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Fluctuation theorems are a generalization of thermodynamics on small scales and provide the tools to characterize the fluctuations of thermodynamic quantities in non-equilibrium nanoscale systems. They are particularly important for…

Statistical Mechanics · Physics 2014-04-03 Jan Gieseler , Romain Quidant , Christoph Dellago , Lukas Novotny

We develop non-equilibrium theory by using averages in time and space as a generalized way to upscale thermodynamics in non-ergodic systems. The approach offers a classical perspective on the energy dynamics in fluctuating systems. The rate…

Soft Condensed Matter · Physics 2021-09-29 James E. McClure , Steffen Berg , Ryan T. Armstrong

We give a perturbative analysis of Crooks relation and Jarzynski equality in an arbitrary driven quantum system weakly coupled to a heat bath. Invoking no efficient Hamiltonian nor any restriction on the form of the coupling, we derive the…

Statistical Mechanics · Physics 2017-09-15 Yi Peng , Heng Fan

Based on the observation that the thermodynamic equilibrium free energy of an open quantum system in contact with a thermal environment can be understood as the difference between the free energy of the total system and that of the bare…

Statistical Mechanics · Physics 2009-06-01 Michele Campisi , Peter Talkner , Peter Hänggi

We extend a classical relation by Crooks to quantum systems and show that it unifies the Crooks transient fluctuation theorem and the Kawasaki non-linear response relation, which leads to the standard linear response theory. We also show…

Statistical Mechanics · Physics 2012-02-07 Hiroshi Matsuoka

Entropy production is one of the most important characteristics of non-equilibrium steady states. We study here the steady-state entropy production, both at short times as well as in the long-time limit, of two important classes of…

Statistical Mechanics · Physics 2015-05-27 Sven Dorosz , Michel Pleimling

We derive a thermodynamic uncertainty relation for general open quantum dynamics, described by a joint unitary evolution on a composite system comprising a system and an environment. By measuring the environmental state after the…

Statistical Mechanics · Physics 2021-01-06 Yoshihiko Hasegawa

Quantitative studies of irreversibility in statistical mechanics often involve the consideration of a reverse process, whose definition has been the object of many discussions, in particular for quantum mechanical systems. Here we show that…

Quantum Physics · Physics 2021-05-12 Francesco Buscemi , Valerio Scarani

We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but…

Statistical Mechanics · Physics 2017-09-13 Eiki Iyoda , Kazuya Kaneko , Takahiro Sagawa

Systems driven away from thermal equilibrium constantly deliver entropy to their environment. Determining this entropy production requires detailed information about the system's internal states and dynamics. However, in most practical…

Statistical Mechanics · Physics 2017-10-03 Gili Bisker , Matteo Polettini , Todd R. Gingrich , Jordan M. Horowitz

The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schr\"odinger equation, which preserves…

Quantum Physics · Physics 2025-01-16 Florian Meier , Tom Rivlin , Tiago Debarba , Jake Xuereb , Marcus Huber , Maximilian P. E. Lock

Using the stochastic thermodynamics, we determine the entropy production and the dynamic heat capacity of systems subject to a sinusoidally time dependent temperature, in which case the systems are permanently out of thermodynamic…

Statistical Mechanics · Physics 2019-06-26 Carlos E. Fiore , Mário J. de Oliveira

Recent research has considered the stochastic thermodynamics of multiple interacting systems, representing the overall system as a Bayes net. I derive fluctuation theorems governing the entropy production (EP)of arbitrary sets of the…

Statistical Mechanics · Physics 2025-09-01 David H. Wolpert

The detailed fluctuation theorem implies symmetry in the generating function of entropy production probability. The integral fluctuation theorem directly follows from this symmetry and the normalization of the probability. In this paper, we…

Statistical Mechanics · Physics 2024-06-06 Zhiqiang Huang

Recently, Di\'osi et al. (Int. J. Quant. Inf. 4, 99 (2006)) introduced a simple, yet very interesting model for reservoirs, in order to study the relationship between thermodynamic entropy production of a system and the corresponding von…

Mathematical Physics · Physics 2017-06-15 J. Z. Bernád , A. B. Frigyik

We investigate the connection between recent results in quantum thermodynamics and fluctuation relations by adopting a fully quantum mechanical description of thermodynamics. By including a work system whose energy is allowed to fluctuate,…

Quantum Physics · Physics 2017-03-27 Álvaro M. Alhambra , Lluis Masanes , Jonathan Oppenheim , Christopher Perry

The thermodynamics of quantum phase transitions has long been a rich area of research, providing numerous insights and enhancing our understanding of this important phenomenon. This theoretical framework has been well-developed specially…

Quantum Physics · Physics 2024-12-05 Andesson B. Nascimento , Lucas C. Céleri

The Heat theorem reveals the second law of equilibrium Thermodynamics (i.e.existence of Entropy) as a manifestation of a general property of Hamiltonian Mechanics and of the Ergodic Hypothesis, valid for 1 as well as $10^{23}$ degrees of…

Statistical Mechanics · Physics 2008-02-01 Giovanni Gallavotti

We study the thermodynamics of quantum projective measurements by using the set up for the Jarzynski equality. We prove the fluctuations of energy change induced by measurements satisfy the Jarzynski equality, revealing that the quantum…

Statistical Mechanics · Physics 2015-08-31 Juyeon Yi , Yong Woon Kim

Entropy production is a fundamental concept that plays a crucial role in the second law of thermodynamics and the measure of irreversibility. It imposes rigorous constraints on the kinds of transformations allowed in thermodynamic…

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