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Approach to equilibrium in adiabatically evolving potentials

Statistical Mechanics 2007-05-23 v1

Abstract

For a potential function (in one dimension) which evolves from a specified initial form Vi(x)V_{i}(x) to a different Vf(x)V_{f}(x) asymptotically, we study the evolution, in an overdamped dynamics, of an initial probability density to its final equilibeium.There can be unexpected effects that can arise from the time dependence. We choose a time variation of the form V(x,t)=Vf(x)+(ViVf)eλtV(x,t)=V_{f}(x)+(V_{i}-V_{f})e^{-\lambda t}. For a Vf(x)V_{f}(x), which is double welled and a Vi(x)V_{i}(x) which is simple harmonic, we show that, in particular, if the evolution is adiabatic, the results in a decrease in the Kramers time characteristics of Vf(x)V_{f}(x). Thus the time dependence makes diffusion over a barrier more efficient. There can also be interesting resonance effects when Vi(x)V_{i}(x) and Vf(x)V_{f}(x) are two harmonic potentials displaced with respect to each other that arise from the coincidence of the intrinsic time scale characterising the potential variation and the Kramers time.

Keywords

Cite

@article{arxiv.cond-mat/0412215,
  title  = {Approach to equilibrium in adiabatically evolving potentials},
  author = {H. S. Samanta and J. K. Bhattacharjee and R. Ramaswamy},
  journal= {arXiv preprint arXiv:cond-mat/0412215},
  year   = {2007}
}

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This paper contains 5 pages