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We present a new method for realizing the adiabatic connection approach in density functional theory, which is based on combining accurate variational quantum Monte Carlo calculations with a constrained optimization of the ground state…

Materials Science · Physics 2015-06-25 Maziar Nekovee , W. M. C. Foulkes , A. J. Williamson , G. Rajagopal , R. J. Needs

$Aims$: We revisit with new augmented accuracy the theoretical dynamics of basic isotope exchange reactions involved in the $^{12}$C/$^{13}$C, $^{16}$O/$^{18}$O, and $^{14}$N/$^{15}$N balance because these reactions have already been…

Astrophysics of Galaxies · Physics 2015-06-19 Mirjana Mladenović , Evelyne Roueff

For a potential function (in one dimension) which evolves from a specified initial form $V_{i}(x)$ to a different $V_{f}(x)$ asymptotically, we study the evolution, in an overdamped dynamics, of an initial probability density to its final…

Statistical Mechanics · Physics 2007-05-23 H. S. Samanta , J. K. Bhattacharjee , R. Ramaswamy

Nonadiabatic corrections in molecules composed of a few atoms are considered. It is demonstrated that a systematic perturbative expansion around the adiabatic solution is possible, with the expansion parameter being the electron-nucleus…

Chemical Physics · Physics 2009-11-13 Krzysztof Pachucki , Jacek Komasa

An exponential version of a deep nucleon-nucleon potential involving forbidden states and a tensor component is proposed. The parameters of interaction are chosen by fitting the low-energy characteristics and phase shifts of np scattering…

Nuclear Theory · Physics 2007-05-23 S. B. Dubovichenko

When a vacancy is created in an inner-valence orbital of a dimer of atoms or molecules, the resulting species can undergo interatomic/intermolecular Coulombic decay (ICD): the hole is filled through a relaxation process that leads to a…

Chemical Physics · Physics 2023-05-18 Valentina Parravicini , Thomas-C. Jagau

The nuclear cross sections for charged lepton production induced by $\beta$ beam neutrinos (anti-neutrinos) in $^{16}$O have been presented at intermediate energies corresponding to the Lorentz boost factor $\gamma<250 (150)$. The…

Nuclear Theory · Physics 2008-11-26 S. K. Singh , M. Sajjad Athar , Shakeb Ahmad

In this paper we present an invariant perturbation theory to adiabatic process according to the concepts of adiabatic orbits, adiabatic evolution orbit and U(1)-invariant adiabatic orbit. The probabilities of keeping the adiabatic orbit in…

Quantum Physics · Physics 2007-06-06 Jian-Lan Chen , Mei-sheng Zhao , Jian-da Wu , Yong-de Zhang

The leading nonadiabatic corrections to rovibrational levels of a diatomic molecule are expressed in terms of three functions of internuclear distance: corrections to the adiabatic potential, the effective nuclear mass, and the effective…

Chemical Physics · Physics 2015-05-13 Krzysztof Pachucki , Jacek Komasa

The $\beta$-delayed neutron decay of $^{17}$B was studied using a radioactive ion beam. The neutron energies, measured via time-of-flight, give information on states in $^{17}$C above the $^{16}$C + neutron threshold. States in $^{17}$C…

We investigate the LiF spectrum up to $7800$ cm$^{-1}$ above the first dissociation limit. The ab initio calculations of the adiabatic potentials and other molecular functions are performed in a wide range of interatomic separations,…

Atomic Physics · Physics 2025-12-03 V. G. Ushakov , A. Yu. Ermilov , E. S. Medvedev

The total cross sections of the 16O(n,gamma)17O radiative capture process is described in the framework of the modified potential cluster model with the classification of orbital states according to Young tableaux. The possibility to…

Nuclear Theory · Physics 2015-06-18 S B Dubovichenko , N V Afanasyeva , A V Dzhazairov-Kakhramanov

Interstitial hydrogen and deuterium in body-centered-cubic metals constitute archetypal quantum tunneling systems. Their relevance has been renewed by the connection between hydrogenic tunneling in Nb and defect-induced decoherence in…

Quantum Physics · Physics 2026-05-25 P. Graham Pritchard , James M. Rondinelli

In this article, we explore the construction of Hamiltonians with long-range interactions and their corrections using the short-range behavior of the wave function. A key aspect of our investigation is the examination of the one-particle…

Chemical Physics · Physics 2024-05-01 Anthony Scemama , Andreas Savin

While it is well-known that every nearly-periodic Hamiltonian system possesses an adiabatic invariant, extant methods for computing terms in the adiabatic invariant series are inefficient. The most popular method involves the heavy…

Plasma Physics · Physics 2022-06-22 J. W. Burby , J. Squire

We explain the concept of superadiabatic approximations and show how in the context of the Born- Oppenheimer approximation they lead to an explicit formula that can be used to predict transitions at avoided crossings. Based on this formula,…

Chemical Physics · Physics 2016-06-29 Volker Betz , Benjamin D. Goddard , Uwe Manthe

The adiabatic potential energy curves of Rb$_2$ in the long-range Rydberg electronic states are calculated using the two-electron \textit{R}-matrix method [M. Tarana, R. \v{C}ur\'{i}k, Phys. Rev. A \textbf{93}, 012515 (2016)] for the…

Atomic Physics · Physics 2020-12-03 Michal Tarana

The influence of positive $Q$-value four-neutron transfer (PQ4NT) effects on the sub-barrier capture cross sections is systematically investigated using the empirical barrier distribution (EBD2) method. For 13 fusion reactions with…

Nuclear Theory · Physics 2026-01-13 Ning Wang , Yi-Jie Duan , Hong Yao , Hui-Ming Jia

We perform a study of $^{16}$O+$^{16}$O fusion at above and below the interaction barrier energies using three-dimensional time-dependent Hartree-Fock (TDHF) calculations at above barrier energies and density-constrained TDHF calculations…

Nuclear Theory · Physics 2013-09-03 C. Simenel , R. Keser , A. S. Umar , V. E. Oberacker

The lowest order constrained variational method is applied to calculate the polarized symmetrical nuclear matter properties with the modern $AV_{18}$ potential performing microscopic calculations. Results based on the consideration of…

Nuclear Theory · Physics 2008-11-26 G. H. Bordbar , M. Bigdeli