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We have constructed an analytic formula to treat the perpendicular magnetic anisotropy energy in ferromagnetic metals with low symmetry, such as C4V and C3V. We find that the anisotropy energy is proportional to a part of the expectation…

Materials Science · Physics 2019-03-27 Yoshishige Suzuki , Shinji Miwa

Single molecule magnets (SMMs) with single-ion anisotropies $\mathbf d$, comparable to exchange interactions J, between spins have recently been synthesized. In this paper, we provide theoretical insights into the magnetism of such systems.…

Strongly Correlated Electrons · Physics 2017-11-22 Sumit Haldar , Rajamani Raghunathan , Jean-Pascal Sutter , S. Ramasesha

We demonstrate using inelastic scanning tunneling spectroscopy (ISTS) and simulations based on density functional theory that the amplitude and sign of the magnetic anisotropy energy for a single Fe atom adsorbed onto the Pt(111) surface…

The magnetocrystalline anisotropy energy $E_{anis}$ for a monolayer of Fe and Ni is determined using a fully convergent tight-binding calculation including $s$-$d$ hybridization. The spin-orbit interaction $\lambda_{so}$ is treated…

Condensed Matter · Physics 2016-08-31 T. H. Moos , W. Hübner , K. H. Bennemann

The tunnelling anisotropic magnetoresistance (TAMR) effect describes the sensitivity of spin-polarized electron transport to the orientation of the magnetization with respect to the crystallographic axes. As the TAMR effect requires only a…

Materials Science · Physics 2015-06-19 Nuala M. Caffrey , Silke Schröder , Paolo Ferriani , Stefan Heinze

We present a microscopic theory of single molecule magnets. From our exact single-ion spin matrix elements for four arbitrary spins, we study the single-ion anisotropy of equal spins exhibiting $T_d$, $D_{2d}$, or $C_{4v}$ molecular group…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 Richard A. Klemm , Dmitri V. Efremov

The magnetism of single atoms and molecules is governed by the atomic scale environment. In general, the reduced symmetry of the surrounding splits the $d$ states and aligns the magnetic moment along certain favorable directions. Here, we…

Mesoscale and Nanoscale Physics · Physics 2015-11-30 Benjamin W. Heinrich , Lukas Braun , Jose I. Pascual , Katharina J. Franke

Room-temperature superparamagnetism due to a large magnetic anisotropy energy (MAE) of a single atom magnet has always been a prerequisite for nanoscale magnetic devices. Realization of two dimensional (2D) materials such as single-layer…

Mesoscale and Nanoscale Physics · Physics 2018-04-18 M. A. Khan , Michael N. Leuenberger

Motivated by recent STM experiments, we present a theoretical study of the electronic and magnetic properties of the Mn-induced acceptor level obtained by substituting a single Ga atom in the (110) surface layer of GaAs or in one of the…

Materials Science · Physics 2010-01-28 T. O. Strandberg , C. M. Canali , A. H. MacDonald

One-dimensional metal-organic chains often possess a complex magnetic structure susceptible to be modified by a alteration of their chemical composition. The possibility to tune their magnetic properties provides an interesting playground…

$R$V${_6}$Sn${_6}$ ($R$ = Y, Gd - Tm, Lu) single crystals are synthesized by Sn-flux method and their physical properties are characterized by magnetization, resistivity, and specific heat measurements. Powder X-ray diffraction patterns of…

Strongly Correlated Electrons · Physics 2022-10-28 Jeonghun Lee , Eundeok Mun

The interaction between the endohedral unit in the single-molecule magnet Dy$_2$ScN@C$_{80}$ and a rhodium (111) substrate leads to alignment of the Dy 4$f$ orbitals. The resulting orientation of the Dy$_2$ScN plane parallel to the surface…

In several experiments the magnitude of the contribution of magnetic impurities to the Kondo resistivity shows size dependence in mesoscopic samples. It was suggested ten years ago that magnetic surface anisotropy can be responsible for the…

Strongly Correlated Electrons · Physics 2009-11-11 O. Ujsaghy , L. Szunyogh , A. Zawadowski

Exploring an upper limit of magnetic anisotropy in two-dimensional materials, such as graphene and transition metal dichalcogenides, is at the heart of spintronics research. Herein, an atomic-scale perpendicular magnetic anisotropy up to an…

Materials Science · Physics 2016-08-10 Dorj Odkhuu

Dimers are the smallest chemical objects that show magnetic anisotropy. We focus on 3$d$ and 4$d$ transition metal dimers that have magnetic ground states in most cases. Some of these magnetic dimers have a considerable barrier against…

Atomic and Molecular Clusters · Physics 2008-04-09 Daniel Fritsch , Klaus Koepernik , Manuel Richter , Helmut Eschrig

Magnetic anisotropy is a key parameter to describe the exchange bias effect in heterostructures. In this paper, we describe explicit density functional calculations of the magnetic structure of an interface between the industrially…

Materials Science · Physics 2025-09-03 Robert A. Lawrence , Matt I. J. Probert

Single adatoms offer an exceptional playground for studying magnetism and its associated dynamics at the atomic scale. Here we review recent results on single adatoms deposited on metallic substrates, based on time-dependent density…

Mesoscale and Nanoscale Physics · Physics 2018-08-29 Julen Ibañez-Azpiroz , Manuel dos Santos Dias , Stefan Blügel , Samir Lounis

The electronic and magnetic properties of single 3d transition-metal(TM) atom (V, Cr, Mn, Fe, Co, and Ni) adsorbed graphdiyne (GDY) and graphyne (GY) are systematically studied using first-principles calculations within the density…

Materials Science · Physics 2013-01-11 Junjie He , ShuangYing Ma , Pan Zhou , C. X. Zhang , Chaoyu He , L. Z. Sun

Magnetocrystalline anisotropy in transition metal alloys (FePt, CoPt, FePd, MnAl, MnGa, and FeCo) was studied using first-principles calculations to elucidate its specific mechanism. The tight-binding linear muffin-tin orbital method in the…

Materials Science · Physics 2014-03-04 Yohei Kota , Akimasa Sakuma

Density functional calculations with a large unit cell have been conducted to investigate adsorption, segregation and magnetization of Mn monomer on GaAs(110). The Mn adatom is rather mobile along the trench on GaAs(110), with an energy…

Statistical Mechanics · Physics 2009-11-11 J. X. Cao , X. G. Gong , R. Q. Wu