional materials research, oxidation is usually considered as a common source for the degradation of electronic and optoelectronic devices or even device failure. However, in some cases a controlled oxidation can open the…

In this study, we systematically study on crystal and electronic structures and optical absorption properties of perfect monolayer MoS2 (M), M with S vacancy (M@SV), M with N doping at S site (M@ND) and M with both S vacancy and N doping at…

Materials Science · Physics 2019-01-09 Aijun Hong

We study the surface and bulk electronic structure of the room-temperature ferromagnet Co:TiO2 anatase films using soft and hard x-ray photoemission spectroscopy with probe sensitivities of ~1 nm and ~10 nm, respectively. We obtain direct…

Benzobisthiadiazoles (BBTs) are promising organic semiconductors for applications in field effect transistors and solar cells, since they possess a strong electron-accepting character. Thereby the electronic structure of organic/metal…

First-principles density functional theory calculations were carried out to determine the low energy geometries of anatase TiO$_2$(001) with Pt implants in the sublayers as substitutional and interstitial impurities as well as on the…

Strongly Correlated Electrons · Physics 2009-03-19 E. Mete , D. Uner , O. Gulseren , S. Ellialtioglu

In this paper, I demonstrate a density functional theory plus dynamical mean field theory study on the electronic properties of doped $TiO_2$ rutile as well as another tetragonal phase anatase with oxygen vacancy. The density of states and…

Strongly Correlated Electrons · Physics 2021-12-24 S. Koley

Dilute nitride bismide GaNBiAs is a potential semiconductor alloy for near- and mid-infrared applications, particularly in 1.55 $\mu$m optical communication systems. Incorporating dilute amounts of Bismuth (Bi) into GaAs reduces the…

Mesoscale and Nanoscale Physics · Physics 2017-06-22 W. J. Fan , Sumanta Bose , D. H Zhang

The urgent need to mitigate rising atmospheric CO2 levels motivates the search for stable, efficient, and tunable adsorbent materials. In this study, we employ first-principles density functional theory to investigate the adsorption of CO2…

Materials Science · Physics 2026-02-16 Jakkapat Seeyangnok , Rungkiat Nganglumpoon , Joongjai Panpranot , Udomsilp Pinsook

Cobalt and manganese ions are implanted into SiO$_2$ over a wide range of concentrations. For low concentrations, the Co atoms occupy interstitial locations, coordinated with oxygen, while metallic Co clusters form at higher implantation…

Materials Science · Physics 2014-03-18 R. J. Green , D. A. Zatsepin , D. J. St. Onge , E. Z. Kurmaev , N. V. Gavrilov , A. F. Zatsepin , A. Moewes

The electronic structure of BaTi2As2O, a parent compound of the newly discovered titanium-based oxypnictide superconductors, is studied by angle-resolved photoemission spectroscopy. The electronic structure shows multi-orbital nature and…

Superconductivity · Physics 2015-06-18 H. C. Xu , M. Xu , R. Peng , Y. Zhang , Q. Q. Ge , F. Qin , M. Xia , J. J. Ying , X. H. Chen , M. Arita , K. Shimada , M. Taniguchi , D. H. Lu , B. P. Xie , D. L. Feng

The electronic band structure of Ga(PAsN) with a few percent of nitrogen is calculated in the whole composition of Ga(PAs) host using the state-of-the-art density functional methods including the modified Becke-Johnson functional to…

Materials Science · Physics 2021-09-10 Maciej P. Polak , Robert Kudrawiec , Oleg Rubel